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1. Full Text Cp∗Co(III)-Catalyzed C(sp3)-H Bond Activation: A Highly Stereoselective and Regioselective Alkenylation of 8-Methylquinoline with Alkynes
by Sen, Malay and Emayavaramban, Balakumar and Barsu, Nagaraju and Premkumar, J. Richard and Sundararaju, Basker
ACS Catalysis, ISSN 2155-5435, 05/2016, Volume 6, Issue 5, pp. 2792 - 2796
alkenylation | trisubstituted olefins | C-H bond activation | cobalt | quinoline
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2. Full Text I2/TBHP mediated multiple C-H bonds functionalization of azaarenes with methylarenes to synthesize iodoisoquinolinones via iodination/N-benzylation/ amidation sequence
by Luo, Wen-Kun and Xu, Cong-Ling and Yang, Luo
Tetrahedron Letters, ISSN 0040-4039, 11/2019, p. 151328
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3. Full Text Mild, Metal-Free Oxidative Ring-Expansion Approach for the Synthesis of Benzo[ b]azepines
by Stockerl, Sebastian and Danelzik, Tobias and Piekarski, Dariusz G and García Mancheño, Olga
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 12, pp. 4535 - 4539
Benzo[b]azepines are important structural motifs for the pharmaceutical industry. However, their syntheses are usually lengthy, involving several steps,... 
ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | H BOND FUNCTIONALIZATION
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4. Full Text A Common Single-Site Pt(II)-O(OH)(x)- Species Stabilized by Sodium on "Active" and "Inert" Supports Catalyzes the Water-Gas Shift Reaction
by Yang, M and Liu, JL and Lee, S and Zugic, B and Huang, J and Allard, LF and Flytzani-Stephanopoulos, M
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 03/2015, Volume 137, Issue 10, pp. 3470 - 3473
While it has long been known that different types of support oxides have different capabilities to anchor metals and thus tailor the catalytic behavior, it is... 
C-H BOND | FORMATE | LTL | PERFORMANCE | PLATINUM CATALYSTS | ATOMS | CHEMISTRY, MULTIDISCIPLINARY
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5. Full Text Fast and Selective Dehydrogenative C–H/C–H Arylation Using Mechanochemistry
by Lou, Shao-Jie and Mao, Yang-Jie and Xu, Dan-Qian and He, Jiang-Qi and Chen, Qi and Xu, Zhen-Yuan
ACS Catalysis, ISSN 2155-5435, 06/2016, Volume 6, Issue 6, pp. 3890 - 3894
A fast and site-selective biaryl synthesis via dehydrogenative C–H/C–H arylation in a ball mill was developed. In this paper, both electron-deficient oximes... 
C-H bond activation | mechanochemistry | selective arylation | ball milling | biaryls
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6. Full Text Palladium-Catalyzed Aerobic Oxidative Cyclization of N-Aryl lmines: lndole Synthesis from Anilines and Ketones
by Wei, Y and Deb, I and Yoshikai, N
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2012, Volume 134, Issue 22, pp. 9098 - 9101
We report here an operationally simple, palladium-catalyzed cyclization reaction of N-aryl imines, affording indoles via the oxidative linkage of two C-H bonds... 
ACTIVATION | DIOXYGEN | C-H BOND | HECK | AROMATIC IMINES | OXIDANT | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES
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7. Full Text A visible-light-induced cascade reaction of etherification/C-C cyclization: Efficient synthesis of dibenzo[: B, d] oxepin-7(6 H)-ones
by Fu, Wanyong and Yu, Aixia and Jiang, Hongshuo and Zuo, Minghui and Wu, Hongfeng and Yang, Zhongwen and An, Qi and Sun, Zhizhong and Chu, Wenyi
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2019, Volume 17, Issue 13, pp. 3324 - 3327
A visible-light-induced palladium-catalyzed cascade reaction was developed by etherification/C-C coupling cyclization of alpha-bromoacetophenones with phenols.... 
OXIDATION | SAPPAN | CHEMISTRY, ORGANIC | PROTOSAPPANIN | H BOND
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8. Full Text Oxidative Palladium(II)-Catalyzed C‑7 Alkenylation of Indolines
by Jiao, Lin-Yu and Oestreich, Martin
Organic Letters, ISSN 1523-7060, 10/2013, Volume 15, Issue 20, pp. 5374 - 5377
A mild procedure for C-7-selective C–H alkenylation of various indolines under oxidative palladium(II) catalysis is reported. A fully substituted urea, formed... 
H BOND ACTIVATION | CHEMISTRY, ORGANIC | OLEFINATION | ARYL UREAS | INDOLES | ARENES
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9. Full Text Challenges in C-C bond formation through direct transformations of sp 2 C-H bonds
by Yu, Da-Gang and Li, Bi-Jie and Shi, Zhang-Jie
Tetrahedron, ISSN 0040-4020, 07/2012, Volume 68, Issue 26, pp. 5130 - 5136
In the past several decades, organic chemists have made significant contributions to approach direct C-H transformations. However, limited substrate scope and... 
C-H bond activation | Cross dehydrogenative arylation (CDA) | Oxidative coupling
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10. Full Text Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation
by Hari, Durga Prasad and König, Burkhard
Organic Letters, ISSN 1523-7060, 08/2011, Volume 13, Issue 15, pp. 3852 - 3855
Eosin Y catalyzes efficiently the visible light mediated coupling of sp3 C–H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the... 
IMINIUM CATION | ORGANIC-SYNTHESIS | H BOND | TERTIARY-AMINES | PHOTOCATALYSIS | ORGANOCATALYSIS | CHEMISTRY, ORGANIC | ALDEHYDES | ELECTROCHEMICAL OXIDATION | PHOTOREDOX CATALYSIS | PET PROCESSES
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11. Full Text Ni(II)-Catalyzed Oxidative Coupling between C(sp2)–H in Benzamides and C(sp3)–H in Toluene Derivatives
by Aihara, Yoshinori and Tobisu, Mamoru and Fukumoto, Yoshiya and Chatani, Naoto
Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15509 - 15512
Oxidative coupling between C­(sp2)–H bonds and C­(sp3)–H bonds is achieved by the Ni­(II)-catalyzed reaction of benzamides containing an 8-aminoquinoline... 
H BOND ACTIVATION | FUNCTIONALIZATION | CATALYZED ORTHO-ARYLATION | FLUOROALKYLATION | C-C | PERFLUOROALKYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ALKYL-HALIDES
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12. Full Text Control over Organometallic Intermediate Enables Cp∗Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles
by Lu, Qingquan and Vásquez-Céspedes, Suhelen and Gensch, Tobias and Glorius, Frank
ACS Catalysis, ISSN 2155-5435, 04/2016, Volume 6, Issue 4, pp. 2352 - 2356
C-H bond activation | switchable selectivity | cobalt catalysis | dehydrative cyclization | dehydrogenative cyclization
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13. Full Text Recent Advances in C–H Functionalization
by Davies, Huw M. L and Morton, Daniel
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2016, Volume 81, Issue 2, pp. 343 - 350
DIRECTING GROUP | C(SP)-H BOND FUNCTIONALIZATION | QUINOLINE N-OXIDES | VISIBLE-LIGHT | U-SHAPED TEMPLATE | DIRECT ARYLATION | C-8 POSITION | CHEMISTRY, ORGANIC | AROMATIC-COMPOUNDS | LATE-STAGE FUNCTIONALIZATION | PHOTOREDOX CATALYSIS
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14. Full Text Contemporary avenues in catalytic PH bond addition reaction: A case study of hydrophosphination
by Koshti, Vijay and Gaikwad, Shahaji and Chikkali, Samir H
Coordination Chemistry Reviews, ISSN 0010-8545, 04/2014, Volume 265, Issue 1, pp. 52 - 73
Remarkable advances and current state-of-the-art developments in catalytic hydrophosphination of alkenes and alkynes are reviewed. The challenges in... 
Hydrophosphination | Asymmetric hydrophosphination | Metal catalyzed hydrophosphination | P[sbnd]H bond addition | Olefins | Alkynes | PH bond addition
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15. Full Text From C(sp2)-H to C(sp3)-H: systematic studies on transition metal-catalyzed oxidative C-C formation
by Li, Bi-Jie and Shi, Zhang-Jie
Chemical Society Reviews, ISSN 0306-0012, 8/2012, Volume 41, Issue 17, pp. 5588 - 5598
In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative coupling via C-H functionalization of aromatic, benzylic... 
H BOND ACTIVATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | COUPLING REACTIONS | CARBON-CARBON BONDS | ORTHO-ARYLATION | UNACTIVATED ARENES | GRIGNARD-REAGENT | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ARYLBORONIC ACIDS
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16. Full Text β‑Arylation of Carboxamides via Iron-Catalyzed C(sp3)–H Bond Activation
by Shang, Rui and Ilies, Laurean and Matsumoto, Arimasa and Nakamura, Eiichi
Journal of the American Chemical Society, ISSN 0002-7863, 04/2013, Volume 135, Issue 16, pp. 6030 - 6032
A 2,2-disubstituted propionamide bearing an 8-aminoquinolinyl group as the amide moiety can be arylated at the β-methyl position with an organozinc reagent in... 
FUNCTIONALIZATION | HOMOENOLATE | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | COMPLEX | C-H BOND | AMINES | METHYLENE | ALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
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17. Full Text Orbital-specific mapping of the ligand exchange dynamics of Fe(CO)(5) in solution
by Wernet, P and Kunnus, K and Josefsson, I and Rajkovic, I and Quevedo, W and Beye, M and Schreck, S and Grubel, S and Scholz, M and Nordlund, D and Zhang, W and Hartsock, RW and Schlotter, WF and Turner, JJ and Kennedy, B and Hennies, F and de Groot, FMF and Gaffney, KJ and Techert, S and Odelius, M and Fohlisch, A
NATURE, ISSN 0028-0836, 04/2015, Volume 520, Issue 7545, pp. 78 - 81
Transition-metal complexes have long attracted interest for fundamental chemical reactivity studies and possible use in solar energy conversion(1,2).... 
H BOND ACTIVATION | NOBEL LECTURE | TRANSITION-METAL-COMPLEXES | SPIN | SPECTROSCOPY | MULTIDISCIPLINARY SCIENCES | CHEMISTRY | REACTIVITY | PHOTOCHEMISTRY | PHOTOSUBSTITUTION | STRUCTURAL DYNAMICS
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18. Full Text Si-H bond activation: Bridging lewis acid catalysis with Brookhart's iridium(III) pincer complex and B(C6F5)3
by Robert, Tobias and Oestreich, Martin
Angewandte Chemie - International Edition, ISSN 1433-7851, 05/2013, Volume 52, Issue 20, pp. 5216 - 5218
deoxygenation | Lewis acids | Si-H bond activation | silicon | pincer complexes
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19. Full Text Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity
by Liu, Lu and Zhang, Junliang
Chemical Society reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 3, pp. 506 - 516
Metal carbenes, generated from the decomposition of diazo compounds by transition-metals, have a broad range of applications in organic synthesis. The progress... 
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20. Full Text Fast regioselective sulfonylation of pyridine/quinoline N-oxides induced by iodine
by Wang, Ruijia and Zeng, Zebing and Chen, Chuang and Yi, Niannian and Jiang, Jun and Cao, Zhong and Deng, Wei and Xiang, Jiannan
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 23, pp. 5317 - 5321
Fast sulfonylation of pyridine/quinoline N-oxides induced by iodine is demonstrated herein. The regioselective protocol occurs under metal-free conditions in a... 
QUINOLINE | AMINATION | ACID | QUINAZOLINE | CHLORIDES | CHEMISTRY, ORGANIC | H BOND FUNCTIONALIZATION
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