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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4075 - 4078
We report the first enantioselective CC bond formation through CO bond cleavage using aryl ester counterparts. This method is characterized by its wide... 
C‐O cleavage | aryl esters | C‐O electrophiles | nickel catalysis | C-O electrophiles | C-O cleavage
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2018, Volume 59, Issue 39, pp. 3524 - 3527
[Display omitted] •First total synthesis of keto-tetraene 15-oxo-Lipoxin A4 has been achieved.•Synthetic approach: iterative palladium-catalyzed coupling using... 
Palladium-catalyzed coupling | Eicosanoid | MIDA boronate | Electrophile | electrophile | eicosanoid | palladium-catalyzed coupling
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 39, pp. 13929 - 13935
A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This... 
ARYL BROMIDES | HALIDES | NUCLEOPHILES | CATALYSIS | ALKENE ISOMERIZATION-HYDROBORATION | SECONDARY ALKYL ELECTROPHILES | NICKEL | NEGISHI ARYLATIONS | CARBOXYLATION | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Ligands | Usage | Research | Electrophiles
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4188 - 4188
The chemistry of metallabenzenes and fused‐ring metallabenzenes continues to expand. Herein, we report the first simple amino‐substituted derivatives.... 
iridium | amines | aromaticity | electrophiles | metallacycles
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11324 - 11329
By merging cross-electrophile coupling and C–C bond cleavage, we developed a Ni-catalyzed electrophilic ring opening of cycloketone oxime esters with aromatic... 
Ni-catalysis | C-C bond cleavage | ring opening | cross-electrophile | cyanoketones | 4-EXO CYCLIZATIONS | BUILDING-BLOCKS | CHEMISTRY, PHYSICAL | CLEAVAGE | C-H CYANOALKYLATION | ALKYL-HALIDES | ARYL BROMIDES | EPOXIDES | ring opening cross-electrophile | TERTIARY ALKYL | COUPLING REACTIONS | STEREOSELECTIVE-SYNTHESIS
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 03/2009, Volume 48, Issue 14, pp. 2588 - 2591
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4075 - 4078
We report the first enantioselective C-C bond formation through C-O bond cleavage using aryl ester counterparts. This method is characterized by its wide... 
PALLADIUM | ACTIVATION | aryl esters | O BOND | ALPHA-ARYLATION | STRATEGY | C-O electrophiles | CHEMISTRY, MULTIDISCIPLINARY | C-O cleavage | nickel catalysis | KETONES | CROSS-COUPLING REACTIONS | REDUCTIVE CLEAVAGE | CONSTRUCTION | ELECTROPHILES
Journal Article
Journal Article
Annual Review of Pharmacology and Toxicology, ISSN 0362-1642, 2012, Volume 52, Issue 1, pp. 221 - 247
Quinones are a group of highly reactive organic chemical species that interact with biological systems to promote inflammatory, anti-inflammatory, and... 
Covalent bond | Oxidative stress | Prooxidant | Redox cycling | Quinone | Electrophile | DIESEL EXHAUST PARTICLES | redox cycling | KAPPA-B ACTIVATION | BRONCHIAL EPITHELIAL-CELLS | AIRBORNE PARTICULATE MATTER | POLYCYCLIC AROMATIC-HYDROCARBONS | NITRIC-OXIDE SYNTHASE | electrophile | CYTOCHROME P450 REDUCTASE | EPIDERMAL-GROWTH-FACTOR | ELECTROPHILE-BINDING MOTIFS | PHARMACOLOGY & PHARMACY | TOXICOLOGY | prooxidant | covalent bond | oxidative stress | PROTEIN-TYROSINE-PHOSPHATASE | quinone | Air Pollutants - analysis | Naphthoquinones - analysis | Quinones - analysis | Reactive Oxygen Species - metabolism | Naphthalenes - analysis | Humans | Carcinogens - analysis | Carcinogens - toxicity | Carcinogens - classification | Anti-Inflammatory Agents - analysis | Cysteine - metabolism | Naphthalenes - chemistry | Quinones - chemistry | Anti-Inflammatory Agents - pharmacology | Cells, Cultured | Naphthoquinones - pharmacology | Environmental Exposure - analysis | Protein Tyrosine Phosphatase, Non-Receptor Type 1 - metabolism | Animals | Anti-Inflammatory Agents - chemistry | Environment | Naphthoquinones - chemistry | Naphthalenes - toxicity | Glyceraldehyde-3-Phosphate Dehydrogenases - metabolism | Air Pollutants - chemistry | Environmental aspects | Environmental chemistry | Chemical properties | Research | Environmental impact analysis | Index Medicus
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 22, p. 4421
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1878 - 1881
Iron­(III) salts promote the condensation of aldehydes or acetals with electron-rich phenols to generate ortho-quinone methides that undergo DielsAlder... 
BIOMIMETIC SYNTHESIS | ROBUSTADIAL-A | ACID | DIASTEREOSELECTIVE SYNTHESIS | FORMAL SYNTHESIS | CHIRAL BIPHENOLS | CYCLOADDITIONS | CHEMISTRY, ORGANIC | ELECTROPHILE | DERIVATIVES | CYCLIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 52, pp. 15618 - 15620
Palladium and nickel: This Highlight summarizes recent developments in the area of dual‐catalytic Ullman‐type coupling reactions of aryl bromides and... 
cross‐electrophile coupling | multicatalysis | dual catalysis | Ullman coupling | reductive coupling | cross-electrophile coupling | HALIDES | BOND FORMATION | ARYL | CHEMISTRY, MULTIDISCIPLINARY | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2013, Volume 135, Issue 2, pp. 624 - 627
The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst... 
CROSS-COUPLING REACTIONS | COMPLEX | ALLYLATION | ALLYLIC GRIGNARD-REAGENTS | BROMIDES | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 05/2014, Volume 16, Issue 9, pp. 2566 - 2569
A simple protocol for iron-catalyzed cross-coupling of nonactivated secondary alkyl bromides and iodides with alkynyl Grignard reagents at room temperature has... 
NUCLEOPHILES | IODIDES | COMPLEX | REACTIVITY | CHEMISTRY, ORGANIC | SONOGASHIRA REACTIONS | BROMIDES | ELECTROPHILES
Journal Article
Experimental Neurology, ISSN 0014-4886, 03/2020, Volume 325, p. 113142
A major gap in the field of ischemic preconditioning (IPC) is whether or not long-lasting neuroprotection can be achieved. Moreover, the specific mechanisms... 
Ischemic tolerance | Post-stroke cognitive impairment | Neuroprotection | Stroke | Electrophile
Journal Article
Bioscience, Biotechnology, and Biochemistry, ISSN 0916-8451, 07/2015, Volume 79, Issue 7, pp. 1044 - 1049
Lipid-derived electrophilic molecules are endogenously generated and are causally involved in many pathophysiological effects. Prostaglandin D 2 , a major... 
prostaglandin | lipid mediator | electrophile | protein modification
Journal Article
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