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1. Catalytic asymmetric Friedel-Crafts alkylations
by Bandini, Marco and Umani-Ronchi, Achille
2009, 1. Aufl., ISBN 3527626980, xvi, 301
This first comprehensive overview of this important synthetic reaction covers the whole spectrum of this modern and rapidly developing field. Clearly... 
Friedel-Crafts reaction | Chemistry, Organic
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2. Full Text Transition-Metal-Catalyzed C–H Alkylation Using Alkenes
by Dong, Zhe and Ren, Zhi and Thompson, Samuel J and Xu, Yan and Dong, Guangbin
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9333 - 9403
Alkylation reactions represent an important organic transformation to form C–C bonds. In addition to conventional approaches with alkyl halides or sulfonates... 
ACTIVATED METHYLENE-COMPOUNDS | C(SP)-H ALPHA-ALKYLATION | BRANCHED-SELECTIVE HYDROARYLATION | NICKEL/LEWIS ACID CATALYSIS | CARBON-HYDROGEN BONDS | BETA-KETO-ESTERS | STEP-GROWTH COPOLYMERIZATION | FRIEDEL-CRAFTS ALKYLATION | ANTI-MARKOVNIKOV HYDROARYLATION | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC INTERMOLECULAR HYDROARYLATION
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3. Full Text Chiral N,N′‐Dioxide–Scandium(III) Complex‐Catalyzed Asymmetric Friedel–Crafts Alkylation Reaction of ortho‐Hydroxybenzyl Alcohols with C3‐Substituted N‐Protected Indoles
by Zheng, Jianfeng and Lin, Lili and Dai, Li and Yuan, Xiao and Liu, Xiaohua and Feng, Xiaoming
Chemistry – A European Journal, ISSN 0947-6539, 12/2016, Volume 22, Issue 50, pp. 18254 - 18258
The first Lewis acid catalyzed asymmetric Friedel–Crafts alkylation reaction of ortho‐hydroxybenzyl alcohols with C3‐substituted indoles is described. A chiral... 
ortho-quinone methides | Friedel–Crafts alkylation | indole | asymmetric catalysis | diarylindol-2-ylmethanes | HIGHLY ENANTIOSELECTIVE SYNTHESIS | ORGANIC-SYNTHESIS | TRIARYLMETHANES | Friedel-Crafts alkylation | CHEMISTRY, MULTIDISCIPLINARY | CYCLOADDITIONS | MALONONITRILE | DIELS-ALDER REACTION | BRONSTED ACID CATALYSIS | IN-SITU | CONJUGATE ADDITION | Alcohol
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4. Full Text Palladium‐Catalyzed Direct CH Alkylation of Electron‐Deficient Pyrrole Derivatives
by Jiao, Lei and Bach, Thorsten
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2013, Volume 52, Issue 23, pp. 6080 - 6083
The apparent and the real: What looks like a Friedel–Crafts alkylation reaction of electron‐deficient pyrroles is actually a PdII‐catalyzed,... 
alkylation | CH activation | palladium | homogeneous catalysis | heterocycles | C-H activation | 1,3-DICARBONYL COMPOUNDS | ALPHA,BETA-UNSATURATED ALDEHYDES | BOND FUNCTIONALIZATION | PYRRYLMAGNESIUM BROMIDE | ALKENE-PHOSPHINE LIGANDS | AROMATIC-SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | CH activation | ASYMMETRIC ALLYLIC ALKYLATION | FRIEDEL-CRAFTS ALKYLATION | RADICAL ALKYLATION | FUNCTIONALIZED PYRROLES | Activation | Derivatives | Alkylation | Pyrroles
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5. Full Text A Novel Sc(OTf)3‐Catalyzed (2+2+1)‐Cycloannulation/Aza‐Friedel–Crafts Alkylation Sequence toward Multicyclic 2‐Pyrrolines
by Schlegel, Marcel and Coburger, Peter and Schneider, Christoph
Chemistry – A European Journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 53, pp. 14207 - 14212
The rapid assembly of molecular complexity continues to be at the forefront of novel reaction development. In the pursuit of that goal, we herein report a... 
1-azaallyl cations | multicomponent reactions | tertiary alcohols | aza-Friedel–Crafts reaction | Lewis acid catalysis | Amines | Quaternary | Pyrroles | Cations | Indoles | Nucleophiles | Alkylation | Complexity
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6. Full Text Enantioselective Construction of Cyclic Indolyl α‐Amino Esters via a Friedel–Crafts Alkylation Reaction
by Wu, Liang and Liu, Ren‐Rong and Zhang, Guoqi and Wang, Dan‐Jie and Wu, Hao and Gao, Jianrong and Jia, Yi‐Xia
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2015, Volume 357, Issue 4, pp. 709 - 713
An enantioselective Friedel–Crafts alkylation reaction of indoles with cyclic N‐sulfonyl ketimino esters was developed. Under the optimized conditions using a... 
Friedel–Crafts reaction | copper | indoles | ketimino esters | asymmetric catalysis | Indoles | Copper | Asymmetric catalysis | Ketimino esters | Friedel-Crafts reaction | IMINO ESTERS | ASYMMETRIC-SYNTHESIS | CHEMISTRY, ORGANIC | N-SULFONYL KETIMINES | PIPECOLIC ACID | MANNICH REACTIONS | CARBON STEREOCENTERS | ZINC/BINOL-CATALYZED ALKYNYLATION | RECENT PROGRESS | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, APPLIED | DERIVATIVES | Synthesis | Asymmetry | Pyrroles | Esters | Transformations | Derivatives | Alkylation | Bearing
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7. Full Text Enantioselective Friedel–Crafts Alkylation Reactions of β‐Naphthols with Donor–Acceptor Aminocyclopropanes
by Zhu, Man and Wang, Dong‐Chao and Xie, Ming‐Sheng and Qu, Gui‐Rong and Guo, Hai‐Ming
Chemistry – A European Journal, ISSN 0947-6539, 10/2018, Volume 24, Issue 58, pp. 15512 - 15516
The enantioselective Friedel–Crafts alkylation reaction of β‐naphthols with donor–acceptor aminocyclopropane was developed. In the presence of a copper complex... 
enantioselectivity | aminocyclopropane | Friedel–Crafts alkylation | asymmetric catalysis | beta-naphthol | BRONSTED ACID | ASYMMETRIC-SYNTHESIS | ANNULATION | DA-CYCLOPROPANES | RING-OPENING-CYCLIZATION | Friedel-Crafts alkylation | CHEMISTRY, MULTIDISCIPLINARY | ACID-CATALYZED-REACTIONS | 3+2 DIPOLAR CYCLOADDITION | ACTIVATED CYCLOPROPANES | AROMATIC AZOMETHINE IMINES | DERIVATIVES | Cyclopropane | Copper compounds | Catalysis | Crafts | Enantiomers | Copper | Coordination compounds | Alkylation | Oxazine
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8. Full Text 3‐Mono‐Substituted BINOL Phosphoric Acids as Effective Organocatalysts in Direct Enantioselective Friedel–Crafts‐Type Alkylation of N‐Unprotected α‐Ketiminoester
by Yonesaki, Ryohei and Kondo, Yuta and Akkad, Walaa and Sawa, Masanao and Morisaki, Kazuhiro and Morimoto, Hiroyuki and Ohshima, Takashi
Chemistry – A European Journal, ISSN 0947-6539, 10/2018, Volume 24, Issue 57, pp. 15211 - 15214
Although BINOL‐derived phosphoric acids are among the most widely used chiral Brønsted acid organocatalysts, their structures are mostly limited to... 
Friedel–Crafts-type alkylation | asymmetric catalysis | N-unprotected ketimines | chiral phosphoric acids | amino acids | AROMATIC KETIMINES | DIRECT ACCESS | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | 3+2 ANNULATION | Friedel-Crafts-type alkylation | TRIFLUOROMETHYL KETIMINES | CHIRAL BRONSTED ACID | METAL CATALYSIS | DERIVATIVES | INSIGHTS | Substitutes | Crafts | Acids | Enantiomers | Alkylation
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9. Full Text Mechanochemical Friedel–Crafts Alkylation—A Sustainable Pathway Towards Porous Organic Polymers
by Troschke, Erik and Grätz, Sven and Lübken, Tilo and Borchardt, Lars
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 24, pp. 6859 - 6863
This study elucidates an innovative mechanochemical approach applying Friedel–Crafts alkylation to synthesize porous covalent triazine frameworks (CTFs).... 
polymerization | covalent triazine frameworks | mechanochemistry | porous polymers | microporous materials | SURFACE-AREA | COVALENT | NETWORKS | CHEMISTRY, MULTIDISCIPLINARY | TRIAZINE-BASED FRAMEWORKS | FACILE SYNTHESIS | TEMPERATURE | LITHIUM-SULFUR BATTERIES | CAPTURE | Sustainable agriculture | Analysis | Polymerization | Nuclear magnetic resonance spectroscopy | Polymer industry | Porosity | Polymers | Spectroscopy | Infrared spectroscopy | Nuclear magnetic resonance--NMR | Carbazole | Alkylation | Monomers | Magnetic resonance spectroscopy | Chloride | Temperature effects | Spectrum analysis | Triazine
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10. Full Text Palladium‐Catalyzed para‐Selective Alkylation of Electron‐Deficient Arenes
by Jiao, Zhiwei and Lim, Li Hui and Hirao, Hajime and Zhou, Jianrong Steve
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 21, pp. 6294 - 6298
Intermolecular alkylations of electron‐deficient arenes proceed with good para selectivity. Palladium catalysts were used to generate nucleophilic alkyl... 
palladium catalysis | alkyl radicals | alkylation | arenes | synthetic methods | HALIDES | C-H ALKYLATION | ROOM-TEMPERATURE | SECONDARY | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | IODIDES | EPHA2 RECEPTOR | COOPERATIVE NICKEL/ALUMINUM CATALYSIS | HECK-TYPE REACTIONS | RADICAL REACTIONS | Palladium catalysts | Palladium | Catalysis | Catalysts | Halides | Aromatic compounds | Alkylation | Electrons
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11. Full Text Controlling the C(sp3)–C(sp2) Axial Conformation in the Enantioselective Friedel–Crafts-Type Alkylation of β‑Naphthols with Inden-1-ones
by Di Iorio, Nicola and Filippini, Giacomo and Mazzanti, Andrea and Righi, Paolo and Bencivenni, Giorgio
Organic Letters, ISSN 1523-7060, 12/2017, Volume 19, Issue 24, pp. 6692 - 6695
The Friedel–Crafts-type reaction between properly functionalized inden-1-ones and 2-naphthols generates a hindered single bond which displays a unique... 
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12. Full Text Synthesis of Indolo[1,2‐b]isoquinoline Derivatives by Lewis Acid‐Catalyzed Intramolecular Friedel–Crafts Alkylation Reaction
by Gour, Jitendra and Gatadi, Srikanth and Nagarsenkar, Atulya and Babu, Bathini Nagendra and Madhavi, Y. V and Nanduri, Srinivas
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2018, Volume 2018, Issue 22, pp. 2817 - 2821
A methodology for the synthesis of indolo[1,2‐b]isoquinoline derivatives by Lewis acid‐catalyzed intramolecular Friedel–Crafts alkylation reaction has been... 
Friedel–Crafts reaction | Synthetic methods | Nitrogen heterocycles | Cyclization | Polycycles | CHEMISTRY, ORGANIC | 2-INDOLYLMETHANOLS | ALCOHOLS | RECEPTOR-BINDING AFFINITIES | POTENT | INDOLE | CONSTRUCTION | CHEMISTRY | SCAFFOLDS | Friedel-Crafts reaction | ACCESS | ALKALOIDS | Alkaloids
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13. Full Text P -Selective (sp2)-C-H functionalization for an acylation/alkylation reaction using organic photoredox catalysis
by Pandey, Ganesh and Tiwari, Sandip Kumar and Singh, Bhawana and Vanka, Kumar and Jain, Shailja
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 91, pp. 12337 - 12340
p-Selective (sp(2))-C-H functionalization of electron rich arenes has been achieved for acylation and alkylation reactions, respectively, with... 
FRIEDEL-CRAFTS ACYLATION | C-H BOND | COUPLING REACTIONS | CARBON-MONOXIDE | REDUCTIVE ACTIVATION | ARYL | CARBONYLATIVE CYCLIZATION | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-TRANSFER PET | ALKYL-HALIDES | Catalysis | Aromatic compounds | Alkylation | Acylation
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14. Full Text Brønsted acid ionic liquid-catalyzed reductive Friedel-Crafts alkylation of indoles and cyclic ketones without using an external reductant
by Taheri, Amir and Lai, Bingbing and Cheng, Cheng and Gu, Yanlong
Green Chemistry, ISSN 1463-9262, 02/2015, Volume 17, Issue 2, pp. 812 - 816
In the absence of an external reductant, C3-cycloalkylated indole could be synthesized through reductive alkylation of indole with cyclic ketone using a... 
ALCOHOLS | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | DELEOBUVIR | BENZIMIDAZOLE | HCV | CHEMISTRY, MULTIDISCIPLINARY | VIRUS NS5B POLYMERASE | ALLOSTERIC INHIBITORS | DISCOVERY
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