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Organic Letters, ISSN 1523-7060, 04/2015, Volume 17, Issue 7, pp. 1728 - 1731
The atroposelective desymmetrization of N-arylmaleimides was realized by means of a primary amine catalyzed Diels–Alder reaction of enones. The chiral axis as... 
BIARYL NATURAL-PRODUCTS | CATALYZED ENANTIOSELECTIVE REACTIONS | C-2-CHIRAL PYRROLIDINES | ASYMMETRIC-SYNTHESIS | PRIMARY AMINE | ATROPISOMERIC AMIDES | CHEMISTRY, ORGANIC | VINYLOGOUS MICHAEL ADDITION | CHIRAL PHOSPHORIC-ACID | 1ST EXAMPLE | DYNAMIC KINETIC RESOLUTION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2016, Volume 358, Issue 20, pp. 3173 - 3178
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 29, pp. 8529 - 8532
An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desymmetrization of 1,4‐dienes under the catalysis of... 
enantioselectivity | gold | alkoxylation | desymmetrization | Claisen rearrangement | INTRAMOLECULAR CARBOALKOXYLATION | ACTIVATION | ASYMMETRIC CLAISEN REARRANGEMENT | GOLD CATALYSIS | COMPLEXES | TRANSITION-STATE | CHEMISTRY, MULTIDISCIPLINARY | CYCLOADDITION | CHIRALITY | SELECTION | ALLYL VINYL ETHERS | Enantiomers | Catalysis | Formations | Transformations | Gold | enantioselective
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2017, Volume 58, Issue 51, pp. 4731 - 4739
[Display omitted] •Desymmetrization of meso-diols is a useful method for natural products synthesis.•Catalytic method using enzyme, organic compound, and metal... 
meso-Diol | Oxidation | Desymmetrization | Acylation | Horeau-Langenbeck amplification | ASYMMETRIC DESYMMETRIZATION | DESIGN | DIAMIDOPHOSPHITES | BUILDING-BLOCKS | HYDROLYSIS | CHEMISTRY, ORGANIC | TRANSITION-METALS | ENANTIOSELECTIVE DESYMMETRIZATION | mesa-Dial | KINETIC RESOLUTION | DESYMMETRISATION | CATALYSTS | Hydrolysis | Enzymes | Synthesis | Biological products | Metal catalysts | Glycols | Organic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14447 - 14451
A gold(I)‐catalyzed enantioselective desymmetrization of 1,3‐diols was achieved by intramolecular hydroalkoxylation of allenes. The catalyst system... 
enantioselective synthesis | gold | allenes | desymmetrization | hydroalkoxylation | TRANSITION-METAL CATALYSIS | BROMOETHERIFICATION | ALLYLATION | COMPLEXES | ACYL TRANSFER | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | ALKENES | LIGANDS | HYDROARYLATION | Gold - chemistry | Catalysis | Stereoisomerism | Alkadienes - chemistry
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 07/2016, Volume 52, Issue 62, pp. 9640 - 9643
The first alpha -sp2-carbon of carbonyl compounds attacked catalytic desymmetrization reaction of aziridines is disclosed. A simple in situ generated magnesium... 
Carbonyl compounds | Level (quantity) | Catalysts | Chemical attack | Ligands | Magnesium | Catalysis | Enantiomers
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2014, Volume 136, Issue 15, pp. 5627 - 5630
An enantioselective and highly diastereoselective bromoetherification and desymmetrization of olefinic 1,3-diols has been developed using a C 2-symmetric... 
PRACTICAL CHEMOENZYMATIC SYNTHESIS | INDUCED POLYENE CYCLIZATIONS | BROMOLACTONIZATION | LEWIS-BASE CATALYSIS | 2,2,4-TRISUBSTITUTED TETRAHYDROFURANS | ACTIVE ANTIFUNGAL AGENT | SCH 56592 | CHIRAL PHOSPHORIC-ACID | ALKENOIC ACIDS | ENANTIOSELECTIVE IODOLACTONIZATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 12/2012, Volume 14, Issue 23, pp. 6016 - 6019
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15093 - 15097
A desymmetrization strategy was developed involving iridium‐catalyzed allylic dearomatization of indoles. The six‐membered‐ring spiroindolenines contain three... 
enantioselective synthesis | indoles | asymmetric catalysis | iridium catalysts | dearomatization | CIRCULARLY-POLARIZED LUMINESCENCE | CHIRAL RECOGNITION | MACROMOLECULES | ELECTRON-DONOR | NANOSTRUCTURES | CHEMISTRY, MULTIDISCIPLINARY | DYE | FLUORESCENCE | ASSEMBLIES | ENANTIOSELECTIVE RECOGNITION | SUPRAMOLECULAR GELS | Enantiomers | Catalysis | Iridium | Indoles | Quaternary | Indole
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 29, pp. 10250 - 10253
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2016, Volume 55, Issue 19, pp. 5829 - 5833
An unprecedented asymmetric desymmetrization of meso‐epoxides, derived from cyclopentene‐1,3‐diones, with 2‐mercaptobenzothiazoles has been realized. It was... 
enantioselectivity | dysprosium | asymmetric catalysis | heterocycles | N ligands | N ligands | ASYMMETRIC DESYMMETRIZATION | COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | THIOLS | PYRROLIDINES | KINETIC RESOLUTION | 1,3-DIPOLAR CYCLOADDITION | ENANTIOSELECTIVE INTERMOLECULAR DESYMMETRIZATION | Nligands | INHIBITORS | EFFICIENT CONSTRUCTION | QUATERNARY STEREOGENIC CENTER | Cytokinins | Catalysis | Thiophene
Journal Article
by Li, XQ and Xiong, Q and Guan, MM and Dong, SX and Liu, XH and Feng, XM
ORGANIC LETTERS, ISSN 1523-7060, 08/2019, Volume 21, Issue 15, pp. 6096 - 6101
A highly enantioselective ring-opening desymmetrization of meso-aziridines with isocyanides was achieved in the presence of a chiral N,N'-dioxide/Mg(OTf)(2)... 
COMPLEX | MAGNESIUM CATALYSIS | CHEMISTRY | CHEMISTRY, ORGANIC | ALPHA-ADDITION | STEREOSELECTIVE-SYNTHESIS | UGI REACTION | EFFICIENT | ENANTIOSELECTIVE DESYMMETRIZATION | CYCLIZATION | DEAROMATIZATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2017, Volume 359, Issue 21, pp. 3729 - 3734
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 24, pp. 7524 - 7527
A carbene-catalyzed desymmetrization of prochiral bisphenol compounds bearing remote P-stereogenic centers is disclosed. The catalytic reactions can be... 
ORGANOCATALYSTS | ENANTIOSELECTIVE SYNTHESIS | TERTIARY PHOSPHINES | RESOLUTION | ACYL TRANSFER | EFFICIENT ASYMMETRIC-SYNTHESIS | REDUCTIVE ALDOL REACTION | CHEMISTRY, MULTIDISCIPLINARY | INTRAMOLECULAR STETTER REACTION | PHOSPHORUS-COMPOUNDS | CYCLOHEXADIENONES | Phosphorus compounds | Chemical properties | Catalysis | Research
Journal Article