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2008, 1st ed., ISBN 0470049618, viii, 301
Superelectrophiles and Their Chemistry contains, for the first-time, a discussion of the basics of this emerging field of organic chemistry, alongside tools to... 
SCIENCE / Chemistry / Organic | Organic compounds–Synthesis | Superelectrophiles | Chemical affinity | Organic Chemistry | Synthesis | Organic compounds
Book
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 39, pp. 13929 - 13935
A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This... 
Arylation | Ligands | Usage | Research | Electrophiles
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 6, pp. 2236 - 2239
A Ni/Cu-catalyzed silylation of unactivated C–O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its... 
Usage | Nickel | Research | Electrophiles | Copper
Journal Article
Catalysis science & technology, ISSN 2044-4753, 2013, Volume 3, Issue 3, pp. 562 - 571
Significant progress has been accomplished in direct C-H bond arylations of arenes and heteroarenes with readily accessible, inexpensive phenol derivatives.... 
Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
Journal Article
Chemical reviews, ISSN 0009-2665, 01/2015, Volume 115, Issue 2, pp. 650 - 682
  The authors study the use of hypervalent iodine reagents in electrophilic trifluoromethylation reactions. Activation of the reagents by Lewis acids and.... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Chemical properties | Iodides | Methylation | Electrophiles | Analysis | Chemical synthesis | Chemical reactions | Chemical compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 27, pp. 8356 - 8359
A room-temperature stable (phosphino)-phosphinidene reacts with carbon monoxide, stable singlet carbenes, including the poor π-accepting imidazol-2-ylidene,... 
Research | Carbon monoxide | Chemical properties | Electrophiles
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 28, pp. 9423 - 9426
Synthesis of biaryls via the Suzuki–Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies... 
Palladium | Chemical properties | Catalysis | Research | Electrophiles
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2013, Volume 135, Issue 40, pp. 14968 - 14971
A one-pot protocol for the asymmetric α-allylation reaction is reported relying on a key efficient asymmetric Claisen rearrangement, triggered by electrophilic... 
Allylic compounds | Research | Electrophiles | Chirality
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2016, Volume 138, Issue 16, pp. 5214 - 5217
The direct, catalytic, asymmetric α-functionalization of acyclic esters constitutes a significant challenge in the area of asymmetric catalysis, particularly... 
Ammonium compounds | Catalysis | Electrophiles | Ammonium paratungstate | Analysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4075 - 4078
We report the first enantioselective CC bond formation through CO bond cleavage using aryl ester counterparts. This method is characterized by its wide... 
C‐O cleavage | aryl esters | C‐O electrophiles | nickel catalysis | C-O electrophiles | C-O cleavage
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 4, pp. 1207 - 1210
A novel palladium-catalyzed intermolecular ditrifluoromethoxylation of unactivated alkenes has been developed, using a new electrophilic reagent,... 
Palladium | Chemical properties | Fluorometholone | Electrophiles | Analysis | Olefins
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2018, Volume 140, Issue 6, pp. 2036 - 2040
Regioselective α,α-difunctionalization adjacent to a ketone is a significant synthetic challenge. Here, we present a solution to this problem through the... 
Electrophiles | Analysis | Enolates | Electric properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 50, pp. 15620 - 15623
A copper-catalyzed regio- and enantio­selective hydroamination of alkenyl dan boronates (dan =1,8-diaminonaphthyl) with hydrosilanes and hydroxylamines... 
Amino acids | Usage | Separation | Chemical properties | Electrophiles | Analysis
Journal Article
Chemical reviews, ISSN 0009-2665, 03/2011, Volume 111, Issue 3, pp. 1780 - 1824
Bond formations between two nucleophiles are examined. Chemical reactions during transition metal matalyzed oxidative cross-coupling reactions are also... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Transition metals | Analysis | Chemical bonds | Catalysis | Chemical properties | Research | Nucleophiles | Electrophiles | Chemical reactions | Catalytic oxidation | Metals | Bonding
Journal Article