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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 12, pp. 3394 - 3397
Unequivocal evidence of enantioselective, equilibrium separation of a racemic mixture on a naturally chiral metal surface is presented for the first time. The... 
enantioselectivity | adsorption | asymmetric catalysis | chirality | surfaces
Journal Article
ChemCatChem, ISSN 1867-3880, 2018, Volume 10, Issue 5, pp. 861 - 861
The Cover Feature shows the combination of a gold‐catalyzed hydration and a biocatalytic reduction step leading to chiral aryl‐ethyl alcohols in excellent... 
enantioselectivity | enzymes | alcohols | biocatalysis | alkynes
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 17, pp. 4189 - 4189
Planar chiral ligands based upon (η5‐cyclopentadienyl)(η4‐tetraphenylcyclobutadiene)cobalt(I) were readily synthesised as single stereoisomers. This chemistry... 
enantioselectivity | sandwich complexes | ligands | cobalt | diastereoselectivity
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2017, Volume 23, Issue 27, p. n/a
This article summarized the significant works in the catalytic asymmetric diastereodivergent synthesis without changing drastically the reaction conditions or... 
enantioselectivity | diastereodivergency | asymmetric catalysis | Catalysis | Chemical synthesis
Journal Article
Synlett, ISSN 0936-5214, 01/2017, Volume 28, Issue 2, pp. 270 - 274
Abstract A novel approach has been developed for the enantioselective synthesis of α-chiral γ-acetoxyallylboronates via the copper(I)-catalyzed γ-boryl... 
letter | enantioselectivity | catalysis | copper | allylation | boron
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2008, Volume 47, Issue 26, pp. 4882 - 4886
The relay of chiral information from the α‐carbon atom of the amino acid ligand is believed to be crucial for chiral induction in the PdII‐catalyzed... 
enantioselectivity | CH activation | amino acids | boronic acids | CC coupling | C-C coupling | Amino acids | C-H activation | Enantioselectivity | Boronic acids
Journal Article
Proceedings of the National Academy of Sciences - PNAS, ISSN 1091-6490, 2017, Volume 114, Issue 10, pp. 2474 - 2478
Noncovalent interactions between molecules are key for many biological processes. Necessarily, when molecules interact, the electronic charge in each of them... 
Enantioselectivity | Spin | Chirality | Exchange interaction | Biorecognition | enantioselectivity | PROTEIN | chirality | biorecognition | ELECTRONS | MULTIDISCIPLINARY SCIENCES | spin | exchange interaction | ATOMS | SELECTIVITY | Biological Sciences | Physical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2019, Volume 141, Issue 17, pp. 6817 - 6821
Herein, we show the highly enantioselective borylation of unactivated methylene C­(sp3)–H bonds in 2-alkylpyridines and 2-alkyl-1,3-azole derivatives using an... 
FUNCTIONALIZATION | ACTIVATION | ENANTIOSELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 18, pp. 5460 - 5464
The first catalytic asymmetric inverse‐electron‐demand (IED) oxa‐Diels–Alder reaction of ortho‐quinone methides, generated in situ from ortho‐hydroxybenzyl... 
enantioselectivity | organocatalysis | cycloaddition | asymmetric catalysis | heterocycles | Heterocycles | Cycloaddition | Enantioselectivity | Asymmetric catalysis | Organocatalysis | BRONSTED ACID | ACTIVATION | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | COOPERATIVE CATALYSIS | BIFUNCTIONAL ORGANOCATALYTIC STRATEGY | PHOSPHORIC-ACID | STEREOCENTERS | ACCESS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2006, Volume 12, Issue 4, pp. 1216 - 1220
Cytochrome P450 BM‐3 from Bacillus megaterium was engineered for enantioselective epoxidation of simple terminal alkenes. Screening saturation mutagenesis... 
enantioselectivity | cytochrome p450 | epoxidation | alkenes | cofactors | biocatalysis | Epoxidation | Biocatalysis | Alkenes | Enantioselectivity | Cytochrome p450 | Cofactors
Journal Article
Synlett, ISSN 0936-5214, 06/2016, Volume 27, Issue 9, pp. 1379 - 1382
Abstract A novel organocatalyzed C–C bond-scission reaction of saturated aldehydes containing a suitable leaving group at the β-position was used for the in... 
letter | enantioselectivity | organocatalysis | alkylation | aldehydes | bond scission
Journal Article
Organic letters, ISSN 1523-7060, 10/2012, Volume 14, Issue 20, pp. 5230 - 5233
The synthesis of a series of tridentate ligands based on a homochiral 1,2-diamine structure attached to a triazole group and their subsequent applications to... 
ALCOHOLS | ORIGIN | AROMATIC KETONES | REDUCTION | ENANTIOSELECTIVITY | MECHANISM | ACETOPHENONE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CATALYST
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 1/2019, Volume 17, Issue 5, pp. 1284 - 1285
Correction for 'Enantioselective copper catalysed intramolecular C-H insertion reactions of α-diazo-β-keto sulfones, α-diazo-β-keto phosphine oxides and... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 28, pp. 9537 - 9541
Morpholine ketene aminal is employed in iridium‐catalyzed asymmetric allylic alkylation reactions as a surrogate for amide enolates to prepare γ,δ‐unsaturated... 
enantioselectivity | iridium | alkylation | amides | allylation | REARRANGEMENT | 2,4-DISUBSTITUTED CYCLOPENTENONES | ENANTIOSELECTIVE SYNTHESIS | ACIDITIES | ACETATES | CHEMISTRY, MULTIDISCIPLINARY | Amides | Silane | Enolates | Silanes | Morpholine | Amines | Ketones | Chemical reactions | Iridium | Catalysis | Alkylation
Journal Article
Synlett, ISSN 0936-5214, 2014, Volume 26, Issue 3, pp. 350 - 351
Abstract The diastereo- and enantioselective reductive coupling of vinylazaarenes with N -Boc aldimines is described. The reactions proceed using chiral... 
cluster | enantioselectivity | copper | imines | vinylazaarenes | Asymmetric catalysis | asymmetric catalysis | ALKENYLAZAARENES | HYDROGENATION | VINYL KETONES | ACTIVATING GROUPS | CHEMISTRY, ORGANIC | HYDROAMINATION | ALDOL REACTION | MANNICH REACTIONS | NITROALKENES | ACRYLATES
Journal Article
Synthesis (Stuttgart), ISSN 0039-7881, 2017, Volume 50, Issue 2, pp. 314 - 322
An enantio- and regioselective organocatalytic cascade starting from isatin has been disclosed to construct tetrahydrofuranyl spirooxindoles in high yields and... 
paper | enantioselectivity | Michael addition | organocatalysis | heterocycles | domino reaction
Journal Article
Angewandte Chemie (International ed.), ISSN 1521-3773, 2008, Volume 47, Issue 17, pp. 3096 - 3099
Copper makes the difference: Important challenges have been overcome in copper‐catalyzed Ullmann reactions since its renaissance in the early 2000s.... 
enantioselectivity | copper | homogeneous catalysis | cross‐coupling | arylation | Arylation | Cross-coupling | Enantioselectivity | Copper | Homogeneous catalysis | ALPHA-ARYLATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | ETHER FORMATION | IODIDES | MILD CONDITIONS | LIGANDS | ARYL HALIDES | cross-coupling | NITROGEN | BENZIMIDAZOLES
Journal Article
Chemical Society reviews, ISSN 0306-0012, 10/2018, Volume 47, Issue 21, pp. 7845 - 7850
Questions of relevance to those working in the field of natural products synthesis that can be answered, at least in part, using computational chemistry... 
Journal Article
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