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The FEBS Journal, ISSN 1742-464X, 12/2012, Volume 279, Issue 23, pp. 4269 - 4282
Journal Article
Journal Article
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2009, Volume 131, Issue 13, pp. 4872 - 4879
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 06/2019, Volume 9, Issue 6, pp. 4930 - 4943
Biosynthetic enzyme complexes selectively catalyze challenging chemical transformations, including alkane functionalization (e.g., halogenation of threonine,... 
halogenases | DIOXYGEN ACTIVATION | MOLECULAR-DYNAMICS | CRYSTAL-STRUCTURE | QUANTUM MECHANICS/MOLECULAR MECHANICS | CHEMISTRY, PHYSICAL | non-heme iron | ALPHA-KETOGLUTARATE | ALIPHATIC HALOGENASE | QM/MM | natural product biosynthesis | hydrogen bonding | substrate specificity | IRON HALOGENASE SYRB2 | NONHEME FE(II) | C-H | CATALYTIC CYCLE
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2017, Volume 56, Issue 21, pp. 13382 - 13389
The iron­(II)- and 2-(oxo)­glutarate-dependent (Fe/2OG) oxygenases catalyze an array of challenging transformations via a common iron­(IV)-oxo (ferryl)... 
OXYGEN ACTIVATION | OXIDATIVE DEMETHYLATION | CRYSTAL-STRUCTURE | ESCHERICHIA-COLI | ALIPHATIC HALOGENASE | TAURINE/ALPHA-KETOGLUTARATE DIOXYGENASE | TAUD | CATALYTIC MECHANISM | SPIN FE(IV) COMPLEX | HIF-ALPHA | CHEMISTRY, INORGANIC & NUCLEAR | Chemical bonds | Enzymes | Chemical reactions | Transition metals | Research | Analysis
Journal Article
Journal Article
JBIC Journal of Biological Inorganic Chemistry, ISSN 0949-8257, 4/2017, Volume 22, Issue 2, pp. 367 - 379
A wide range of spectroscopic approaches have been used to interrogate the mononuclear iron metallocenter in 2-oxoglutarate (2OG)-dependent oxygenases. The... 
Life Sciences | Biochemistry, general | Oxygenase | Spectroscopy | Microbiology | 2-Oxoglutarate | Nonheme iron | RESONANCE VIBRATIONAL SPECTROSCOPY | HEME-LINKED IONIZATION | FERROUS ACTIVE-SITE | BIOCHEMISTRY & MOLECULAR BIOLOGY | ESCHERICHIA-COLI | ALPHA-KETOGLUTARATE | TAURINE/ALPHA-KETOGLUTARATE DIOXYGENASE | SPIN FE(IV) COMPLEX |