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halide-free carbonylation (21) 21
chemistry, physical (19) 19
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Advances in Catalysis, ISSN 0360-0564, 01/2010, Volume 53, Issue C, pp. 1 - 45
The carbonylation of methanol to acetic acid is established as one of the major industrial applications of homogeneous catalysis. Since the introduction of a... 
VAPOR-PHASE CARBONYLATION | MIGRATORY CO INSERTION | DIMETHYL ETHER | CHEMISTRY, PHYSICAL | METAL-COMPLEX CATALYST | ACETIC-ACID SYNTHESIS | RHODIUM(I) CARBONYL | METHYL ACETATE FORMATION | OXIDATIVE ADDITION | HALIDE-FREE CARBONYLATION | LOW-TEMPERATURE
Journal Article
Journal of Energy Chemistry, ISSN 2095-4956, 09/2019, Volume 36, pp. 51 - 63
Syngas to ethanol, consisting of dimethyl ether (DME) carbonylation to methyl acetate (MA) over zeolites and MA hydrogenation to ethanol on copper catalyst,... 
Mordenite | Reaction mechanism | Acid sites | DME carbonylation | Deactivation | Zeolites | SELECTIVE CARBONYLATION | VAPOR-PHASE CARBONYLATION | ENERGY & FUELS | CHEMISTRY, PHYSICAL | CATALYTIC CARBONYLATION | ENGINEERING, CHEMICAL | CHEMISTRY, APPLIED | HALIDE-FREE CARBONYLATION | MORDENITE ZEOLITE | H-MORDENITE | METHYL ACETATE | HETEROGENEOUS CATALYSTS
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 03/2013, Volume 117, Issue 11, pp. 5840 - 5847
Carbonylation of dimethyl ether (DME) with CO over H-mordenite (H-MOR) zeolites from 423 to 573 K was studied by in-situ 13C solid-state NMR spectroscopy. The... 
VAPOR-PHASE CARBONYLATION | METHANOL | SPECIFICITY | MECHANISM | CONVERSION | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | ACETIC-ACID | ACIDIC ZEOLITES | SHAPE SELECTIVITY | HALIDE-FREE CARBONYLATION | HETEROGENEOUS CATALYSTS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2006, Volume 45, Issue 10, pp. 1617 - 1620
A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This... 
ethers | zeolites | heterogeneous catalysis | carbonylation | carboxylic acids | Heterogeneous catalysis | Carbonylation | Carboxylic acids | Ethers | Zeolites | VAPOR-PHASE CARBONYLATION | H-ZEOLITES | METHANOL | TERT-BUTYL ALCOHOL | ACETIC-ACID | CHEMISTRY, MULTIDISCIPLINARY | SPECTROSCOPY | CARBON-MONOXIDE | HALIDE-FREE CARBONYLATION | MAS NMR | HETEROGENEOUS CATALYSTS
Journal Article
Journal of Catalysis, ISSN 0021-9517, 2007, Volume 245, Issue 1, pp. 110 - 123
Journal Article
Catalysis Letters, ISSN 1011-372X, 10/2010, Volume 139, Issue 1-2, pp. 33 - 37
Dimethyl ether (DME) carbonylation to methyl acetate (MA) was comparatively investigated over HZSM-35 and mordenite (HMOR) zeolites. The HZSM-35 catalyst... 
HMOR | HZSM-35 | Carbonylation | Dimethyl ether | Stability | Methyl acetate | VAPOR-PHASE CARBONYLATION | METHANOL | SPECIFICITY | REACTIVITY | CHEMISTRY, PHYSICAL | FERRIERITE | ACIDIC ZEOLITES | SITES | HALIDE-FREE CARBONYLATION | HETEROGENEOUS CATALYSTS | Methyl ether | Soft drink industry | Aromatic compounds | Zeolites | Deactivation | Catalysts | Coke | Selectivity | Catalysis | Porosity | Carbonyls
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2012, Volume 2, Issue 7, pp. 1368 - 1376
Robust, bifunctional catalysts comprising Rh(CO)(Xantphos) exchanged phosphotungstic acids of general formulas [Rh(CO)(Xantphos)]+ n [H3–n PW12O40] n− have... 
methanol | heteropoly acid | carbonylation | EXAFS | rhodium | VAPOR-PHASE CARBONYLATION | FINE CHEMICAL-SYNTHESIS | C2+ OXYGENATE SYNTHESIS | DIMETHYL ETHER | CHEMISTRY, PHYSICAL | HETEROPOLY ACIDS | HALIDE-FREE CARBONYLATION | HETEROGENEOUS CATALYSTS | METHYL ACETATE | HYDROFORMYLATION
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 02/2015, Volume 5, Issue 2, pp. 843 - 850
Supported rhodium carbonyls were synthesized by deposition of Rh-6(CO)(16) on TiO2. The samples were active for gas-phase dimethyl ether carbonylation in the... 
METHANOL CARBONYLATION | VAPOR-PHASE CARBONYLATION | SUPPORTED RHODIUM | HEXARHODIUM CLUSTERS | KEY INTERMEDIATE | ORGANOMETALLIC CHEMISTRY | CHEMISTRY, PHYSICAL | HALIDE-FREE CARBONYLATION | ACIDIC ZEOLITES | METHYL ACETATE | METAL-OXIDES
Journal Article
Chinese Journal of Catalysis, ISSN 1872-2067, 2010, Volume 31, Issue 7, pp. 729 - 738
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 05/2013, Volume 117, Issue 21, pp. 11168 - 11175
Knowledge of the elementary steps of the reaction on the surface of a heterogeneous catalyst is crucial for understanding the reaction mechanism. This valuable... 
METHANOL | CHEMICAL-SHIFTS | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | ACETIC ACID | NANOSCIENCE & NANOTECHNOLOGY | H3PW12O40 | KEGGIN 12-H3PW12O40 | ZEOLITES | HALIDE-FREE CARBONYLATION | STATE NMR | MAS NMR | HETEROGENEOUS CATALYSTS
Journal Article
Chinese Journal of Chemical Physics, ISSN 1674-0068, 04/2013, Volume 26, Issue 2, pp. 220 - 224
The effect of calcination temperature on the catalytic activity for the dimethyl ether (DME) carbonylation into methyl acetate (MA) was investigated over... 
HMOR | Carbonylation | Dimethyl ether | Methyl acetate | Calcination temperature | SELECTIVE CARBONYLATION | METHANOL | SPECIFICITY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | ACETIC-ACID | ACIDIC ZEOLITES | EXCHANGE | HALIDE-FREE CARBONYLATION | H-MORDENITE | HETEROGENEOUS CATALYSTS
Journal Article
Catalysis Communications, ISSN 1566-7367, 2009, Volume 10, Issue 9, pp. 1292 - 1295
The combination of a Pd/CeO 2 catalyst for in situ generation of CO, via methanol decomposition, with a copper mordenite methanol carbonylation catalyst has... 
Halide-free | Carbonylation | Decomposition | Acetyls | Methanol | VAPOR-PHASE CARBONYLATION | CHEMISTRY, PHYSICAL | CATALYSTS | METHYL ACETATE
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 09/2014, Volume 118, Issue 36, pp. 21042 - 21048
Solid cesium salts of 12-tungstophosphoric acid show high surface area and strong acidity, which stimulate their applications as the catalysts for many... 
PROTON MOBILITY | EXCHANGE-REACTION | HETEROPOLY COMPOUNDS | SPIN-DIFFUSION | PHOSPHOTUNGSTIC ACID | MATERIALS SCIENCE, MULTIDISCIPLINARY | NUCLEAR-MAGNETIC-RESONANCE | DIMETHYL ETHER | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | H-1 MAS NMR | HALIDE-FREE CARBONYLATION | IN-SITU
Journal Article
Journal Article