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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 5, pp. 1404 - 1408
Isoxazolinones are biologically and synthetically interesting densely functionalized heterocycles, which for a long time were not accessible in enantioenriched... 
regioselectivity | isoxazolinones | phosphoramidite | heterocycles | quaternary stereocenters | ENANTIOSELECTIVE ALLYLIC SUBSTITUTION | 2H-AZIRINES | ISOXAZOL-5(4H)-ONES | ALKYLATION | COMPLEXES | NUCLEOPHILE | CHEMISTRY, MULTIDISCIPLINARY | AMINATION | ESTERS | SELECTIVITY | Enantiomers | Catalysis | Regioselectivity | Catalysts | Chirality | Chemical reactions | Iridium | Allyl compounds | Isomers
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2018, Volume 57, Issue 52, pp. 17151 - 17155
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2016, Volume 49, Issue 10, pp. 2169 - 2178
Stereoselective indium-mediated organic reactions have enjoyed tremendous growth in the last 25 years. This is in part due to the insensitivity of allylindium... 
ORGANIC-SYNTHESIS | BARBIER-TYPE ALLYLATION | AQUEOUS-MEDIA | CARBONYL-COMPOUNDS | CHIRAL HYDRAZONES | NEUTRAL-COORDINATE-ORGANOCATALYSTS | ENANTIOSELECTIVE ALLYLATION | ORGANOINDIUM REAGENTS | ALLYLIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALLYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 3020 - 3023
We describe the fully stereodivergent, dual catalytic α-allylation of linear aldehydes. The reaction proceeds via direct iridium-catalyzed substitution of... 
TRANSITION-METAL CATALYSIS | 2,4-DISUBSTITUTED CYCLOPENTENONES | ASYMMETRIC CLAISEN REARRANGEMENT | ENANTIOSELECTIVE SYNTHESIS | FORMAL SYNTHESIS | VICINAL TERTIARY | ALLYLIC ALKYLATION | CARBONYL-COMPOUNDS | ENAMINE CATALYSIS | BRANCHED ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | Amines | Influence | Chemical properties | Iridium | Catalysis | Research | Aldehydes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2016, Volume 138, Issue 37, pp. 12252 - 12257
The Rh­(III)-catalyzed oxidative C–H allylation of N-acetyl­benzamides with 1,3-dienes is described. The presence of allylic hydrogens cis to the less... 
SIGMA-CAM MECHANISM | DIRECTING GROUPS | 3+2 ANNULATION | 1,4-METAL MIGRATION | NUCLEOPHILIC ALLYLATION | ELECTRON-DEFICIENT ARENES | CARBONYL-COMPOUNDS | BOND ACTIVATION | ENANTIOSELECTIVE ALLYLATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIC IMINES | Usage | Rhodium | Oxidation-reduction reaction | Chemical properties | Catalysis | Carbon compounds | Hydrogen bonding
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2018, Volume 2018, Issue 37, pp. 5109 - 5116
A series of unsymmetrically substituted diastereoisomeric (Ra,R) and (Sa,R) bipyridine N,N′‐dioxides was synthesized by using oxidative coupling of the... 
Catalyst design | Asymmetric synthesis | Aldehydes | Organocatalysis | Asymmetric catalysis | Allylation | PYRIDINE-N-OXIDES | PROPARGYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | AROMATIC-ALDEHYDES | ALLYLTRICHLOROSILANE | ORGANOCATALYSTS | PATHWAY | N,N'-DIOXIDES | ENANTIOSELECTIVE ALLYLATION | ASYMMETRIC ALLYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14363 - 14367
Fully stereodivergent dual‐catalytic α‐allylation of protected α‐amino‐ and α‐hydroxyacetaldehydes is achieved through iridium‐ and amine‐catalyzed... 
iridium | aldehydes | amine catalysis | dual catalysis | stereodivergence | ENANTIOSELECTIVE ALLYLIC ALKYLATION | ASYMMETRIC-SYNTHESIS | ACID | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | MANNICH-TYPE REACTIONS | TRANSITION-METAL | ESTERS | DIRECT ADDITION
Journal Article
Synthesis, ISSN 0039-7881, 07/2019, Volume 51, Issue 13, pp. 2585 - 2631
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2013, Volume 52, Issue 52, pp. 14200 - 14203
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2016, Volume 138, Issue 35, pp. 11093 - 11096
An Ir/Zn dual catalysis has been developed for the enantio- and diastereodivergent α-allylation of unprotected α-hydroxyketones under mild conditions, in the... 
ASYMMETRIC ALDOL REACTION | MANNICH-TYPE REACTION | ENANTIOSELECTIVE SYNTHESIS | IRIDIUM | ALLYLIC SUBSTITUTION-REACTIONS | DINUCLEAR ZINC CATALYST | ALKYLATION | AMINO | DIASTEREOSELECTIVITY | CONSTRUCTION | CHEMISTRY, MULTIDISCIPLINARY | Stereoisomers | Zinc compounds | Usage | Catalysis | Iridium | Chemical properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 18, pp. 5050 - 5054
Palladium‐catalyzed regio‐, diastereo‐, and enantioselective allylic alkylation of β‐ketocarbonyls with Morita–Baylis–Hillman adducts has been developed using... 
palladium | P ligands | asymmetric catalysis | spiro compounds | allylic compounds | P ligands | ENANTIOSELECTIVE ALLYLIC ALKYLATION | REAGENTS | HYDROGENATION | ENANTIO | CHEMISTRY, MULTIDISCIPLINARY | DIASTEREO | SPIROKETALS | AMINATION | LIGANDS | ALPHA-ALLYLATION | DUAL CATALYSIS
Journal Article