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fluoroarenes (117) 117
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arenes (4) 4
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Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2017, Volume 53, Issue 77, pp. 10688 - 10691
We have developed a novel approach for the stereodivergent hydrodefluorination of gem-difluoroalkenes using copper(i) catalysts to obtain stereodefined... 
Journal Article
Nature Communications, ISSN 2041-1723, 10/2013, Volume 4, Issue 1, p. 2553
Catalytic hydrodefluorination of organic molecules is a major organometallic challenge, owing to the strength of C-F sigma bonds, and it is a process with... 
ALCOHOLS | ROOM-TEMPERATURE | FLUOROARENES | ACTIVATION | REDUCTION | LIGANDS | DEHALOGENATION | MULTIDISCIPLINARY SCIENCES | COMPLEXES | C-F BONDS | STRUCTURAL FEATURES
Journal Article
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 22, pp. 7249 - 7252
A mild and practical cobalt-catalyzed defluoroborylation of fluoroarenes is presented for the first time. The method permits straightforward functionalization... 
FLUOROARENES | COPPER-MEDIATED FLUORINATION | ACTIVATION | POLYFLUOROARENES | COMPLEXES | C(SP)-H BORYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | METAL | F-18-FLUORINATION | LATE-STAGE FLUORINATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2016, Volume 18, Issue 12, pp. 2966 - 2969
A catalytic Miyaura-type ipso-borylation of aryl sulfides with diboron reagents has been achieved, providing arylboronate esters of synthetic use. The key... 
BORONIC ACIDS | FLUOROARENES | CROSS-COUPLING REACTION | CHLORIDES | REACTIVITY | CHEMISTRY, ORGANIC | BOND FORMATION | C-S ACTIVATION | METAL | SULFUR | LITHIATION
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 03/2017, Volume 53, Issue 26, pp. 3634 - 3636
Iridium(i) carbonyl complex [Ir(2,6-(P Bu CH ) C H )(CO)] undergoes reversible C-H bond activation of benzene and a series of fluorobenzenes on UV irradiation.... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 12, pp. 1805 - 1808
The reaction of a metal complex containing a polar Fe-Mg bond with 2-(pentafluorophenyl)pyridine leads to selective C-F bond activation. A stepwise SNAr... 
ANIONS | FLUOROARENES | MG-MG | PERFLUOROCARBONS | INTERMEDIATE | BOND ACTIVATION | METAL-CARBONYL CHEMISTRY | OXIDATIVE ADDITION | C-F | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 05/2015, Volume 179, pp. 14 - 22
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 39, pp. 12763 - 12766
Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds... 
FLUOROARENES | ACTIVATION | MAGNESIUM(I) DIMERS | REAGENTS | BUILDING-BLOCKS | METAL | C-F BOND | CATALYZED BORYLATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | HYDRODEFLUORINATION | Communication
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2016, Volume 52, Issue 1, pp. 202 - 205
Nickel(II) fluorido complexes bearing NNN-pincer ligands were found to be catalysts in the hydrodefluorination of geminal difluorocyclopropanes which undergo... 
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 01/2017, Volume 15, Issue 4, pp. 787 - 789
The N-heterocyclic carbene IBioxMe enacts selective single and double C-F bond activation of octafluorotoluene and hexafluorobenzene, respectively. The... 
Journal Article
Chemistry Letters, ISSN 0366-7022, 9/2017, Volume 46, Issue 9, pp. 1315 - 1318
A two-step transformation of α,β-unsaturated carboxylic acids to alkenylboronic esters has been achieved via thioesterification of carboxylic acids followed by... 
Rhodium catalyst | Alkenylboron | Decarbonylative borylation | HALIDES | ACTIVATION | IPSO-BORYLATION | HYDROBORATIONS | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | FLUOROARENES | COUPLING REACTIONS | CARBON-DIOXIDE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 43, pp. 13342 - 13346
A copper catalytic system was established for the stereoselective hydrodefluorination of gem‐difluoroalkenes through C−F activation to synthesize various Z... 
copper | Z selectivity | hydrodefluorination | fluoroalkanes | fluorine | Z selectivity | LIMITATIONS | ACIDS | BUILDING-BLOCKS | CHEMISTRY, MULTIDISCIPLINARY | INACTIVATION | FLUOROARENES | Zselectivity | OLEFINATION | POLYFLUOROARENES | DERIVATIVES | BORYLATION | Fluorides | Ketones | Copper | Aldehydes | Hydrogen | Carbonyl compounds | Complex compounds | Fluorine | Catalysis | Chemical synthesis | Aliphatic compounds | Carbonyls
Journal Article
Synlett, ISSN 0936-5214, 10/2010, Volume 2010, Issue 17, pp. 2601 - 2606
Abstract Catalytic S N Ar reaction of fluoroarenes possessing no electron-withdrawing group(s) with cyclic amines was achieved using a readily accessible Ru... 
letter | fluoroarenes | amines | ruthenium | catalysis | Ar reaction
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 04/2019, Volume 21, Issue 7, pp. 2482 - 2487
Palladium catalyzed hydrodefluorination was developed for fine-tuning the properties of fluoro-(hetero)aromatic compounds. The robust reaction can be set up in... 
MEDICINAL CHEMISTRY | FLUOROARENES | FACILE ACCESS | HYDROGEN-TRANSFER | FLUORINE SCAN | ELECTROCHEMICAL HYDRODEFLUORINATION | ARYL HALIDES | CHEMISTRY, ORGANIC | C-F | F BOND ACTIVATION | NUCLEOPHILIC AROMATIC-SUBSTITUTION
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 10/2017, Volume 56, Issue 42, pp. 13006 - 13010
A practical method for radiofluorination of anilines with [ 18 F]fluoride via N -arylsydnone intermediates is described. These precursors are stable, easy to... 
click chemistry | fluorine-18 | sydnone | fluoroarene | peptide radiolabeling
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 31, pp. 9075 - 9078
An ortho‐selective CF bond borylation between N‐heterocycle‐substituted polyfluoroarenes and Bpin‐Bpin with simple and commercially available [Rh(cod)2]BF4 as... 
fluoroarenes | homogeneous catalysis | CF activation | borylation | rhodium | C-F activation | IRIDIUM | COMPLEXES | ARYLATION | ARENES | FLUOROPYRIDINES | CHEMISTRY, MULTIDISCIPLINARY | H ACTIVATION | HYDRODEFLUORINATION | FUNCTIONALIZATION | CARBON-FLUORINE BONDS | ALKANES | Hydrides | Synthesis | Catalysis | Catalysts | Bonding
Journal Article
Chemistry Letters, ISSN 0366-7022, 1/2018, Volume 47, Issue 1, pp. 85 - 88
An efficient ipso-thiolation of arylboronic acid esters with thiosulfonates has been achieved under mild and odorless conditions using a copper catalyst. The... 
Aryl sulfide | Arylboronic acid ester | Thiosulfonate | SULFIDES | BOND FORMATION | THIOESTERS | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | FLUOROARENES | DECARBONYLATIVE BORYLATION | AMINATION | ARYL | C-H BORYLATION | CARBOXYLIC-ACIDS
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 12/2015, Volume 44, Issue 45, pp. 19597 - 19605
The room temperature reaction of C6F6 or C6F5H with [Ru(IEt2Me2)2(PPh3)2H2] (; IEt2Me2 = 1,3-diethyl-4,5-dimethylimidazol-2-ylidene) generated a mixture of the... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16191 - 16196
Journal Article
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