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Organic Letters, ISSN 1523-7060, 04/2013, Volume 15, Issue 8, pp. 1994 - 1997
A three-step sequence to access functionalized 4,5-dihydrooxepines from cyclohexenones has been developed. This approach features a regioselective... 
OXACYCLES | EPOXIDES | 2-CF3-CIS-2,3-BIS(ALKENYL)OXIRANES | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | STEREOSELECTIVE PREPARATION | SESQUITERPENE | GLIOTOXIN | COPE REARRANGEMENT | RING-SYSTEM | EPICOCCIN G
Journal Article
Chemical Communications, ISSN 1359-7345, 09/2014, Volume 50, Issue 68, pp. 9690 - 9692
An asymmetric synthetic strategy for constructing the divergent-synthesis monomer of epidithiodiketopiperazine (ETP) natural products has been successfully... 
MARINE ORGANISMS | DIKETOPIPERAZINES | SULFURATING REAGENT | EPIPOLYTHIODIKETOPIPERAZINE ALKALOIDS | EPIPOLYTHIODIOXOPIPERAZINES | GENERAL-APPROACH | GLIOTOXIN | EPICOCCIN G | DEMAND DIELS-ALDER | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Asymmetry | Natural products | Precursors | Strategy | Inverse | Scaffolds | Monomers
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2015, Volume 2015, Issue 34, pp. 7438 - 7442
Structurally diverse natural products from unrelated sources typically require the development of individual synthetic routes. In a novel approach, we have... 
Clausenamide | Cyclization | Natural products | Total synthesis | Hyalodendrin | FORMAL SYNTHESIS | CONCISE TOTAL-SYNTHESIS | SYNAPTIC-TRANSMISSION | EPIPOLYTHIODIOXOPIPERAZINES | CHEMISTRY, ORGANIC | EPICOCCIN G | ENANTIOSELECTIVE TOTAL SYNTHESES | PROSTATE-CANCER | BIOLOGICAL EVALUATION | GLIOTOXIN | Pharmacy | Synthesis | Organic compounds
Journal Article
Chemical Science, ISSN 2041-6520, 05/2014, Volume 5, Issue 5, pp. 2003 - 2006
The epidithiodioxopiperazine skeleton is found in a variety of biologically active compounds. Despite numerous attempts at constructing this highly... 
HYALODENDRIN | PROLINE ANHYDRIDE | EPIPOLYTHIODIKETOPIPERAZINE ALKALOIDS | ANTIBIOTICS GLIOTOXIN | TRIOXOPIPERAZINE PRECURSORS | IN-VIVO | GENERAL-APPROACH | PREPARING EPIDITHIODIOXOPIPERAZINES | EPICOCCIN G | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Asymmetry | Construction | Synthesis
Journal Article
Synthesis, ISSN 0039-7881, 01/2017, Volume 49, Issue 2, pp. 391 - 396
Abstract The desymmetrized meso -chimonantine core of leptosin C was prepared in a short stereoselective convergent sequence in 5 steps as the longest linear... 
paper | tandem reaction | cycloadditions | asymmetric synthesis | mycotoxins | alkaloids | DIAZO TRANSFER | CHEMISTRY, ORGANIC | BIOLOGICAL-ACTIVITIES | EPICOCCIN G | QUATERNARY CARBON STEREOCENTERS | AZIDE | CYTOTOXIC METABOLITES | EPIPOLYTHIODIKETOPIPERAZINE ALKALOIDS | MARINE ALGA | AMINO-ACIDS | GENERAL-APPROACH
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2013, Volume 135, Issue 11, pp. 4231 - 4234
Journal Article
Organic Letters, ISSN 1523-7060, 06/2014, Volume 16, Issue 11, pp. 2854 - 2857
A concise route to the core structure 1 of 6-5-6-5-6-membered epipolythiodiketopiperazines is described. The strategy relies on construction of the pyrrolines... 
SCABROSIN ESTERS | MICROCIN SF608 | CYCLOADDITION REACTIONS | METABOLITES | NATURAL-PRODUCTS | BIOLOGICAL EVALUATION | CHEMISTRY, ORGANIC | B METHYL-ESTER | EPICOCCIN G | ACETYLARANOTIN | DERIVATIVES | Piperazines - chemical synthesis | Molecular Structure | Piperazines - chemistry | Stereoisomerism | Aldehydes - chemistry
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2014, Volume 50, Issue 68, pp. 9690 - 9692
An asymmetric synthetic strategy for constructing the divergent-synthesis monomer of epidithiodiketopiperazine (ETP) natural products has been successfully... 
Biological Products - chemical synthesis | Biological Products - chemistry | Stereoisomerism | Indoles - chemical synthesis | Piperazines - chemical synthesis | Piperazines - chemistry | Cycloaddition Reaction | Indoles - chemistry | Electrons
Journal Article
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