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Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 9, pp. 2804 - 2808
The reaction of SIPr, [1,3‐bis(2,6‐diisopropylphenyl)‐imidazolin‐2‐ylidene] (1), with C6F6 led to the formation of an unprecedented mesoionic compound (2). The... 
ylides | structure elucidation | C−F activation | carbanions | N-heterocyclic carbenes | Lewis acid | Fluoride | Fluorides
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1412 - 1418
Palladium‐catalyzed CF bond formation via directed CH activation has recently emerged as a significant method to introduce fluorine atoms into organic... 
fluorination | catalysis | CH activation | palladium | CF bond formation | C-H activation | C-F bond formation | RHODIUM | MECHANISM | PHARMACEUTICALS | CONVERSION | COMPLEXES | ARYLATION | CHEMISTRY, ORGANIC | REDUCTIVE ELIMINATION | MEDICINAL CHEMISTRY | FUNCTIONALIZATION | CHEMISTRY, APPLIED | ORTHO-FLUORINATION | Organic chemistry | Synthesis | Fluorine | Strategy | Activation | Transformations | Fluorination | Bonding
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 39, pp. 12763 - 12766
Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds... 
FLUOROARENES | ACTIVATION | MAGNESIUM(I) DIMERS | REAGENTS | BUILDING-BLOCKS | METAL | C-F BOND | CATALYZED BORYLATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | HYDRODEFLUORINATION | Communication
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 24, pp. 3852 - 3860
The detailed mechanism for arylation of styrene or its α-CF 3 substituted analog using aryliron complex [CpFe(CO) 2Ar] was studied using density functional... 
β-H/F elimination | Insertion | Arylation | Styrene derivative | Stilbene | MOLECULAR CALCULATIONS | MECHANISM | ALKYL | EFFECTIVE CORE POTENTIALS | CHEMISTRY, ORGANIC | ARYLZINC | CHEMISTRY, INORGANIC & NUCLEAR | beta-H/F elimination | KINETICS | PALLADIUM-CATALYZED TRANSMETALATION | CONTINUUM | Thermodynamics | Specific gravity | Analysis
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 04/2015, Volume 119, Issue 13, pp. 7156 - 7163
The reaction of CH3F on partially dehydroxylated Al2O3 yields isobutene and higher hydrocarbons along with dimethyl ether. In a combined experimental and... 
SOLID-STATE NMR | ACTIVE-SITE | METAL CENTERS | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | TOTAL-ENERGY CALCULATIONS | ELASTIC BAND METHOD | GAMMA-ALUMINA | FLUORINATED ALUMINAS | CATALYTIC HYDRODEFLUORINATION | 2,2,3-TRIMETHYLBUTANE TRIPTANE | C-F
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2005, Volume 127, Issue 44, pp. 15585 - 15594
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 02/2015, Volume 10, Issue 2, pp. 468 - 473
Transition‐metal‐catalyzed CF activation, in comparison with CH activation, is more difficult to achieve and therefore less fully understood, mainly because... 
iridium | chemoselectivity | arenes | homogeneous catalysis | CF activation | Arenes | Iridium | Chemoselectivity | C-F activation | Homogeneous catalysis | ROOM-TEMPERATURE | O-ARYLATION | COPPER | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | HYDRODEFLUORINATION | PHENOLS | COUPLING REACTION | ARYL HALIDES | METAL | AMIDATE ANCILLARY LIGANDS
Journal Article
Polyhedron, ISSN 0277-5387, 01/2019, Volume 157, pp. 458 - 466
Synthesis and characterization of [P,N]-ligated perfluoronickelacyclopentanes based on the bidentate ligand 2-(diphenylphosphino)phenyl-N-phenylaniline [P,NH]... 
C–F bond activation | Organonickel chemistry | Bifunctional ligands | Metal organofluorine chemistry | CATALYSIS | ACTIVATION | MECHANISM | COMPLEXES | C-F bond activation | CRYSTALLOGRAPHY | CHEMISTRY, INORGANIC & NUCLEAR | REDUCTION | LIGANDS | ESTERS | ASYMMETRIC HYDROGENATION | PYROLYSIS | Surface active agents | Chemical properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2007, Volume 46, Issue 28, pp. 5321 - 5324
A clean break: The novel catalytic conversion of hexafluoropropene into (3,3,3‐trifluoropropyl)silanes by CF activation has been developed (see scheme). The... 
silanes | alkenes | CF activation | fluorine | rhodium | Silanes | Alkenes | Rhodium | Fluorine | C-F activation | CROSS-COUPLING REACTION | MECHANISM | REACTIVITY | RUTHENIUM | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-FLUORINE BONDS | NICKEL | DERIVATIVES | METAL-COMPLEXES
Journal Article
Synthesis, ISSN 0039-7881, 12/2015, Volume 47, Issue 23, pp. 3727 - 3732
Abstract A simple and convenient approach is developed for the synthesis of the imidazo[1,2- f ]phenanthridine framework via post-functionalization of... 
paper | palladium catalysis | C-H activation | C-C bond formation | imidazo[1,2- f ]phenanthridines | direct arylation | MECHANISM | ONE-POT SYNTHESIS | DIVERSE | POLYSUBSTITUTED IMIDAZOLES | CHEMISTRY, ORGANIC | SEQUENTIAL SYNTHESIS | HIGHLY EFFICIENT | HETEROCYCLES | UGI | 3-COMPONENT | imidazo[1, 2-f]phenanthridines
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2001, Volume 40, Issue 18, pp. 3387 - 3389
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2019, Volume 58, Issue 2, pp. 390 - 402
Journal Article
Organometallics, ISSN 0276-7333, 02/2018, Volume 37, Issue 4, pp. 521 - 525
The nickel-C4F8 fragment coordinates an aminoaryl N–H ketimine to form a stable complex, which upon treatment with base and oxidant leads to an N–N... 
ACTIVATION | N-N BOND | COMPLEXES | CHEMISTRY, ORGANIC | LIGAND | C-F | CHEMISTRY, INORGANIC & NUCLEAR | Chemistry
Journal Article