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European Journal of Inorganic Chemistry, ISSN 1434-1948, 03/2019, Volume 2019, Issue 11-12, pp. 1586 - 1593
Boryl‐substituted phosphines NHB–P(R)Ph (R = H, Ph, NHB = N‐heterocyclic boryl substituent) react with Fe2(CO)9 to give isolable Fe(CO)4 complexes, two of... 
Ligand effects | Boranes | Palladium | Cross‐coupling | Phosphane ligands | Cross-coupling | ELECTRON-RICH | C-N | ANALOGS | MICROWAVE-ASSISTED AMINATION | CHEMISTRY, INORGANIC & NUCLEAR | PHOSPHORUS LIGANDS | CROSS-COUPLING REACTIONS | ARYL HALIDES | ORGANOMETALLIC CHEMISTRY | BINDING | Heterocyclic compounds | Catalysis | Organic chemistry | Cross coupling | Chemical reactions | Iron | Cobalt | Phosphines
Journal Article
ChemCatChem, ISSN 1867-3880, 04/2015, Volume 7, Issue 8, pp. 1292 - 1301
Iron hydride complexes of the general formula P2Fe(NO)CO)H are highly active catalysts for the hydrosilylation of aldehydes or ketones and phosphine oxides.... 
catalysis | iron | phosphine | reduction | olefination | Reduction | Iron | Catalysis | Olefination | Phosphine | ELECTRON-RICH | HYDROSILYLATION | CHEMISTRY, PHYSICAL | KETONES | MITSUNOBU REACTIONS | IRON COMPLEXES | SUBSTITUTED STYRENES | ASYMMETRIC HYDROGENATION | STEREOSELECTIVE-SYNTHESIS | EFFICIENT | Oxides | Ketones | Aldehydes
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2010, Volume 75, Issue 15, pp. 5320 - 5322
A novel, air-stable phosphine ligand, prepared from readily available 2-bromonitrobenzene and vinylmagnesium bromide, combines with Pd(CH3CN)2Cl2 to afford an... 
ROOM-TEMPERATURE | HIGHLY-ACTIVE CATALYST | AQUEOUS SOLVENTS | C-C | CHEMISTRY, ORGANIC | NICKEL(II) COMPLEXES | N BOND FORMATION | EFFICIENT LIGANDS | ELECTRON-RICH PHOSPHINE | ARYL CHLORIDES | ARYLBORONIC ACIDS | Palladium catalysts | Bromides | Chemical properties | Magnesium | Benzene
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 03/2020, Volume 909, p. 121097
Bidentate phosphines are important ligands in inorganic and organometallic chemistry. However, their electron-donating ability is generally limited by the use... 
Phosphine ligands | Electron-rich complexes | Phosphane | Bidentate ligands
Journal Article
Organic Letters, ISSN 1523-7060, 07/2007, Volume 9, Issue 15, pp. 2795 - 2798
This study describes a new class of easily accessible indolyl phosphine ligands, prepared via an efficient protocol involving Fischer indolization from readily... 
BORONIC ACIDS | HALIDES | ROOM-TEMPERATURE | EFFICIENT CATALYST | ACTIVATION | MILD CONDITIONS | CHEMISTRY, ORGANIC | COORDINATION | ALKYL BROMIDES | ELECTRON-RICH PHOSPHINE | ARYLBORONIC ACIDS | Ligands | Phosphines - chemistry | Catalysis | Chlorides - chemistry | Indoles - chemistry | Palladium - chemistry
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 06/2015, Volume 54, Issue 12, pp. 5888 - 5896
Four bidentate, hybrid ligands ((R)(NP)(R)'H) featuring imine-nitrogen and alkyl-phosphine donors linked by a cyclopentyl ring were synthesized. The ortho... 
COORDINATION CHEMISTRY | ELECTRON-RICH | CATALYSIS | HYDROGENATION | DIHYDROGEN | ALCOHOL DEHYDROGENATION | BOND ACTIVATION | PINCER COMPLEX | STEREOSELECTIVE FORMATION | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2010, Volume 39, Issue 2, pp. 694 - 711
The strong electron-donation and the steric bulk of trialkylphosphines renders them as very useful ligands for palladium-catalyzed cross coupling reactions.... 
ELECTRON-RICH PHOSPHINES | ROOM-TEMPERATURE | ALPHA-ARYLATION | C-O BOND | RESONANCE ENERGY-TRANSFER | HOMOGENEOUS CATALYSIS | DEACTIVATED ARYL CHLORIDES | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA
Journal Article
Chemical Society reviews, ISSN 0306-0012, 02/2010, Volume 39, Issue 2, pp. 694 - 711
The strong electron-donation and the steric bulk of trialkylphosphines renders them as very useful ligands for palladium-catalyzed cross coupling reactions.... 
Journal Article
Arkivoc, ISSN 1551-7012, 03/2012, Volume 2012, Issue 6, pp. 164 - 172
This work established that highly regioselective Heck-Mizoroki arylation of olefins can be accomplished with aryl halides using Pd-2(dba)(3) (dba =... 
Heck reaction | Palladium catalyst | Regioselectivity | Microwave heating | Ionic liquid | regioselectivity | PALLADIUM | PHOSPHINE | ARYLATION | COMPLEXES | CHEMISTRY, ORGANIC | ionic liquid | microwave heating | COUPLING REACTIONS | ARYL HALIDES | CHLORIDES | ELECTRON-RICH OLEFINS | EFFICIENT
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2005, Volume 46, Issue 11, pp. 1815 - 1818
DOE-optimized conditions, 13 additional examples. A combination of Pd 2(dba) 3·CHCl 3 (0.5 mol %) and commercially available, air-stable phosphonium salt [(... 
Electron-rich phosphines | Cyanation | Aryl bromides | Design of experiments | Room temperature | HALIDES | room temperature | electronrich phosphines | PHOSPHINE | aryl bromides | COMPLEXES | CHEMISTRY, ORGANIC | BOND FORMATION | CONVENIENT | cyanation | MILD CONDITIONS | TRANSITION-METAL | CHLORIDES | LIGAND | design of experiments
Journal Article
Inorganic Chemistry Communications, ISSN 1387-7003, 2004, Volume 7, Issue 11, pp. 1225 - 1228
The synthesis, characterization, and the result of the X-ray crystal structure determination of trans - [ Rh ( NO ) ( NO 2 ) 2 ( Bu 2 t PH ) 2 ] is presented.... 
Nitrite | Rhodium | Nitric oxide | Secondary phosphines | Crystal structure | ELECTRON-RICH | nitric oxide | PLATINUM METALS | secondary phosphines | NUCLEAR MAGNETIC RESONANCE | REACTIVITY | NITROSYL COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | nitrite | LIGANDS | CLUSTERS | MOLECULAR-STRUCTURES | crystal structure | DERIVATIVES | rhodium
Journal Article