X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
grunwald-winstein equation (83) 83
chemistry, multidisciplinary (80) 80
solvolysis (63) 63
tert-butyl chloride (45) 45
scale (39) 39
extended grunwald-winstein equation (37) 37
solvent nucleophilicity (37) 37
화학 (33) 33
sn2-sn1 spectrum (32) 32
rates (30) 30
mechanism (26) 26
chemistry (25) 25
chloroformate (25) 25
chemistry, organic (24) 24
product (24) 24
1-adamantyl chloride (22) 22
reaction channels (22) 22
addition-elimination (21) 21
biology (21) 21
kinetics (20) 20
hydrolysis (17) 17
ion (17) 17
chemistry, physical (16) 16
biochemistry & molecular biology (15) 15
derivatives (14) 14
transition-state variation (14) 14
s2 mechanism (13) 13
chloride (12) 12
grunwald–winstein equation (12) 12
index medicus (12) 12
ionization (12) 12
ionizing power (12) 12
solvation (12) 12
kinetic solvent isotope effect (11) 11
solvent kinetic isotope effect (11) 11
acid-chlorides (10) 10
alcohol-water mixtures (10) 10
chloroformates (9) 9
product selectivity (9) 9
solvent ionizing power (9) 9
solvent nucleophilicity scale (9) 9
solvents - chemistry (9) 9
y-scale (9) 9
aromatic ring parameter (8) 8
extended grunwald–winstein equation (8) 8
formates - chemistry (8) 8
linear free energy relationships (8) 8
nucleophilicity (8) 8
solvent isotope effect (8) 8
acyl chlorides (7) 7
benzoyl chloride (7) 7
dual pathways (7) 7
methyl chloroformate (7) 7
nucleophilic-substitution (7) 7
nucleophilic-substitution reactions (7) 7
solvent (7) 7
transition-state (7) 7
attack (6) 6
chlorides (6) 6
concerted mechanism (6) 6
decomposition (6) 6
grunwald-winstein equations (6) 6
leaving group effect (6) 6
methanesulfonyl chloride (6) 6
product selectivities (6) 6
product-rate correlations (6) 6
reactivity (6) 6
selectivity (6) 6
sn2 mechanism (6) 6
solvent effect (6) 6
solvents (6) 6
2 mechanism (5) 5
2 pathway (5) 5
benzenesulfonyl chlorides (5) 5
benzylic chlorides (5) 5
chlorothioformate (5) 5
nitrobenzoyl chloride (5) 5
nucleophilic solvent assistance (5) 5
pathways (5) 5
phenyl chlorodithioformate (5) 5
phenyl chloroformates (5) 5
phosphorochloridate (5) 5
phosphorus (5) 5
similarity models (5) 5
substituent (5) 5
sulfur (5) 5
temperature (5) 5
3rd-order rate laws (4) 4
addition–elimination (4) 4
aqueous-media (4) 4
benzoyl chlorides (4) 4
benzyl (4) 4
chemical reactions (4) 4
fluoroformate (4) 4
full research paper (4) 4
grunwald‐winstein equation (4) 4
kinetics and mechanism (4) 4
mixtures (4) 4
naphthoyl chlorides (4) 4
nucleophilic solvent participation (4) 4
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Journal of the Korean Chemical Society, ISSN 1017-2548, 02/2016, Volume 60, Issue 1, pp. 16 - 20
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 07/2011, Volume 32, Issue 7, pp. 2413 - 2417
...) Grunwald-Winstein equation is applied. The sensitivities (1 and in-values) to changes in solvent nucleophilicity (N... 
Grunwald-Winstein equation | Naphthyl chloroformates | Solvolysis | Addition-Elimination | TERT-BUTYL CHLORIDE | DISPERSION | DECOMPOSITION | ION | CHEMISTRY, MULTIDISCIPLINARY | 1-ADAMANTYL CHLORIDE | SCALE | METHYL CHLOROFORMATE | DERIVATIVES
Journal Article
International Journal of Molecular Sciences, ISSN 1422-0067, 2005, Volume 6, Issue 1-2, pp. 87 - 96
  Application of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate in a variety of pure and binary solvents indicates an addition-elimination pathway in the majority... 
Grunwald-Winstein equation | Solvent isotope effect | n-Propyl chloroformate | Addition-elimination | Ionization | solvent isotope effect | ionization | addition-elimination
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 05/2012, Volume 33, Issue 5, pp. 1729 - 1733
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 09/2013, Volume 34, Issue 9, pp. 2697 - 2701
Journal Article
Journal of Physical Organic Chemistry, ISSN 0894-3230, 02/2007, Volume 20, Issue 2, pp. 88 - 92
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 02/2012, Volume 33, Issue 2, pp. 499 - 504
...) in terms of linear free energy relationships (LFER) are helpful in mechanistic considerations, as is also treatment in terms of the extended Grunwald-Winstein equation... 
Grunwald-Winstein equation | Ionization (I) | Z-value | Selectivity | Addition-Elimination (A-E) | PRODUCT-RATE CORRELATIONS | SOLVENT POLARITY | NUCLEOPHILIC-SUBSTITUTION | REACTION CHANNELS | CHLOROFORMATE | SOLVATION | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-STATE VARIATION | DUAL PATHWAYS | PARASUBSTITUTED BENZOYL CHLORIDES | REACTIVITY-SELECTIVITY PRINCIPLE
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 11/2010, Volume 31, Issue 11, pp. 3366 - 3370
... correlation over the full range of solvents when the extended Grunwald-Winstein equation, with incorporation of the solvent nucleophilicity and the solvent ionizing power... 
Grunwald-Winstein equation | T-Butyl fluoroformate | Alkyl haloformate esters | Ionization pathway | t-Butyl fluoroformate | REACTIVITY | CHLOROFORMATE | CHEMISTRY, MULTIDISCIPLINARY | MIXTURES | 1-ADAMANTYL CHLORIDE | NUCLEOPHILIC SOLVENT PARTICIPATION | CHLOROTHIOFORMATE | SCALE | ADAMANTANE | SN2-SN1 SPECTRUM | WATER
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 11/2011, Volume 32, Issue 11, pp. 3941 - 3946
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 10/2009, Volume 30, Issue 10, pp. 2408 - 2412
.... Analysis with the extended Grunwald-Winstein equation leads to sensitivities toward changes in solvent nucleophilicity (l) of 1 33... 
Grunwald-Winstein equation | Solvent isotope effect | Addition-elimination | Methyl fluoroformate | PATHWAYS | ION-PAIR RETURN | MECHANISM | CHLOROFORMATE | CHEMISTRY, MULTIDISCIPLINARY | FLUORIDE | TRANSITION-STATE VARIATION | BENZYL | PRODUCT | ATTACK | DERIVATIVES
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 07/2010, Volume 31, Issue 7, pp. 1963 - 1967
...) Grunwald-Winstein equation correlation gave sensitivities towards changes in solvent nucleophilicity and solvent ionizing power as expected for a dissociative S(N)2 and/or S(N)1 (ionization) pathway... 
4-morpholinecarbonyl chloride (MPC) | Grunwald-Winstein equation | Ionization (I) | Addition-elimination (A-E) | Ksie | KSIE | NUCLEOPHILIC-SUBSTITUTION | REACTION CHANNELS | CHLOROFORMATE | SOLVATION | CHEMISTRY, MULTIDISCIPLINARY | SOLVENT | TRANSITION-STATE VARIATION | DUAL PATHWAYS | PARASUBSTITUTED BENZOYL CHLORIDES | PRODUCT | KINETICS | 4-Morpholinecarbonyl chloride (MPC)
Journal Article
Bulletin of the Korean Chemical Society, ISSN 0253-2964, 10/2008, Volume 29, Issue 10, pp. 1927 - 1931
Journal Article
No results were found for your search.

Cannot display more than 1000 results, please narrow the terms of your search.