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Inorganic Chemistry, ISSN 0020-1669, 08/2013, Volume 52, Issue 15, pp. 8993 - 9004
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 33, pp. 7843 - 7846
The synthesis of the N‐aminocarbazole R‐NH2 (2) is reported. Subsequent reaction with bis[bis(trimethylsilyl)amido]tetrylenes E[N(SiMe3)2]2 (E=Ge, Sn, or Pb)... 
tin | amides | germanium | steric hindrance | lead | ANALOG | REACTIVITY | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | DIGERMYNE | BIS(AMINO)STANNYLENES | STABLE COMPOUND | BOND | Amides | Lead | Tin | Germanium | Decomposition | Thermal decomposition
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 05/2019, Volume 38, Issue 9, pp. 1939 - 1945
Radicals and biradicals can easily be obtained when silicon(IV) compounds are reduced and stabilized by the Lewis base cyclic(alkyl)(amino)carbene (cAAC =... 
DENSITY | SILYLENE | PHOSPHORUS | STABLE RADICALS | ENERGY | APPROXIMATION | SI-H | COMPLEXES | CHEMISTRY, ORGANIC | BOND | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 01/2017, Volume 56, Issue 2, pp. 701 - 704
The reaction of the amidinato silylsilylene with a functionalized diaminochlorosilyl substituent, [LSiSi­(Cl)­{(NtBu)2C­(H)­Ph}] (1; L = PhC­(NtBu)2), with... 
ANIONS | SILICON-COMPOUNDS | ELEMENTS | STABLE RADICALS | DATIVE BONDS | REDUCTION | DISILENE | ISOLABLE SILYL | MAIN-GROUP COMPOUNDS | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR | Schiff bases | Chemical reactions | Amidines | Usage | Chemical properties | Radicals (Chemistry)
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2017, Volume 2017, Issue 3, pp. 741 - 751
Cyclopentadienyl‐based (Cp‐based) tricarbonyl rhenium complexes [Cp′Re(CO)3] are convenient precursors for the corresponding Cp‐based trioxorhenium complexes... 
Cyclopentadienyl ligands | Cycloaddition | Rhenium | Carbonyl ligands | Piano‐stool complexes | Piano-stool complexes | 3-COMPONENT SYNTHESIS | CRYSTAL-STRUCTURE | OXO | MAIN-GROUP ELEMENTS | TRANSITION-METALS | CHEMISTRY, INORGANIC & NUCLEAR | DIOLS | CATALYZED DEOXYDEHYDRATION | DEOXYGENATION | CHEMISTRY | MULTIPLE BONDS | Ligands | Phenyls | Synthesis | Olefins | Infrared absorption | Lithium
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 06/2019, Volume 38, Issue 11, pp. 2381 - 2390
The synthesis of alkali metal salts of sterically demanding cyclopentadienyls CpBIGi-PrM (CpBIGi-Pr = Cp(4-i-Pr-Ph)(5); M = Li 1, Na 2, K 3, Rb 4, Cs 5),... 
CP-BIG | SODIUM | NMR | DYNAMICS | CHEMISTRY, ORGANIC | X-RAY-DIFFRACTION | CRYSTAL-STRUCTURES | SUPERBULKY METALLOCENES | MAIN-GROUP ELEMENTS | SOLID-STATE | CATIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2014, Volume 43, Issue 38, pp. 14440 - 14449
The amidines Dipp-N=C(tBu)-N(H)-Qu (1a) (Dipp = 2,6-diisopropylphenyl, Qu = 8-quinolyl) and Dipp-N=C(tBu)-N(H)-Py (1b) (Py = 2-pyridyl) are deprotonated with... 
ALKALINE-EARTH METALS | SANDWICH COMPLEX | S-BLOCK METALS | YTTERBIUM COMPLEXES | STYRENE POLYMERIZATION | AGOSTIC INTERACTIONS | CYCLOPENTADIENYL CHEMISTRY | CRYSTALLOGRAPHIC CHARACTERIZATION | CRYSTAL-STRUCTURES | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | Calcium | Aromatic compounds | Ligands | Formations | Lewis base | Potassium | Lead (metal) | Dipping
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 09/2015, Volume 44, Issue 33, pp. 14842 - 14853
The synthesis of a series of extremely bulky secondary amines with a phosphine function, Ar(†)(PR2)NH (Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4; R = Ph, NEt2,... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2015, Volume 44, Issue 33, pp. 14842 - 14853
The synthesis of a series of extremely bulky secondary amines with a phosphine function, Ar dagger(PR2)NH (Ar dagger = C6H2{C(H)Ph-2}(2)Pr-i-2,6,4; R = Ph,... 
SILYLENE | ACTIVATION | AMIDO-DIGERMYNE | BONDS | SPECTROSCOPIC CHARACTERIZATION | CRYSTAL-STRUCTURES | GROUP ELEMENTS | H-2 | MAIN-GROUP CHEMISTRY | METAL-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Silicon compounds | Chlorosilanes | Synthesis | Precursors | Alkali metals | Amides | Phosphines | Bearing
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 09/2014, Volume 640, Issue 11, pp. 2183 - 2192
A series of simple halogen compounds was studied with respect to steric hindrance by means of quantum mechanical methods utilizing the M062X/aug‐cc‐pvdz level... 
Cone angles | Bulky substituents | Pauli repulsion | Steric hindrance | Steric effects | Tolman angle | Charge transfer | TERPHENYL | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | PHOSPHORUS LIGANDS | RADII | NHC LIGANDS
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 01/2017, Volume 121, Issue 1, pp. 401 - 417
The effect of substituents in disilene mediated N2O activation was studied at the M06-2X/QZVP//ωB97xD/TZVP level of theory. The relationship between structural... 
NITROUS-OXIDE | SILICON DOUBLE-BOND | TRANSITION-STATE METHOD | ZETA VALENCE QUALITY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | ENERGY DECOMPOSITION SCHEME | N-HETEROCYCLIC CARBENES | REVERSIBLE TRANSFORMATION | MAIN-GROUP ELEMENTS | GAUSSIAN-BASIS SETS | QUANTUM-CHEMICAL ANALYSIS
Journal Article
by Wen, XT and Li, YC and Su, MD
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 7/2014, Volume 87, Issue 7, pp. 816 - 818
Substituent effects on the potential energy surface of XSiSb (X = H, Li, Na, BeH, MgH, BH2, AlH2, CH3, SiH3, NH2, PH2, OH, SH, F, and Cl) were investigated by... 
CHEMISTRY | HEAVIER GROUP 14 | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHORUS TRIPLE BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2019, Volume 58, Issue 47, pp. 17041 - 17046
Adamantane‐type organotin chalcogenide clusters of the general composition [(RT)4S6] (R=aromatic substituent, T=Si, Ge, Sn) have extreme non‐linear optical... 
quantum chemical calculations | second-harmonic generation | main-group clusters | substituent effects | white-light generation | APPROXIMATION | CLUSTERS | CORRELATION-ENERGY | TIN | CHEMISTRY, MULTIDISCIPLINARY | Chalcogenides | Semiconductor lasers | Organotin | Emission spectra | Optical properties | Irradiation | Tin | Germanium | I.R. radiation | Silicon | Electron density | Light effects
Journal Article
Chemical Physics Letters, ISSN 0009-2614, 11/2012, Volume 552, pp. 27 - 31
All the B3LYP, B3PW91, and CCSD(T) computational results suggest that electropositively substituted:GeBiX species are more stable than their isomeric XGeBi... 
DENSITY | PSEUDOPOTENTIALS | APPROXIMATION | HIGH-ENERGY-PHYSICS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY | CRYSTALS | CHEMISTRY, PHYSICAL | BASIS-SETS | MAIN-GROUP ELEMENTS | HARTREE-FOCK | ACCURACY | Thermodynamics | Analysis
Journal Article
Science, ISSN 0036-8075, 10/2012, Volume 338, Issue 6106, pp. 504 - 506
Metal complexes coordinated by a single cyclopentadienyl (Cp) ligand are widely used, versatile catalysts, but their application to asymmetric reactions has... 
Coordination polymers | Catalysts | Alkenes | Reactants | REPORTS | Atoms | Lead | Ligands | Catalysis | Acetals | Functional groups | ACTIVATION | MULTIDISCIPLINARY SCIENCES | COMPLEXES | REACTIVITY | OLEFINS | 2+2+2 CYCLOADDITION | AROMATIC-ALDEHYDES | DERIVATIVES | ALKANES |