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Chemistry – A European Journal, ISSN 0947-6539, 09/2016, Volume 22, Issue 39, pp. 13946 - 13952
The addition of Sn and Zn ions to [Ge9] clusters by reaction of [Ge9]4− with SnPh2Cl2, ZnCp*2 (Cp*=pentamethylcyclopentadienyl), or Zn2[HC(Ph2P=NPh)2]2 is... 
tin | germanium | metal–metal interactions | zinc | Zintl anions | Atoms & subatomic particles | Electrons | Orbitals | Molecular structure | Metals | Fragments | Ions | Zinc | Fragmentation | Covalence | Bridging | Bonding strength | Clusters | Chemical bonds | Atomic structure | Symmetry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 34, pp. 11933 - 11940
Reactions of silylated clusters [Ge9{Si­(TMS)3}3]− or [Ge9{Si­(TMS)3}2]2− with dialkylhalophosphines R2PCl (Cy, i Pr, t Bu) at ambient temperature yield the... 
N-HETEROCYCLIC CARBENE | GERMANIUM CLUSTERS | INSERTION | CHEMICAL-BOND | CHEMISTRY | I COMPLEXES | IONS | COORDINATION | ATOMS | BASIS-SETS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2017, Volume 2017, Issue 4, pp. 805 - 810
The synthesis and characterization of the metalloid germanium clusters {Ge9[Si(SiMe3)2(SiPh3)]2}2– (1), {Ge9[Si(SiMe3)3][Si(SiMe3)2(SiPh3)]2}– (2),... 
Si ligands | Germanium | Metalloid clusters | Cluster compounds | Zintl anions | ELEMENTS | GERMANIUM CLUSTERS | CHEMISTRY | IONS | ZINTL CLUSTERS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Physical chemistry chemical physics : PCCP, ISSN 1463-9076, 07/2016, Volume 18, Issue 30, pp. 20321 - 20329
Gold-doped germanium clusters, AuGen(-) (n = 2-12), were investigated by using anion photoelectron spectroscopy in combination with ab initio calculations.... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2009, Volume 131, Issue 43, pp. 15588 - 15589
Through the use of bis(carboxyethylgermanium) sesquioxide as the germanium source, lanthanide has been successfully introduced into germanate systems under... 
12-RING CHANNELS | 24-RING CHANNELS | CHEMISTRY, MULTIDISCIPLINARY | METAL-COMPLEXES | Thermal properties | Rare earth metals | Neodymium | Organometallic compounds | Germanium | Chemical properties | Structure
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 08/2017, Volume 56, Issue 16, pp. 9693 - 9697
The reaction of [(Hyp)2Ge9]2– (Hyp = Si­(SiMe3)3) with ClSiMe2-C6H4-SiMe2Cl gives [K­(THF)]­[(Hyp)2Ge9-SiMe2-C6H4-SiMe2-Ge9(Hyp)2K] K1 in 45% yield in the form... 
ENERGY | GERMANIUM | APPROXIMATION | POPULATION ANALYSIS | OCCUPATION NUMBERS | BASIS-SETS | ZINTL CLUSTERS | ATOM | CHEMISTRY, INORGANIC & NUCLEAR | Silicon compounds | Ligands | Clusters (Chemistry) | Research | Chemical properties
Journal Article
Structure and Bonding, ISSN 0081-5993, 03/2017, Volume 174, pp. 135 - 200
Metalloid cluster compounds of the general formulae MnRm (n>m; M=metal like Al, Au, Sn, etc.; R=ligand like S-C6H4-COOH, N(SiMe3)(2), etc.) represent a novel... 
Nanoscale | Tin | Germanium | Gallium | Metal | Aluminum | GERMANIUM CLUSTERS | HIGH-PRESSURE | GALLIUM CLUSTERS | CRYSTAL-STRUCTURE | CHEMISTRY, PHYSICAL | X-RAY-DIFFRACTION | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, INORGANIC & NUCLEAR | TIN CLUSTER | DELTAHEDRAL ZINTL IONS | FREE GERMYL CATION | ORGANOMETALLIC CHEMISTRY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 67, pp. 17089 - 17094
We report on the synthesis and structure, as well as on the mechanism of formation of the [Ge9−CH=CH−CH=CH−Ge9]6− unit. As shown by in situ NMR spectroscopy... 
germanium | Raman spectroscopy | Zintl triads | crystal structures | buta-1,3-dien-1,4-diyl | Nuclear magnetic resonance spectroscopy | Structure | Analysis | Ethylenediamines | Crystals | Magnetic resonance spectroscopy | Single crystals | Ethylenediamine | Salts | Synthesis | Nuclear magnetic resonance--NMR | Toluene | Spectrum analysis | NMR spectroscopy | Structural analysis
Journal Article
The Journal of Chemical Physics, ISSN 0021-9606, 12/2017, Volume 147, Issue 23, p. 234310
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2009, Volume 131, Issue 9, pp. 3396 - 3404
We report a joint experimental and theoretical study on the structures of a series of gold clusters doped with a group-14 atom: MAux- (M = Si, Ge, Sn; x =... 
NANOCLUSTERS | PSEUDOPOTENTIALS | TRANSITION-METAL CLUSTERS | CAGE | APPROXIMATION | SILICON CLUSTERS | CHEMISTRY | LOW-SYMMETRY STRUCTURES | CHEMISTRY, MULTIDISCIPLINARY | PHOTOELECTRON-SPECTROSCOPY | GOLD | GERMANIUM | MOLECULAR CLUSTERS | SILICON | TIN | ISOMERS | Environmental Molecular Sciences Laboratory | CRYSTAL STRUCTURE | MATERIALS SCIENCE | DOPED MATERIALS | MORPHOLOGICAL CHANGES
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2016, Volume 18, Issue 30, pp. 20321 - 20329
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2019, Volume 25, Issue 19, pp. 4914 - 4919
Journal Article
Journal of Physical Chemistry C, ISSN 1932-7447, 03/2017, Volume 121, Issue 12, pp. 7037 - 7046
We present a joint experimental and theoretical study on double iron atom doped germanium clusters, Fe2Gen-\0 (n = 3-12). The experimental photoelectron... 
TRANSITION | GEOMETRIES | GERMANIUM CLUSTERS | STATES | EVOLUTION | STABILITY | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | BINDING-ENERGIES | GE-N | GENETIC ALGORITHM
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2017, Volume 56, Issue 17, pp. 10361 - 10369
Journal Article
Journal of Computational Chemistry, ISSN 0192-8651, 09/2018, Volume 39, Issue 25, pp. 2103 - 2109
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 9, pp. 3216 - 3219
The oxidation of [Ge9(Hyp)3]− (Hyp=Si(SiMe3)3) with an FeII salt leads to Ge18(Hyp)6 (1), the largest Group 14 metalloid cluster that has been structurally... 
quantum-chemical calculations | clathrates | metalloid clusters | germanium | solid-state structures | Clathrate compounds
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 09/2017, Volume 121, Issue 37, pp. 6949 - 6956
The global minima of both neutral and anionic clusters of VGe3 –/0 were determined using different quantum chemical methods (DFT, RCCSD­(T), CASSCF/CASPT2). On... 
TRANSITION | STATES | GERMANIUM | APPROXIMATION | DENSITY-FUNCTIONAL CALCULATIONS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | ATOMS | BASIS-SETS | KINETIC-ENERGY SPECTROSCOPY
Journal Article