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chemistry, inorganic & nuclear (82) 82
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2019, Volume 141, Issue 5, pp. 1871 - 1876
While diamagnetic transition metal complexes that bind and split H-2 have been extensively studied, paramagnetic complexes that exhibit this behavior remain... 
NMR | DIHYDROGEN | MOLECULAR-HYDROGEN | REVERSIBLE HETEROLYTIC CLEAVAGE | OXIDATIVE ADDITION | H-H DISTANCES | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | ETA-2-DIHYDROGEN | FE | hydride, dihydrogen, EPR
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2013, Volume 52, Issue 43, pp. 11347 - 11350
Bigger and better: The replacement of anionic chloride ligands in Noyori‐type [(diamine)(diphosphine)RuCl2] catalysts with bulky carboxylate ligands enabled... 
base‐free conditions | ruthenium | aldehydes | homogeneous catalysis | hydrogenation | base-free conditions | KETONES | MECHANISM | DIHYDRIDE COMPLEXES | ESTERS | ASYMMETRIC HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | ETA-2-DIHYDROGEN | Ruthenium | Surface active agents | Aldehydes | Hydrogenation | Catalysts | Chlorides | Ligands | Carboxylic acids | Catalysis | Carboxylates
Journal Article
Journal of Physical Chemistry C, ISSN 1932-7447, 10/2012, Volume 116, Issue 42, pp. 22245 - 22252
The solid state complex [Mn(CO)dppe(2)]-[BArF24] was synthesized, and the thermodynamic behavior and properties of the hydrogen absorption reaction to form the... 
STORAGE | ACTIVATION | ETA-2-DIHYDROGEN COMPLEXES | EFFECTIVE CORE POTENTIALS | MATERIALS SCIENCE, MULTIDISCIPLINARY | MOLECULAR-HYDROGEN COMPLEXES | AB-INITIO | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | DENSITY | ML5 METAL FRAGMENTS | LIGAND | EXCHANGE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2002, Volume 124, Issue 50, pp. 15104 - 15118
The complexes trans-RuH(Cl)(tmen)(R-binap) (1) and (OC-6−43)-RuH(Cl)(tmen)(PPh3)2 (2) are prepared by the reaction of the diamine NH2CMe2CMe2NH2 (tmen) with... 
LIGAND BIFUNCTIONAL CATALYSIS | ASYMMETRIC TRANSFER HYDROGENATION | ETA-2-DIHYDROGEN COMPLEXES | CRYSTAL-STRUCTURE | SPECTROSCOPIC PROPERTIES | X-RAY STRUCTURE | STEREOSELECTIVE HYDROGENATION | DIHYDROGEN COMPLEXES | PHOSPHINE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | PROTON-TRANSFER EQUILIBRIUM
Journal Article
Canadian Journal of Chemistry, ISSN 0008-4042, 2006, Volume 84, Issue 2, pp. 164 - 175
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2005, Volume 127, Issue 12, pp. 4152 - 4153
The compound fac-[Ru((R)-BINAP)(H)(2-PrOH)3]+ (6) (BINAP = 2,2‘-bis(diphenylphosphino)-1,1‘-binaphthyl) reacts with (R,R)-dpen (dpen =... 
ALCOHOLS | MECHANISM | COMPLEXES | COORDINATION | ASYMMETRIC HYDROGENATION | H-H BOND | PROTON-TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | METAL-DIHYDROGEN | CATALYSTS | ETA-2-DIHYDROGEN | Ruthenium | Chemical properties
Journal Article
Organometallics, ISSN 0276-7333, 08/2013, Volume 32, Issue 15, pp. 4409 - 4415
A double-cyclometalated ruthenium complex containing a chiral tripodal phospholane has been prepared by reaction with [Ru(η4-COD)(η3-methylallyl)2] via... 
NONCLASSICAL INTERLIGAND INTERACTIONS | H BOND ACTIVATION | NMR | TRIPHENYL PHOSPHITE | ETA-2-DIHYDROGEN COMPLEXES | TRANSITION-METAL-COMPLEXES | LIGANDS | X-RAY-STRUCTURE | CHEMISTRY, ORGANIC | DIHYDROGEN COMPLEXES | POLYHYDRIDE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 1996, Issue 14, pp. 1665 - 1666
The ancillary ligands in trans-[FeH(CN)L(2)] control whether protonation occurs at hydride to produce a dihydrogen complex or at cyanide to produce a hydrogen... 
HYDROGEN ISOCYANIDE | DIHYDROGEN | SERIES | CHEMISTRY | METAL-COMPLEX | COORDINATION | 1ST EXAMPLE | ETA-2-DIHYDROGEN
Journal Article
Canadian Journal of Chemistry, ISSN 0008-4042, 11/1996, Volume 74, Issue 11, pp. 1907 - 1915
Some of the research of the author and his research group into the structure and reactions of dihydrogen complexes of transition metals is reviewed. The... 
NMR | Neutron diffraction | Hydride | Transition metal | Dihydrogen | Iridium | Complexes | Osmium | TRANSITION-METAL COMPLEXES | MOLECULAR-HYDROGEN COMPLEXES | dihydrogen | NEUTRON-DIFFRACTION | osmium | CRYSTAL-STRUCTURE DETERMINATION | transition metal | iridium | hydride | X-RAY | CHEMISTRY | neutron diffraction | K DY CHEMISTRY | LIGAND | BOND | complexes | ETA-2-DIHYDROGEN | ACIDITY
Journal Article
Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, ISSN 0376-4710, 01/2005, Volume 44, Issue 1, pp. 27 - 33
A new dihydrogen hydride complex of ruthenium of the type trans-[(dppm)Ru(H)(eta(2) -H-2)(PPh3)(2)][BF4] (1) (dppm = Ph2PCH2PPh2) has been prepared by... 
MOLECULAR-HYDROGEN COMPLEXES | AB-INITIO | ORGANOMETALLIC COMPLEXES | REACTIVITY | TRIAD | POLYHYDRIDES | LIGAND | OSMIUM | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | ETA-2-DIHYDROGEN
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2009, Issue 30, pp. 4563 - 4565
Unexpected changes in the T-1 values for the F-19 NMR signal of the BF4- anion in the presence of dihydrogen complexes reveal that ion pairing with BF4-center... 
DEPROTONATION | SUBSTITUTION | NMR METHODS | LIGANDS | SPECTROSCOPIC PROPERTIES | ORGANOMETALLIC CHEMISTRY | RUTHENIUM | DIFFUSION | CHEMISTRY, MULTIDISCIPLINARY | ETA-2-DIHYDROGEN
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2008, Issue 38, pp. 5197 - 5206
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/1996, Volume 118, Issue 23, pp. 5396 - 5407
A high-yield route to the new complexes OsBr2(dppe)(2) and trans-OsHBr(dppe)(2) starting from (NH4)(2)-[OsBr6] is described. The new 5-coordinate complexes... 
RUTHENIUM FORMYL | R = PH | CRYSTAL-STRUCTURE | MOLECULAR-HYDROGEN COMPLEXES | NEUTRON-DIFFRACTION | X-RAY | CHEMISTRY | IRON | METAL-HYDRIDES | 1,2-BIS(DICYCLOHEXYLPHOSPHINO)ETHANE | ETA-2-DIHYDROGEN
Journal Article
Russian Chemical Bulletin, ISSN 1066-5285, 11/2014, Volume 63, Issue 11, pp. 2434 - 2437
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 05/2004, Volume 43, Issue 11, pp. 3341 - 3343
The water-soluble iron phosphine complex trans-Fe(DMeOPrPE)(2)Cl-2 (DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) reacts with H-2 in water to produce... 
M = FE | MOLECULAR-HYDROGEN COMPLEXES | X-RAY | COORDINATION | IRON | EXCHANGE | DIHYDROGEN COMPLEXES | ETA-2-DIHYDROGEN | CHLORIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2004, Volume 126, Issue 22, pp. 7049 - 7062
Diastereomerically pure complexes of formula CpRuCl(PP*) and CpRuH(PP*) with chiral ferrocenyl diphosphines were prepared and the selectivity of... 
LIGANDS | RAY CRYSTAL-STRUCTURES | DIHYDRIDE COMPLEXES | STEREOCHEMISTRY | REACTIVITY | CYCLOPENTADIENYL-OSMIUM CHEMISTRY | COORDINATED DIHYDROGEN | CHEMISTRY, MULTIDISCIPLINARY | METAL-COMPLEXES | ETA-2-DIHYDROGEN | Deuteron reactions | Ruthenium | Chemical properties | Cyclopentadiene | Analysis
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2004, Volume 43, Issue 4, pp. 1328 - 1335
Hydride complexes [FeH(N-N)P3]BPh4 (1, 2) [N-N = 2,2‘-bipyridine (bpy) and 1,10-phenanthroline (phen); P = P(OEt)3, PPh(OEt)2, and PPh2OEt] were prepared by... 
RU | OS | CRYSTAL-STRUCTURE | MOLECULAR-HYDROGEN COMPLEXES | COORDINATION | POLYHYDRIDES | METAL | M=FE | DIHYDROGEN COMPLEXES | ETA-2-DIHYDROGEN | CHEMISTRY, INORGANIC & NUCLEAR | Iron compounds | Chemical properties | Chemical compounds | Analysis
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2003, Volume 42, Issue 9, pp. 2859 - 2866
Journal Article
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