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European Journal of Organic Chemistry, ISSN 1434-193X, 07/2019, Volume 2019, Issue 28, pp. 4597 - 4603
The construction of (Z)‐(hetero)arylethenesulfonyl fluorides was achieved utilizing Iridium photoredox catalysis under UV‐light irradiation. This protocol... 
Sulfur fluoride exchange | Iridium | Click chemistry | ETHENESULFONYL FLUORIDES | SULFONYL FLUORIDES | DRUG DISCOVERY | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, ORGANIC | ANTITUMOR-ACTIVITY | CATALYZED FLUOROSULFONYLVINYLATION | XANTHINE-OXIDASE | COVALENT INHIBITORS | IRREVERSIBLE ENZYME-INHIBITORS | SUFEX CLICK | Fluorides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 45, pp. 14155 - 14158
A Heck–Matsuda process for the synthesis of the otherwise difficult to access compounds, β‐arylethenesulfonyl fluorides, is described. Ethenesulfonyl fluoride... 
Heck–Matsuda reaction | Michael addition | β-arylethenesulfonyl fluorides | ethenesulfonyl fluoride | sulfur(VI) fluoride exchange (SuFEx) | ethenesulfonyl fluoride (ESF) | Heck-Matsuda
Journal Article
by Xu, RT and Xu, TX and Yang, MC and Cao, TP and Liao, SH
NATURE COMMUNICATIONS, ISSN 2041-1723, 08/2019, Volume 10, Issue 1, pp. 3752 - 7
The past few years have witnessed a fast-growing research interest on the study of sulfonyl fluorides as reactive probes in chemical biology and molecular... 
SUFEX CLICK CHEMISTRY | PHOTOREDOX | ACIDS | MULTIDISCIPLINARY SCIENCES | LIGHT | ESTERS | ETHENESULFONYL FLUORIDE | SOF4 | ELECTROPHILES | METAL-FREE | Organic chemistry | Forging | Fluoride | Peptides | Natural products | Sulfonamides | Amino acids | Pharmacology | Carboxylic acids | Fluorides | Aliphatic compounds
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2018, Volume 2018, Issue 32, pp. 4407 - 4410
The first RhIII‐catalyzed activation of ortho‐C–H bonds of arylcarboxylic esters for monoselective coupling with ethenesulfonyl fluoride (ESF) was developed.... 
C‐H activation | Synthetic methods | Electrophiles | Fluorine | Sulfur(VI) fluoride exchange (SuFEx) | C-H activation | ETHENESULFONYL FLUORIDES | SULFONYL FLUORIDES | CELLS | RHODIUM | FUNCTIONALIZATIONS | TRANSTHYRETIN | ARENES | CHEMISTRY, ORGANIC | OLEFINATION | ARYL | ALKENYL | Esters | Fluorides
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2016, Volume 55, Issue 45, pp. 14155 - 14158
Journal Article
by Chen, XY and Wu, YC and Zhou, J and Wang, P and Yu, JQ
ORGANIC LETTERS, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1426 - 1429
A rapid synthesis of beta-arylethenesulfonyl fluorides is realized using ligand-accelerated Pd(II)-catalyzed nondirected C-H alkenylation of simple arenes. The... 
FLUOROSULFONYLVINYLATION | FUNCTIONALIZATION | SULFONYL FLUORIDES | PALLADIUM | OLEFINATION | SUFEX CLICK CHEMISTRY | DRUG DISCOVERY | ARENES | CHEMISTRY, ORGANIC | ETHENESULFONYL FLUORIDE | ELECTROPHILES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2017, Volume 359, Issue 18, pp. 3254 - 3260
(E)‐2‐(hetero)arylethenesulfonyl fluorides and (E,E)‐1,3‐dienylsulfonyl fluorides are bis‐electrophiles and rare members of the sulfonyl fluoride family with... 
Fused δ-sultone | Pyrazolones | DBU | Ethenesulfonyl fluorides | SULFONYL FLUORIDES | PALLADIUM | CHEMISTRY | CHEMISTRY, ORGANIC | Fused delta-sultone | SULFURYL FLUORIDE | CHEMISTRY, APPLIED | Organic chemistry | Chemical reactions | Catalysis | Fluorides | Chemical synthesis
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2019, Volume 361, Issue 19, pp. 4596 - 4601
The intermolecular cyclopropanation of 2‐aryl and 2‐styryl substituted ethenesulfonyl fluorides with active cyano‐containing methylene compounds was described.... 
Cyclopropanation | Diastereoselectivity | Nitrile-substituted | Ethenesulfonyl fluorides | MEDIATED CYCLOPROPANATION | ALKENES | OXINDOLES | CHEMISTRY, ORGANIC | CHEMISTRY, APPLIED | SUFEX CLICK | CATALYZED FLUOROSULFONYLVINYLATION | ACCESS | Substitutes | Stereoselectivity | Aromatic compounds | Cleavage | Fluorides | Sulfur | Carbon | Organic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 14, pp. 4552 - 4556
SuFEx is a new‐generation click chemistry transformation that exploits the unique properties of S−F bonds and their ability to undergo near‐perfect reactions... 
click chemistry | trifluoromethylation | bis(trifluoromethyl)sulfur oxyimines | SuFEx chemistry | fluorine | PHASE | AZIDES | ETHENESULFONYL FLUORIDE | SOF4 | CHEMISTRY, MULTIDISCIPLINARY | Sulfur compounds | Fluorides | Chromatography | Innovations | Organic chemistry | Transformation | Purification | Synthesis | Chemical synthesis | Sulfur | Nucleophiles | Potassium | Substrates | Anticancer properties
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2019, Volume 21, Issue 23, pp. 9742 - 9746
An enantioselective conjugate addition of ethylene sulfonyl fluorides to 3-amido-2-oxindoles has been developed. Quinine-derived squaramides were identified as... 
ETHENESULFONYL FLUORIDES | DESIGN | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | 3-AMINOOXINDOLES | INHIBITORS | CATALYZED FLUOROSULFONYLVINYLATION | DERIVATIVES | DUAL WARHEAD | SUFEX | MICHAEL ADDITION
Journal Article