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gem-silylborylation (12) 12
chemistry, multidisciplinary (8) 8
boron (5) 5
heteroatom bonds (5) 5
stereoselective-synthesis (5) 5
alkenes (3) 3
carbenoids (3) 3
chemistry, organic (3) 3
cross-coupling reaction (3) 3
organic-synthesis (3) 3
platinum complexes (3) 3
reagents (3) 3
silicon (3) 3
terminal alkynes (3) 3
alkene (2) 2
alkyl-halides (2) 2
asymmetric silaboration (2) 2
bor (2) 2
boronic esters (2) 2
c bond-cleavage (2) 2
carbenoid (2) 2
carbon (2) 2
carbonyl-compounds (2) 2
catalyzed regioselective silaboration (2) 2
chemistry, inorganic & nuclear (2) 2
cross-coupling reactions (2) 2
diastereoselective synthesis (2) 2
diastereoselectivity (2) 2
diborylation (2) 2
insertion (2) 2
ketones (2) 2
reactivity (2) 2
silylboranes (2) 2
stereoselectivity (2) 2
-tamoxifen (1) 1
1,1-diboronate esters (1) 1
1,2-migration (1) 1
access (1) 1
acrylamid (1) 1
acrylamides (1) 1
aldehydes (1) 1
alkane (1) 1
alkanes (1) 1
allylation (1) 1
allylic substitution (1) 1
aromatic compounds (1) 1
arylation (1) 1
arylboronic acids (1) 1
asymmetric catalysis (1) 1
asymmetric conjugate addition (1) 1
asymmetric synthesis (1) 1
asymmetric-catalysis (1) 1
asymmetric-synthesis (1) 1
asymmetrische katalyse (1) 1
attraction (1) 1
b bond (1) 1
bidirectional asymmetric allylboration (1) 1
bisabolane sesquiterpenes (1) 1
bond formation (1) 1
boranes (1) 1
boron - chemistry (1) 1
boron bonds (1) 1
borylation (1) 1
carbanions (1) 1
catalyzed cis-silaboration (1) 1
catalyzed enantioselective diboration (1) 1
chemical synthesis (1) 1
chemistry (1) 1
chemoselectivity (1) 1
chemoselektivität (1) 1
chiral-compounds (1) 1
chirale verbindung (1) 1
cobalt (1) 1
conjugate additions (1) 1
cross coupling (1) 1
dehydrogenative borylation (1) 1
deprotonation (1) 1
diboronates (1) 1
diborylalkanes (1) 1
dimetalated reagents (1) 1
diols (1) 1
domino reactions (1) 1
efficient (1) 1
enantio-selectivity (1) 1
enantiomers (1) 1
enantioselective synthesis (1) 1
enantioselektivität (1) 1
epoxides (1) 1
esters (1) 1
fcsnbu3 (1) 1
fluoro olefins (1) 1
functionalisation (1) 1
funktionalisierung (1) 1
gem -silylborylation (1) 1
geminal diborylalkanes (1) 1
generation (1) 1
grignard reagents (1) 1
halomethane (1) 1
homoallylboronates (1) 1
homogene katalyse (1) 1
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Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 13, pp. 3498 - 3501
We report a transition-metal-free coupling of aldehydes and ketones with geminal bis­(boron) building blocks which provides the coupled, homologated carbonyl... 
HYDROXYL BORONIC ESTERS | ASYMMETRIC-SYNTHESIS | DIASTEREOSELECTIVE SYNTHESIS | DEHYDROGENATIVE BORYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | GEM-SILYLBORYLATION | STEREOSELECTIVE-SYNTHESIS | ALLYLIC SUBSTITUTION | ARYLBORONIC ACIDS | ALKYL-HALIDES
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 1/2009, Volume 82, Issue 1, pp. 29 - 49
New reactivities of silylboranes are described with their applications to organic synthesis. The silylboranes add to unsaturated organic compounds such as... 
ORGANOBORON COMPOUNDS | C BOND-CLEAVAGE | TRANSITION-METAL-COMPLEXES | ASYMMETRIC SILABORATION | HETEROATOM BONDS | GEM-SILYLBORYLATION | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED REGIOSELECTIVE SILABORATION | PLATINUM COMPLEXES | INTRAMOLECULAR BIS-SILYLATION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2016, Volume 22, Issue 52, pp. 18737 - 18741
An easy access to highly versatile gem‐silylboronate synthons is achieved by means of a new olefination reagent, HC(Bpin)2(SiMe3). Subsequent silicon or... 
insertion | alkenes | gem-silylborylation | tamoxifen | iododesilylation | CARBENOIDS | REAGENTS | MECHANISM | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | (Z)-TAMOXIFEN | SILYLBORANES | STEREOSELECTIVE-SYNTHESIS | EFFICIENT | Olefins | Attraction | Cross coupling | Boron | Synthesis | Ketones | Alkenes | Reagents
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 34, pp. 8013 - 8017
Vinyl epoxides and styrene oxide can react with diborylmethide lithium salts through an exclusive SN2 borylmethylation/ring opening in a regio‐ and... 
SN2 mechanism | homoallylboronates | geminal diborylalkanes | diboronates | lithium salts | DEPROTONATION | INSERTION | GEM-SILYLBORYLATION | CARBANIONS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | KETONES | S(N)2 mechanism | ESTERS | DIBORYLALKANES | ACCESS | Stereoselectivity | Salts | Styrene | Lithium | Epoxides | Ring opening | Substrates | Diols
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 10/2018, Volume 57, Issue 40, pp. 13293 - 13297
An intramolecular 1,2-boryl-anion migration from boron to carbon has been achieved by selective activation of the system in [(vinyl)B(2)Pin(2))](-) using soft... 
boranes | B BOND | ORGANIC-SYNTHESIS | borylation | Lewis acids | DIBORYLATION | REACTIVITY | Grignard reagents | BOND FORMATION | TERMINAL ALKYNES | GEM-SILYLBORYLATION | N-HETEROCYCLIC CARBENES | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE DIBORATION | CONJUGATE ADDITIONS | 1,2-migration
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2018, Volume 57, Issue 39, pp. 12935 - 12939
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2017, Volume 23, Issue 61, pp. 15534 - 15537
A facile method for the preparation of β‐boryl‐α‐silyl aryl acrylamides using phenyllithium, dimethylphenylsilylpinacolborane, and propargylamides is reported.... 
chemoselectivity | silicon | diastereoselectivity | boron | synthetic methods | PALLADIUM | CARBON | CATALYZED CIS-SILABORATION | REGIOSELECTIVE SILABORATION | TERMINAL ALKYNES | GEM-SILYLBORYLATION | CHEMISTRY, MULTIDISCIPLINARY | PLATINUM COMPLEXES | ALKENES | CROSS-COUPLING REACTIONS | SILYLBORANES | Stereoselectivity | Lewis base | Aromatic compounds
Journal Article
Organometallics, ISSN 0276-7333, 02/2007, Volume 26, Issue 5, pp. 1291 - 1294
New silylpinacolboranes bearing chloro, fluoro, alkoxy, and dialkylamino groups on silicon were synthesized in high yields via derivatization of... 
C BOND-CLEAVAGE | NICKEL-COMPLEXES | BORON BONDS | ASYMMETRIC SILABORATION | HETEROATOM BONDS | CHEMISTRY, ORGANIC | METAL EXCHANGE-REACTION | GEM-SILYLBORYLATION | STEREOSELECTIVE-SYNTHESIS | CATALYZED REGIOSELECTIVE SILABORATION | PLATINUM COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry Letters, ISSN 0366-7022, 8/2006, Volume 35, Issue 8, pp. 838 - 839
(Z)-1,2,3,4-Tetraboryl-2-butene reacted with three molecules of 2,3-dialkylidene-1,5-alkanediol as a single stereoisomer. Preparation and triple addition of... 
ORGANIC-SYNTHESIS | CARBENOIDS | CARBON | CROSS-COUPLING REACTION | METALS | SILICON | HETEROATOM BONDS | REACTIVITY | GEM-SILYLBORYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Proceedings of the Japan Academy, Series B, ISSN 0386-2208, 2008, Volume 84, Issue 3, pp. 75 - 85
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2007, Volume 2, Issue 9, pp. 1142 - 1149
Treatment of (Z)‐1,2,3,4‐tetrakis(pinacolatoboryl)but‐2‐ene, prepared from 2,3‐bis(pinacolatoboryl)buta‐1,3‐diene and bis(pinacolato)diboron, with three molar... 
diastereoselectivity | domino reactions | allylation | boron | synthesis design | Domino reactions | Boron | Synthesis design | Diastereoselectivity | Allylation | ORGANIC-SYNTHESIS | REAGENTS | CROSS-COUPLING REACTION | ENANTIOSELECTIVE SYNTHESIS | ONE-POT SYNTHESIS | METAL-CATALYZED ADDITIONS | GEM-SILYLBORYLATION | CHEMISTRY, MULTIDISCIPLINARY | HETEROATOM BONDS | BIDIRECTIONAL ASYMMETRIC ALLYLBORATION
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2003, Volume 686, Issue 1, pp. 286 - 293
gem-Silylborylation of halomethyllithiums with silylboranes allows us to prepare boryl(silyl)methanes substituted by such heteroatoms as Cl, Br, I, O, S, Si,... 
Boron | Tetrametalmethane | Silylborane | gem-Silylborylation | Silicon | Halomethane | Carbenoid | halomethane | FLUORO OLEFINS | REAGENTS | CARBENOIDS | TETRAMETALLOMETHANES | gem -silylborylation | CHEMISTRY, ORGANIC | silylborane | BORONIC ESTERS | STEREOSELECTIVE SYNTHESIS | FC(SIME3)SNBU3 | CHEMISTRY, INORGANIC & NUCLEAR | silicon | tetrametalmethane | CHEMISTRY | GENERATION | boron | carbenoid | METHANETRIBORONIC ESTERS
Journal Article
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