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Journal of the American Chemical Society, ISSN 0002-7863, 01/2013, Volume 135, Issue 2, pp. 624 - 627
The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst... 
CROSS-COUPLING REACTIONS | COMPLEX | ALLYLATION | ALLYLIC GRIGNARD-REAGENTS | BROMIDES | ELECTROPHILES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Synthesis, ISSN 0039-7881, 01/2017, Volume 49, Issue 1, pp. 188 - 194
Abstract An efficient protocol for chromium(III)-catalyzed C(sp 2 )–C(sp 3 ) cross-coupling is reported. The alkylations of halo-quinoline and phenacyl... 
paper | cross-coupling | Grignard reagents | magnesium | chromium | quinolines | ORGANIC-SYNTHESIS | IODIDES | ALKYL | CHEMISTRY, ORGANIC | GRIGNARD-REAGENTS
Journal Article
Chemical Society reviews, ISSN 1460-4744, 2014, Volume 43, Issue 23, pp. 8081 - 8097
This review highlights the prospective impact of simple ethers as aryl halide surrogates in the cross-coupling arena C–O bond-activation. In 1979, the seminal... 
ORGANOBORON COMPOUNDS | ARYL GRIGNARD-REAGENTS | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | CARBON-OXYGEN BONDS | REDUCTIVE CLEAVAGE | METHYL ETHERS | N-HETEROCYCLIC CARBENES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | PHENOL DERIVATIVES
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 23, pp. 6921 - 6925
Although iron‐catalyzed cross‐coupling of Grignard reagents with alkyl halides has been well established, the adoption of the reaction for fluoroalkylations... 
cross-coupling | ligand design | Grignard reagents | iron | fluoroalkylation | ORGANIC-SYNTHESIS | PALLADIUM | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | ARYL BORONIC ACIDS | NICKEL | CHLORIDES | FLUORINE | INHIBITORS | GRIGNARD-REAGENTS | TRIFLUOROMETHYLATION | Cytokinins | Usage | Catalysis | Chemical tests and reagents | Butylene | Halides | Reagents | Bromides | Chemical reactions | Ligands | Iron | Coupling | Defluorination | Ethane
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2018, Volume 140, Issue 13, pp. 4503 - 4507
Journal Article
Nature (London), ISSN 1476-4687, 2014, Volume 509, Issue 7500, pp. 299 - 309
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 37, pp. 11188 - 11192
Treatment of readily available enynes with alkyl‐Grignard reagents in the presence of catalytic amounts of Fe(acac)3 engenders a remarkably facile and... 
1,3-dienes | cross-coupling | Grignard reagents | iron catalysis | enynes | cycloisomerization | 1,6-ENYNES | COMPLEXES | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | CARBOCYCLIZATIONS | ALKYL-HALIDES | CYCLOADDITION | ARYL | REDUCTIVE CYCLIZATION | GRIGNARD-REAGENTS | DIYNES | Chemical tests and reagents
Journal Article
Nature communications, ISSN 2041-1723, 2016, Volume 7, Issue 1, p. 11129
New carbon-carbon bond formation reactions expand our horizon of retrosynthetic analysis for the synthesis of complex organic molecules. Although many methods... 
ALKENES | CROSS-COUPLING REACTIONS | MULTIDISCIPLINARY SCIENCES | ARYL HALIDES | INTERNAL OLEFINS | HYDROAMINATION | ALKYLBORONIC ESTERS | GRIGNARD-REAGENTS | HYDROHYDRAZINATION | BORYLATION | ALKYL-HALIDES
Journal Article
by Gu, J and Wang, X and Xue, WC and Gong, HG
ORGANIC CHEMISTRY FRONTIERS, ISSN 2052-4129, 2015, Volume 2, Issue 10, pp. 1411 - 1421
The formation of C-C bonds directly by catalytic reductive cross-coupling of two different electrophiles represents one of the practical synthetic protocols... 
CROSS-COUPLINGS | UNACTIVATED TERTIARY ALKYL | ARYL HALIDES | KETONE FORMATION | SECONDARY | CHEMISTRY, ORGANIC | ORGANIC HALIDES | CARBOXYLATION | BROMIDES | GRIGNARD-REAGENTS | TOSYLATES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2012, Volume 134, Issue 35, pp. 14322 - 14325
The first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and dienes is reported. The reaction provides good yields of optically... 
TRANSFORMATION | ALLENEDIENES | N-HETEROCYCLIC CARBENE | 1,6-ENYNES | DIELS-ALDER REACTIONS | GOLD CATALYSIS | COMPLEXES | ORGANOCATALYSIS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 22, pp. 6701 - 6704
The alkylmagnesium alkoxide sBuMgOR⋅LiOR (R=2‐ethylhexyl), which was prepared as a 1.5 m solution in toluene, undergoes very fast Br/Mg exchange with aryl and... 
lithium | Grignard reagents | magnesium | toluene | halogen–magnesium exchange | ENHANCED AIR | METALATION | halogen-magnesium exchange | STABILITY | CHEMISTRY, MULTIDISCIPLINARY | ZINC | SOLVENT | KETONES | BROMINE | KINETICS | GRIGNARD-REAGENTS | ORGANOLITHIUM | Dichloropropane | Chemical tests and reagents | Aldehydes | Toluene | Chlorides | Exchanging | Alkoxides | Ketones | Aromatic compounds | Reagents | Bromides | Magnesium | Epoxides
Journal Article