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electron-deficient polyfluoroarenes (105) 105
chemistry, organic (58) 58
chemistry, multidisciplinary (49) 49
palladium (43) 43
direct arylation (38) 38
catalysis (34) 34
activation (27) 27
arenes (26) 26
functionalization (26) 26
index medicus (21) 21
fluorine (20) 20
c-h activation (19) 19
derivatives (18) 18
alkenylation (17) 17
allylation (17) 17
arylation (16) 16
cross-coupling reactions (15) 15
polyfluoroarenes (15) 15
catalyzed direct arylation (14) 14
chemistry, inorganic & nuclear (14) 14
perfluoroarenes (14) 14
bond activation (13) 13
molecular structure (13) 13
arylboronic acids (12) 12
c-h bonds (11) 11
aromatic compounds (10) 10
c-h bond (10) 10
c-h functionalization (10) 10
copper (10) 10
room-temperature (10) 10
alkylation (9) 9
electron-deficient arenes (9) 9
f bond (9) 9
organic-synthesis (9) 9
palladium - chemistry (9) 9
proton-abstraction mechanism (9) 9
aryl (8) 8
bond formation (8) 8
chemical reactions (8) 8
chemical sciences (8) 8
heterocycles (8) 8
reactivity (8) 8
simple arenes (8) 8
terminal alkynes (8) 8
carbon-hydrogen bonds (7) 7
catalysts (7) 7
chemical properties (7) 7
coupling reactions (7) 7
cross-coupling (7) 7
general-method (7) 7
halides (7) 7
potassium polyfluorobenzoates (7) 7
aryl halides (6) 6
benzoic-acids (6) 6
c-h arylation (6) 6
chemical bonds (6) 6
copper - chemistry (6) 6
efficient synthesis (6) 6
electrons (6) 6
intermolecular direct arylation (6) 6
organometallic compounds - chemistry (6) 6
oxidant (6) 6
synthetic methods (6) 6
[ chim ] chemical sciences (5) 5
allyl compounds (5) 5
analysis (5) 5
aryl bromides (5) 5
aryl iodides (5) 5
c-f activation (5) 5
carbonates (5) 5
chemistry (5) 5
chemistry, physical (5) 5
complexes (5) 5
ch activation (5) 5
elektron (5) 5
heteroaromatic-compounds (5) 5
hydrogen bonds (5) 5
ligands (5) 5
mechanism (5) 5
mild (5) 5
nickel (5) 5
acetates (4) 4
alcohols (4) 4
alkenes (4) 4
alkynes (4) 4
allylierung (4) 4
aromatic-compounds (4) 4
aryl fluorides (4) 4
arylierung (4) 4
c-f bond (4) 4
carbon-hydrogen (4) 4
carboxylic-acids (4) 4
ch activation (4) 4
copper-catalyzed arylation (4) 4
cross-coupling reaction (4) 4
c–h activation (4) 4
directing group (4) 4
facile access (4) 4
fluorination (4) 4
grignard-reagents (4) 4
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Journal Article
Organometallics, ISSN 0276-7333, 02/2012, Volume 31, Issue 4, pp. 1335 - 1340
We report a Pd-catalyzed aerobic dehydrogenative cross-coupling of polyfluoroarenes with thiophenes via 2-fold C–H functionalization. The advantages of this... 
DIRECT ALKENYLATION | DIRECT ARYLATION | ARYL BOND FORMATION | ELECTRON-DEFICIENT POLYFLUOROARENES | CRYSTAL-STRUCTURE | CHEMISTRY | CHEMISTRY, ORGANIC | C-H FUNCTIONALIZATION | SIMPLE ARENES | (HETERO)ARENES | PROTON-ABSTRACTION MECHANISM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 22, pp. 5813 - 5817
Journal Article
Organic Letters, ISSN 1523-7060, 01/2011, Volume 13, Issue 2, pp. 276 - 279
Journal Article
Organic Letters, ISSN 1523-7060, 06/2016, Volume 18, Issue 11, pp. 2548 - 2551
Cross-coupling of polyfluoroarenes with aryl carbamates through the cleavage of both sp2 C–O and C–H bonds is reported. The reaction conditions are simple, and... 
O BONDS | ACTIVATION | ETHERS | DIRECT ARYLATION | ELECTRON-DEFICIENT POLYFLUOROARENES | TRANSITION-METAL | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | CLEAVAGE | PHENOL DERIVATIVES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2015, Volume 357, Issue 16‐17, pp. 3753 - 3757
Journal Article
Organic Letters, ISSN 1523-7060, 07/2016, Volume 18, Issue 13, pp. 3302 - 3305
A copper-catalyzed direct propargylation of polyfluoroarenes with secondary propargyl phosphates has been developed. The reaction proceeds under mild reaction... 
ALCOHOLS | CROSS-COUPLINGS | ELECTRON-DEFICIENT POLYFLUOROARENES | C-H ALLYLATION | ARYLATION | ARENES | PERFLUOROARENES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | AROMATIC-COMPOUNDS | ALKENYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 10/2013, Volume 15, Issue 20, pp. 5266 - 5269
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2012, Volume 77, Issue 6, pp. 2992 - 2998
We report a Pd-catalyzed direct arylation of polyfluoroarenes with aryl iodides. The advantages of this reaction are its high reaction efficiency, excellent... 
ORGANIC-SYNTHESIS | ACTIVATION | ELECTRON-DEFICIENT POLYFLUOROARENES | PERFLUOROARENES | CHEMISTRY, ORGANIC | FLUORINE | CARBON-HYDROGEN BONDS | C-H BONDS | SIMPLE ARENES | ALKENYLATION | METATHESIS
Journal Article
Synlett, ISSN 0936-5214, 01/2018, Volume 29, Issue 2, pp. 251 - 255
Abstract An efficient 1,5-cyclooctadiene–PdCl 2 /dicyclohexyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine (XPhos) catalytic system was developed for C–H... 
letter | polyfluoroarenes | palladium catalysis | fluoro compounds | C-H functionalization | allylation | CARBONATES | C-H ALLYLATION | CHEMISTRY, ORGANIC | ELECTRON-DEFICIENT | ARYL ETHERS | F ACTIVATION | FUNCTIONALIZATION | MILD | FLUORINE
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2014, Volume 2014, Issue 16, pp. 3323 - 3327
The palladium‐catalyzed direct arylation of polyfluoroarenes with organosilicon reagents was achieved by establishing general reaction conditions. This... 
C–H activation | Fluorine | Cross‐cou­pling | Arenes | Palladium | Silicon | Biaryls | C-H activation | Cross-coupling | ROOM-TEMPERATURE | ELECTRON-DEFICIENT POLYFLUOROARENES | CHEMISTRY, ORGANIC | N-OXIDES | ARYLBORONIC ACIDS | ARYL BROMIDES | CROSS-COUPLING REACTIONS | H BOND ARYLATION | ALKYL BROMIDES | C-H | Silicon compounds | Chemical tests and reagents
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 02/2018, Volume 54, Issue 18, pp. 2256 - 2259
A cooperative Pd/Cu-catalyzed dual C-H bond activation of electron-deficient polyfluoroarenes with aryl halides is developed. This protocol provides a unique... 
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2018, Volume 54, Issue 18, pp. 2256 - 2259
A cooperative Pd/Cu-catalyzed dual C-H bond activation of electron-deficient polyfluoroarenes with aryl halides is developed. This protocol provides a unique... 
FUNCTIONALIZATION | PALLADIUM | C-H BOND | DIRECT ARYLATION | CONCOMITANT ORTHO-ALKYLATION | ELECTRON-DEFICIENT POLYFLUOROARENES | EFFICIENT SYNTHESIS | F BOND | ARYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | GENERAL-METHOD | Substitutes | Hydrogen bonds | Halides | Aromatic compounds | Catalysis | Derivatives | Chemical synthesis
Journal Article
Organic Letters, ISSN 1523-7060, 04/2016, Volume 18, Issue 8, pp. 1784 - 1787
An efficient palladium-catalyzed alkylation of electron-deficient polyfluoroarenes is described. The protocol provides a useful and operationally simple access... 
ACTIVATION | DIRECT ARYLATION | MILD CONDITIONS | ELECTRON-DEFICIENT POLYFLUOROARENES | ARENES | PERFLUOROARENES | F BOND | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ARYLBORONIC ACIDS | ALKENYLATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 03/2013, Volume 54, Issue 10, pp. 1285 - 1289
A novel cross-coupling reaction of arenediazonium tetrafluoroborates with polyfluoroarenes is briefly described. It has advantages of high reaction efficiency,... 
Polyfluoroarene | Cross-coupling | Biaryl | Arenediazonium tetrafluoroborate | HALIDES | PALLADIUM | DIRECT ARYLATION | ELECTRON-DEFICIENT POLYFLUOROARENES | ARENES | CHEMISTRY, ORGANIC | SALTS | C-H BONDS | FLUORINE | ARYL | Copper
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 07/2016, Volume 5, Issue 7, pp. 882 - 885
A novel and efficient palladium‐catalyzed cross‐coupling benzylation reaction of pentafluorobenzene through selective C−H functionalization has been developed.... 
C−H functionalization | polyfluoroarenes | benzylation | carbonates | Pd catalysis | SUZUKI-MIYAURA COUPLINGS | DIRECT ARYLATION | ELECTRON-DEFICIENT POLYFLUOROARENES | REVERSE-TRANSCRIPTASE | PERFLUOROARENES | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | C-H functionalization | ARYLBORONIC ACIDS | CROSS-COUPLINGS | ARYL | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 09/2012, Volume 14, Issue 18, pp. 4950 - 4953
A copper-catalyzed dehydrogenative cross-coupling of benzothiazoles with thiazoles and polyfluoroarene under mild reaction conditions is described. This... 
AZOLES | ACTIVATION | DIRECT ARYLATION | ELECTRON-DEFICIENT POLYFLUOROARENES | CHEMISTRY, ORGANIC | BOND FORMATION | C-H FUNCTIONALIZATION | EFFICIENT | SIMPLE ARENES | INDOLES | GENERAL-METHOD
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2015, Volume 80, Issue 21, pp. 10874 - 10882
Journal Article
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