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Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 12, pp. 4535 - 4539
Benzo[b]azepines are important structural motifs for the pharmaceutical industry. However, their syntheses are usually lengthy, involving several steps,... 
ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | H BOND FUNCTIONALIZATION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 03/2015, Volume 137, Issue 10, pp. 3470 - 3473
While it has long been known that different types of support oxides have different capabilities to anchor metals and thus tailor the catalytic behavior, it is... 
C-H BOND | FORMATE | LTL | PERFORMANCE | PLATINUM CATALYSTS | ATOMS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2016, Volume 6, Issue 6, pp. 3890 - 3894
A fast and site-selective biaryl synthesis via dehydrogenative C–H/C–H arylation in a ball mill was developed. In this paper, both electron-deficient oximes... 
C-H bond activation | mechanochemistry | selective arylation | ball milling | biaryls
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2012, Volume 134, Issue 22, pp. 9098 - 9101
We report here an operationally simple, palladium-catalyzed cyclization reaction of N-aryl imines, affording indoles via the oxidative linkage of two C-H bonds... 
ACTIVATION | DIOXYGEN | C-H BOND | HECK | AROMATIC IMINES | OXIDANT | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2019, Volume 17, Issue 13, pp. 3324 - 3327
A visible-light-induced palladium-catalyzed cascade reaction was developed by etherification/C-C coupling cyclization of alpha-bromoacetophenones with phenols.... 
OXIDATION | SAPPAN | CHEMISTRY, ORGANIC | PROTOSAPPANIN | H BOND
Journal Article
Organic Letters, ISSN 1523-7060, 10/2013, Volume 15, Issue 20, pp. 5374 - 5377
A mild procedure for C-7-selective C–H alkenylation of various indolines under oxidative palladium(II) catalysis is reported. A fully substituted urea, formed... 
H BOND ACTIVATION | CHEMISTRY, ORGANIC | OLEFINATION | ARYL UREAS | INDOLES | ARENES
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2012, Volume 68, Issue 26, pp. 5130 - 5136
In the past several decades, organic chemists have made significant contributions to approach direct C-H transformations. However, limited substrate scope and... 
C-H bond activation | Cross dehydrogenative arylation (CDA) | Oxidative coupling
Journal Article
Organic Letters, ISSN 1523-7060, 08/2011, Volume 13, Issue 15, pp. 3852 - 3855
Eosin Y catalyzes efficiently the visible light mediated coupling of sp3 C–H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the... 
IMINIUM CATION | ORGANIC-SYNTHESIS | H BOND | TERTIARY-AMINES | PHOTOCATALYSIS | ORGANOCATALYSIS | CHEMISTRY, ORGANIC | ALDEHYDES | ELECTROCHEMICAL OXIDATION | PHOTOREDOX CATALYSIS | PET PROCESSES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15509 - 15512
Oxidative coupling between C­(sp2)–H bonds and C­(sp3)–H bonds is achieved by the Ni­(II)-catalyzed reaction of benzamides containing an 8-aminoquinoline... 
H BOND ACTIVATION | FUNCTIONALIZATION | CATALYZED ORTHO-ARYLATION | FLUOROALKYLATION | C-C | PERFLUOROALKYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ALKYL-HALIDES
Journal Article
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 04/2014, Volume 265, Issue 1, pp. 52 - 73
Remarkable advances and current state-of-the-art developments in catalytic hydrophosphination of alkenes and alkynes are reviewed. The challenges in... 
Hydrophosphination | Asymmetric hydrophosphination | Metal catalyzed hydrophosphination | P[sbnd]H bond addition | Olefins | Alkynes | PH bond addition
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 8/2012, Volume 41, Issue 17, pp. 5588 - 5598
In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative coupling via C-H functionalization of aromatic, benzylic... 
H BOND ACTIVATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | COUPLING REACTIONS | CARBON-CARBON BONDS | ORTHO-ARYLATION | UNACTIVATED ARENES | GRIGNARD-REAGENT | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ARYLBORONIC ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2013, Volume 135, Issue 16, pp. 6030 - 6032
A 2,2-disubstituted propionamide bearing an 8-aminoquinolinyl group as the amide moiety can be arylated at the β-methyl position with an organozinc reagent in... 
FUNCTIONALIZATION | HOMOENOLATE | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | COMPLEX | C-H BOND | AMINES | METHYLENE | ALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
Journal Article
NATURE, ISSN 0028-0836, 04/2015, Volume 520, Issue 7545, pp. 78 - 81
Transition-metal complexes have long attracted interest for fundamental chemical reactivity studies and possible use in solar energy conversion(1,2).... 
H BOND ACTIVATION | NOBEL LECTURE | TRANSITION-METAL-COMPLEXES | SPIN | SPECTROSCOPY | MULTIDISCIPLINARY SCIENCES | CHEMISTRY | REACTIVITY | PHOTOCHEMISTRY | PHOTOSUBSTITUTION | STRUCTURAL DYNAMICS
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 20, pp. 5216 - 5218
Journal Article
Chemical Society reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 3, pp. 506 - 516
Metal carbenes, generated from the decomposition of diazo compounds by transition-metals, have a broad range of applications in organic synthesis. The progress... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 23, pp. 5317 - 5321
Fast sulfonylation of pyridine/quinoline N-oxides induced by iodine is demonstrated herein. The regioselective protocol occurs under metal-free conditions in a... 
QUINOLINE | AMINATION | ACID | QUINAZOLINE | CHLORIDES | CHEMISTRY, ORGANIC | H BOND FUNCTIONALIZATION
Journal Article
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