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chemistry, organic (24) 24
nitriles (14) 14
h cyanoalkylation (12) 12
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cyclobutanone o-benzoyloximes (10) 10
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acetates (2) 2
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organic chemistry (2) 2
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by Yang, L and Zhang, JY and Duan, XH and Gao, P and Jiao, J and Guo, LN
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 07/2019, Volume 84, Issue 13, pp. 8615 - 8629
The efficient copper-catalyzed cyanoalkylation of amines via C-C bond cleavage has been demonstrated. Distinctive features of this procedure involves mild... 
TRANSFORMATION | H CYANOALKYLATION | PHOTOREDOX | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY | SECONDARY | CHEMISTRY, ORGANIC | RADICALS | COUPLINGS | REDUCTIVE AMINATION | ALKYL-HALIDES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 4239 - 4249
Metal-catalyzed cyanoalkylation/cyclization of olefinic 1,3-dicarbonyls with cycloketone oxime esters has been developed under redox-neutral conditions. This... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | RING-CLEAVAGE | DERIVATIVES | CYCLIZATION | 2,3-DIHYDROFURANS | C-H CYANOALKYLATION | IMIDATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2019, Volume 60, Issue 31, pp. 2063 - 2066
We have developed a versatile visible-light-driven cyanoalkylation of quinoxalinones under mild conditions. First, the cyanoalkyl radicals are generated from... 
Quinoxalinones | Visible-light-catalysis | Cyclobutanone oxime esters | Nitrogen-centered radicals | STRATEGY | ARYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | CLEAVAGE | C-H CYANOALKYLATION | NITRILES | IMINYL RADICALS | QUINOXALIN-2(1H)-ONES | INHIBITORS | DERIVATIVES | Chemical tests and reagents | Esters | Cyanides
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 07/2017, Volume 4, Issue 7, pp. 1272 - 1275
An iron-catalyzed cascade radical cyanoalkylative dearomatization of N-phenyl cinnamamides was developed. A direct access to the 1-azaspiro[4.5]decanes motif... 
FUNCTIONALIZATION | ALKENES | C-H BOND | ALLYLIC ALCOHOLS | NATURAL-PRODUCTS | ALKYLNITRILES | CHEMISTRY, ORGANIC | ALKYL NITRILES | CYANOMETHYLATION | DERIVATIVES | TRIFLUOROMETHYLATION
Journal Article
Synthesis, ISSN 0039-7881, 06/2015, Volume 47, Issue 11, pp. 1567 - 1580
Abstract A practical and highly efficient azo-compound-mediated/ promoted radical cyanoalkylation of activated alkenes by copper catalysis was developed, which... 
paper | copper catalysis | cyanoalkylation | radical | alkenes | azo compounds | N-ARYL ACRYLAMIDES | ALPHA-ARYLATION | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | ALKYNES | ACTIVATED ALKENES | C-C BOND | DIAMINATION | H BONDS | ACETONITRILE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2018, Volume 83, Issue 23, pp. 14713 - 14722
A copper-catalyzed aerobic oxidative C–C single bond cleavage of acyclic unstrained oxime acetates is reported, providing various aryl nitriles and ketones in... 
ARYL BROMIDES | OXIDATION | FUNCTIONALIZATION | H CYANOALKYLATION | ACTIVATION | AEROBIC OXYGENATION | AMINES | CHEMISTRY, ORGANIC | CYANATION | ALDEHYDES | MOLECULAR-OXYGEN
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 6, pp. 1766 - 1769
Despite the significant progress that has been made in the area of catalyst-dependent chemistry, the exploration of a greener and more environmentally benign... 
ACTIVATION | CHEMISTRY | CHEMISTRY, ORGANIC | BOND-CLEAVAGE | N-CHLOROAMINES | RING-CLEAVAGE | NICKEL-CATALYZED CHEMO | C-H CYANOALKYLATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 71, pp. 9925 - 9928
On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described,... 
VISIBLE-LIGHT | H CYANOALKYLATION | NITROGEN-CENTERED RADICALS | CYCLOBUTANONE O-BENZOYLOXIMES | LIGHT PHOTOREDOX CATALYSIS | GENERATION | RING-CLEAVAGE | OXIME ESTERS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | CARBOXYLIC-ACIDS | Cleavage | Photocatalysis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2018, Volume 54, Issue 71, pp. 9925 - 9928
On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described,... 
Journal Article
by Anand, D and He, YW and Li, LY and Zhou, L
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 01/2019, Volume 17, Issue 3, pp. 533 - 540
The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C-C bond cleavage were described. The... 
H CYANOALKYLATION | NITRILES | AMINES | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | RING-CLEAVAGE | INDOLES | ACCESS
Journal Article
by Tian, L and Gao, SQ and Wang, R and Li, Y and Tang, CL and Shi, LL and Fu, JK
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 05/2019, Volume 55, Issue 37, pp. 5347 - 5350
A novel copper-catalyzed C(sp(3))-N coupling of cycloketone oxime esters with nitrogen nucleophiles has been realized. All of the N-aryl/alkylanilines,... 
HALIDES | AMINATION | CYCLIZATIONS | PHOTOREDOX | SECONDARY | NITROGEN | BOND FORMATION | CLEAVAGE | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | C-H CYANOALKYLATION
Journal Article
by He, YW and Anand, D and Sun, ZC and Zhou, L
ORGANIC LETTERS, ISSN 1523-7060, 05/2019, Volume 21, Issue 10, pp. 3769 - 3773
A visible-light-promoted redox neutral gamma,gamma-difluoroallylation of cycloketone oxime ethers with trifluor-omethyl alkenes through C-C and C-F bond... 
FUNCTIONALIZATION | H CYANOALKYLATION | SUBSTITUTION | ACTIVATION | NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION | ACIDS | ESTERS | CHEMISTRY, ORGANIC | GEM-DIFLUOROALKENES | CARBONYL-COMPOUNDS | IMINYL RADICALS
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 10/2019, Volume 55, Issue 79, pp. 11900 - 11903
A visible-light-induced radical cascade cyclization of aryl isonitriles and cyclobutanone oxime esters for the synthesis of cyclopenta[b]quinoxalines has been... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | IMINYL RADICALS | RING-CLEAVAGE | BOND-CLEAVAGE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H CYANOALKYLATION
Journal Article
by Tang, YQ and Yang, JC and Wang, L and Fan, MJ and Guo, LN
ORGANIC LETTERS, ISSN 1523-7060, 07/2019, Volume 21, Issue 13, pp. 5178 - 5182
A nickel-catalyzed iminyl radical-triggered C-C bond cleavage/radical addition/cyclization cascade of oxime esters and vinyl azides is described. This protocol... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | IMINYL RADICALS | BOND-CLEAVAGE | METAL-FREE | C-H CYANOALKYLATION
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 05/2019, Volume 21, Issue 9, pp. 3153 - 3157
A Cu(OAc)(2)-promoted cascade reaction of malonate-tetherd acyl oximes with indoles, indole-2-alcohols, or indole-2-carboxmides provides facile access to... 
KETOXIME CARBOXYLATES | PALLADIUM-CATALYZED CYCLIZATIONS | ALKENES SYNTHESIS | ESTERS | ACETATES | CHEMISTRY, ORGANIC | PYRIDINES | BOND | CLEAVAGE | DERIVATIVES | C-H CYANOALKYLATION
Journal Article
by Ding, DC and Lan, Y and Lin, ZY and Wang, C
ORGANIC LETTERS, ISSN 1523-7060, 04/2019, Volume 21, Issue 8, pp. 2723 - 2730
By merging C-F and C-C bond activation in the cross-electrophile coupling, we developed an efficient cyanide-free synthesis of diverse functional-group-rich... 
H CYANOALKYLATION | TERTIARY ALKYL | NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION | NICKEL CATALYSIS | CYCLOBUTANONE O-BENZOYLOXIMES | BIOLOGICAL-ACTIVITY | DIFLUOROMETHYL 2-PYRIDYL SULFONE | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | RING-CLEAVAGE | FUNCTIONALIZED 1,1-DIFLUORO-1-ALKENES
Journal Article
by He, Y and Lou, J and Wu, KK and Wang, HM and Yu, ZK
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 02/2019, Volume 84, Issue 4, pp. 2178 - 2190
Carbon-carbon bond formation is among the most important reactions in organic synthesis. Reconstruction of a carbon-carbon bond through ring-opening C-C bond... 
H CYANOALKYLATION | REAGENTS | CYCLOBUTANONE O-BENZOYLOXIMES | THIOBENZOYLKETENE S,N-ACETALS | CHEMISTRY, ORGANIC | IMINYL RADICALS | THIOAROYLKETENE S,N-ACETALS | RING-CLEAVAGE | KETENE N,S-ACETALS | ACCESS | N-TOSYLHYDRAZONES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2018, Volume 360, Issue 9, pp. 1775 - 1779
Journal Article
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