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Accounts of Chemical Research, ISSN 0001-4842, 09/2015, Volume 48, Issue 9, pp. 2587 - 2598
Chiral alcohols are important building blocks in the pharmaceutical and fine chemical industries. The enantioselective reduction of prochiral ketones catalyzed... 
TETRADENTATE LIGAND | PNNP LIGAND | AROMATIC KETONES | REDUCTION | MACROCYCLES | IMINES | IRIDIUM CATALYST | COMPLEXES | SYSTEMS | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE TRANSFER HYDROGENATION | Ketones | Nickel | Iron | Research | Chemical properties | Catalysis | Hydrogenation | Reduction | Asymmetry | Catalysts | Ligands
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2014, Volume 136, Issue 4, pp. 1367 - 1380
After their treatment with LiAlH4 and then alcohol, new iron dicarbonyl complexes mer-trans-[Fe­(Br)­(CO)2(P–CHN–P′)]­[BF4] (where P–CHN–P′ =... 
DENSITY FUNCTIONALS | DIHYDROGEN | MECHANISM | ACETOPHENONE | ENANTIOSELECTIVE HYDROGENATION | TRICARBONYL | COOPERATIVE TRANSITION-METAL | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | HETEROLYTIC CLEAVAGE | HYDRIDE | Density functionals | Usage | Iron compounds | Research | Nuclear magnetic resonance | Ketones
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2017, Volume 23, Issue 30, pp. 7212 - 7216
The reductive amination of α‐dialkylphosphine acetaldehydes with enantiopure β‐aminophosphines is a new, versatile route to unsymmetrical tridentate (pincer)... 
pincer ligand synthesis | ketone reduction | asymmetric synthesis | iron catalysts | hydrogenation | MECHANISM | IMINES | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | DEHYDROGENATION | CHIRAL BETA-AMINOPHOSPHINES | MILD CONDITIONS | ENANTIOSELECTIVE HYDROGENATION | PINCER LIGANDS | ESTERS | Synthesis | Ketones | Catalysts | Enantiomers | Hydrogenation | Organic compounds | Ligands
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2014, Volume 136, Issue 10, pp. 4031 - 4039
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2017, Volume 7, Issue 1, pp. 316 - 326
Our group previously reported the development of iron carbonyl catalysts bearing chiral tridentate P–N–P′ ligands for the asymmetric hydrogenation of prochiral... 
ketone | hydride | iron catalysis | mechanism | asymmetric hydrogenation | ALKENE HYDROGENATION | NEUTRON-DIFFRACTION | CHEMISTRY, PHYSICAL | HOMOGENEOUS HYDROGENATION | SELECTIVE HYDROGENATION | EFFICIENT HYDROGENATION | ENANTIOSELECTIVE HYDROGENATION | TRANSITION-METAL | CHIRAL BRONSTED ACID | NONRIGID 6-COORDINATE MOLECULES | BIFUNCTIONAL ADDITION
Journal Article
Journal Article
Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 21, pp. 5380 - 5383
Catalyzed by a rhodium complex of P-stereogenic diphosphine trichickenfootphos, five-membered cyclic α-dehydroamino ketones bearing endocyclic acyl and... 
BETA-AMINO KETONES | HIGHLY ENANTIOSELECTIVE HYDROGENATION | ENANTIOSPECIFIC SYNTHESIS | SILYL ENOL ETHERS | BINAP RU(II) COMPLEXES | CHEMISTRY, ORGANIC | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | RHODIUM COMPLEX | FRIEDEL-CRAFTS REACTION | RUPHOX-RU | DERIVATIVES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5825 - 5828
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 08/2015, Volume 26, Issue 15-16, pp. 769 - 790
[Display omitted] In this review, we consider the main processes for the asymmetric transfer hydrogenation of ketones from 2008 up today. The most effective... 
PHOSPHINITE LIGANDS | CHIRAL LIGANDS | AROMATIC KETONES | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, PHYSICAL | ARYL KETONES | PROCHIRAL KETONES | IRON CATALYSTS | COMPLEXES BEARING | HETEROGENEOUS CATALYST | DYNAMIC KINETIC RESOLUTION | Ketones | Hydrogenation
Journal Article
Organic Letters, ISSN 1523-7060, 09/2015, Volume 17, Issue 17, pp. 4144 - 4147
Catalyzed by [Rh­(COD)­Binapine]­BF4, the asymmetric hydrogenation of 2-pyridine ketones has been achieved with excellent enantioselectivities (enantiomeric... 
HIGHLY ENANTIOSELECTIVE HYDROGENATION | ABSOLUTE-CONFIGURATION | HETEROAROMATIC KETONES | LIGANDS | KINETIC RESOLUTION | PYRIDYL ALCOHOLS | CU(II)(BORABOX)-CATALYZED ACYLATION | CHEMISTRY, ORGANIC | STEREOSELECTIVE HYDROGENATION | EFFICIENT | IRIDIUM CATALYSTS
Journal Article