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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4075 - 4078
We report the first enantioselective CC bond formation through CO bond cleavage using aryl ester counterparts. This method is characterized by its wide... 
C‐O cleavage | aryl esters | C‐O electrophiles | nickel catalysis | C-O electrophiles | C-O cleavage
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 39, pp. 13929 - 13935
A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This... 
ARYL BROMIDES | HALIDES | NUCLEOPHILES | CATALYSIS | ALKENE ISOMERIZATION-HYDROBORATION | SECONDARY ALKYL ELECTROPHILES | NICKEL | NEGISHI ARYLATIONS | CARBOXYLATION | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Ligands | Usage | Research | Electrophiles
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 17, pp. 4188 - 4188
The chemistry of metallabenzenes and fused‐ring metallabenzenes continues to expand. Herein, we report the first simple amino‐substituted derivatives.... 
iridium | amines | aromaticity | electrophiles | metallacycles
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4075 - 4078
We report the first enantioselective C-C bond formation through C-O bond cleavage using aryl ester counterparts. This method is characterized by its wide... 
PALLADIUM | ACTIVATION | aryl esters | O BOND | ALPHA-ARYLATION | STRATEGY | C-O electrophiles | CHEMISTRY, MULTIDISCIPLINARY | C-O cleavage | nickel catalysis | KETONES | CROSS-COUPLING REACTIONS | REDUCTIVE CLEAVAGE | CONSTRUCTION | ELECTROPHILES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 22, p. 4421
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2013, Volume 135, Issue 2, pp. 624 - 627
The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst... 
CROSS-COUPLING REACTIONS | COMPLEX | ALLYLATION | ALLYLIC GRIGNARD-REAGENTS | BROMIDES | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 05/2014, Volume 16, Issue 9, pp. 2566 - 2569
A simple protocol for iron-catalyzed cross-coupling of nonactivated secondary alkyl bromides and iodides with alkynyl Grignard reagents at room temperature has... 
NUCLEOPHILES | IODIDES | COMPLEX | REACTIVITY | CHEMISTRY, ORGANIC | SONOGASHIRA REACTIONS | BROMIDES | ELECTROPHILES
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 06/2015, Volume 48, Issue 6, pp. 1767 - 1775
Cross-electrophile coupling, the cross-coupling of two different electrophiles, avoids the need for preformed carbon nucleophiles, but development of general... 
Electrophiles | Halides | Chemical properties
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2018, Volume 8, Issue 1, pp. 310 - 313
1,1-Diarylalkanes are important structural frameworks which are widespread in biologically active molecules. Herein, we report a reductive relay cross-coupling... 
alkyl electrophiles | high-valent nickel | 1,1-diarylalkanes | migratory cross-coupling | β-hydride elimination | HALIDES | HYDROCARBONS | NEGISHI ARYLATIONS | UNACTIVATED TERTIARY ALKYL | SECONDARY | CHEMISTRY, PHYSICAL | FUNCTIONALIZATION | beta-hydride elimination | STEREOCENTERS | CARBOXYLATION | REMOTE | ELECTROPHILES
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/2014, Volume 136, Issue 32, pp. 11212 - 11215
A Ni-catalyzed carboxylation of unactivated primary alkyl bromides and sulfonates with CO2 at atmospheric pressure is described. The method is characterized by... 
ARYL BROMIDES | TRANSFORMATION | CROSS-COUPLING REACTIONS | REAGENTS | ACIDS | ZINC HALIDES | BONDS | CARBON-DIOXIDE | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIVE CARBOXYLATION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2016, Volume 138, Issue 24, pp. 7504 - 7507
A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO, at atmospheric pressure is described. This protocol... 
HALIDES | CROSS-COUPLING REACTIONS | TERTIARY ALKYL | COMPLEX | ACIDS | BONDS | OXIDATIVE ADDITION | CARBON-DIOXIDE | ELECTROPHILES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 05/2018, Volume 20, Issue 9, pp. 2770 - 2773
The palladium-catalyzed Ullmann cross-coupling of beta-iodoenones and beta-iodoacrylates such as 5 (X = I) with o-halonitroarenes and o-iodobenzonitriles... 
KETONES | QUINOLINES | CHEMISTRY, ORGANIC | ALPHA | HALO-ENONES | ELECTROPHILES | DERIVATIVES | ENALS
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 888 - 891
It is reported that Pd­(PPh3)2Cl2 in combination with 4,5-bis­(diphenyl­phosphino)-9,9-dimethyl­xanthene (Xantphos) under irradiation of blue LEDs efficiently... 
NUCLEOPHILES | IODIDES | CROSS-COUPLING REACTIONS | ARYL HALIDES | CHEMISTRY, ORGANIC | REDOX-ACTIVE ESTERS | DERIVATIVES | ELECTROPHILES | ALKYL-HALIDES | CARBOXYLIC-ACIDS
Journal Article
Synlett, ISSN 0936-5214, 05/2016, Volume 27, Issue 8, pp. 1165 - 1174
Abstract We have developed a general approach to the catalytic hydrofunctionalization of alkynes, involving hydrocupration and electrophilic functionalization... 
account | metal hydrides | catalysis | copper | N -heterocyclic carbenes | electrophiles
Journal Article
Tetrahedron, ISSN 0040-4020, 03/2019, Volume 75, Issue 9, pp. 1231 - 1245
Herein, we present a full account of our studies with respect to the reactivity of insufficiently explored 1λ -isothiazolidine-1,1,4-triones (so-called... 
Electrophiles | Nucleophiles | Sulfonamides | Spiro compounds | X-ray study
Journal Article
Organic Letters, ISSN 1523-7060, 04/2011, Volume 13, Issue 8, pp. 2138 - 2141
A Ni-catalyzed reductive approach to the cross-coupling of two unactivated alkyl halides has been successfully developed. The reaction works efficiently for... 
REAGENTS | MECHANISM | ARYL HALIDES | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | C-ALKYL | SUZUKI REACTIONS | BROMIDES | ELECTROPHILES | EFFICIENT
Journal Article
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