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hemithioindigo (15) 15
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Tetrahedron Letters, ISSN 0040-4039, 07/2015, Volume 56, Issue 29, pp. 4266 - 4274
Hemithioindigo (HTI) is an emerging photoswitch with many advantageous properties compared to the commonly used photoswitches like azobenzenes, spiropyranes,... 
Photophysical chemistry | Photochromism | Hemithioindigo | Photoswitch | EXPEDIENT SYNTHESIS | LIGHT | CHEMISTRY, ORGANIC | ABSORPTION-SPECTRA | MOLECULAR SWITCH | PHOTOCHROMIC DITHIENYLETHENE | CIS-TRANS PHOTOISOMERIZATION | DIRECTED METALATION | E ISOMERIZATION | Z/E-PHOTOISOMERIZATION | OMEGA-AMINO ACIDS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 05/2018, Volume 51, Issue 5, pp. 1153 - 1163
Conspectus Indigoid photoswitches comprise a class of chromophores that are derived from the parent and well-known indigo dye. Different from most... 
FLUORESCENCE PROPERTIES | HEMITHIOINDIGO PHOTOSWITCHES | SUBSTITUTED HEMITHIOINDIGO | UNIDIRECTIONAL ROTATION | PHOTOISOMERIZATION | ROTARY MOTORS | ISOMERIZATION | PHOTOCHROMISM | DYNAMIC CONTROL | DRIVEN | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 34, p. 130466
The most red-shifted hemithioindigo photoswitches have been identified through systematic introduction of aryl units to a parent pyrrole hemithioindigo... 
Hemithioindigo | Photoswitch | TD-DFT
Journal Article
TETRAHEDRON, ISSN 0040-4020, 08/2019, Volume 75, Issue 34
The most red-shifted hemithioindigo photoswitches have been identified through systematic introduction of aryl units to a parent pyrrole hemithioindigo... 
Hemithioindigo | PHOTOISOMERIZATION | Photoswitch | LIGHT | PHOTOCHROMISM | CHEMISTRY, ORGANIC | TD-DFT
Journal Article
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, 07/2018, Volume 200, pp. 1 - 9
The control of internal molecular motions by outside stimuli is a decisive task in the construction of functional molecules and molecular machines.... 
Intermolecular hydrogen bond | Hemithioindigo | Nonadiabatic dynamic simulation | Two-dimensional photoswitch | EXCITED-STATE | MOLECULAR-ORBITAL METHODS | HYDROGEN-BONDS | SPECTROSCOPY | ROTORS | DYNAMICS | PHOTOPHYSICS | BASIS-SETS | MOTORS | DENSITY-FUNCTIONAL THEORY | Density functionals | Hydrogen | Hydrogen bonding | Bonds | Cyclohexane
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 42, pp. 15060 - 15067
Journal Article
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 1, pp. 186 - 189
A new mode for the activation of elemental sulfur is reported. In the presence of both DMSO and a tertiary aliphatic amine (triethylamine or... 
CHEMISTRY, ORGANIC | THIOFLAVONES | REDOX CONDENSATION | 2-NITROCHALCONES | HEMITHIOINDIGO PHOTOSWITCHES | DERIVATIVES | Organic chemistry | Chemical Sciences
Journal Article
Chemistry of Materials, ISSN 0897-4756, 05/2018, Volume 30, Issue 9, pp. 2873 - 2887
Stimuli-responsive nanocarriers can release their bioactive cargo “on demand”, potentially improving the selectivity, specificity, and efficacy of therapeutic... 
VISIBLE-LIGHT | HEMITHIOINDIGO-PHOTOISOMERIZATION | MATERIALS SCIENCE, MULTIDISCIPLINARY | IRREVERSIBLE PHOTOCHROMIC SYSTEMS | NEGATIVE PHOTOCHROMISM | OPTICAL-PROPERTIES | CHEMISTRY, PHYSICAL | ACCEPTOR STENHOUSE ADDUCTS | AZOBENZENE PHOTOSWITCHES | SUPRAMOLECULAR HYDROGELS | BIOLOGICAL APPLICATIONS | REVERSIBLE PHOTOCYCLIZATION
Journal Article
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1860-5397, 10/2019, Volume 15, pp. 2500 - 2508
Photoswitchable oligonucleotides can determine specific biological outcomes by light-induced conformational changes. In particular, artificial probes activated... 
azobenzene | ZEBRAFISH | TRANSCRIPTION | ISOMERIZATION | CHEMISTRY, ORGANIC | hemithioindigo | peptide nucleic acid (PNA) | photoswitch | STRAND DISPLACEMENT | visible-light irradiation | PHOTOSWITCHES | GENE-EXPRESSION | TETHERED T7 PROMOTER | PHOTOREGULATION | FLUOROAZOBENZENES
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 16, pp. 5027 - 5031
A facile synthesis of peri-naphthoindigo (PNI) was reported for the first time from simple precursor. Installation of a chromophore at the peri-position of... 
PHOTOCHROMIC PERINAPHTHOTHIOINDIGO | HEMITHIOINDIGO PHOTOSWITCHES | TRIANGULAR METALLOPRISM | DESIGN | DIRUTHENIUM COMPLEXES | DEPROTONATED INDIGO | OPTICAL-PROPERTIES | CHEMISTRY | CHEMISTRY, ORGANIC | ORGANIC SEMICONDUCTORS | DERIVATIVES
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 09/2018, Volume 115, Issue 38, pp. 9414 - 9422
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 46, pp. 14536 - 14539
Journal Article
Physical Chemistry Chemical Physics : PCCP, ISSN 1463-9076, 01/2018, Volume 20, Issue 9, pp. 6347 - 6353
The effect of acceptor strength variation on ultrafast twisting relaxation dynamics was investigated by comparing the ultrafast relaxation dynamics in a series... 
Femtosecond | Dynamic tests | Twisting | Fluorescence | Derivatives | Charge transfer | Free energy
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2018, Volume 20, Issue 9, pp. 6347 - 6353
The effect of acceptor strength variation on ultrafast twisting relaxation dynamics was investigated by comparing the ultrafast relaxation dynamics in a series... 
AMINOSTILBENES | CONJUGATION | HEMITHIOINDIGO PHOTOSWITCHES | SOLVENT POLARITY | ELECTRON-TRANSFER | FLUORESCENCE | DONOR | PHOTOISOMERIZATION | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | TRANSFER DYNAMICS | EXCITED-STATES
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 08/2013, Volume 117, Issue 34, pp. 17623 - 17632
We report the properties and switching characteristics of a series of dithienylethene photochromic switches immobilized on gold. Self-assembled monolayers... 
DITHIENYLCYCLOPENTENES | MEMORIES | SELF-ASSEMBLED MONOLAYERS | OPTICAL-DATA STORAGE | AZOBENZENE | PHOTOSWITCHES | RAMAN | HEMITHIOINDIGO CHROMOPHORES | DIARYLETHENES | MOLECULAR SWITCHES | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 34, pp. 11064 - 11068
Journal Article
Synthesis, ISSN 0039-7881, 12/2005, Volume 2005, Issue 19, pp. 3297 - 3300
ABSTRACT Efficient procedures for the preparation of the N-Boc-protected aldehydes 5A and 5B are described which are valuable precursors for the synthesis of... 
paper | Photoswitches | Amino acids | Hemithioindigos | Peptides
Journal Article
Journal of Physical Organic Chemistry, ISSN 0894-3230, 10/2018, Volume 31, Issue 10, pp. e3858 - n/a
Isomerizations of azo, imine, and alkene groups using light are highly tunable. As such, photoswitches based on these functional groups have become critical... 
azobenzene | overcrowded alkenes | molecular switches | photo responsive | HEMITHIOINDIGO PHOTOSWITCHES | DESIGN | ISOMERIZATION | CHEMISTRY, ORGANIC | CHEMISTRY, PHYSICAL | DRIVEN MOLECULAR MOTORS | CIS-TRANS PHOTOISOMERIZATION | PEPTIDE | VISIBLE-LIGHT | MACHINES | SWITCHES | Azo compounds | Chemical properties | Bonds | Olefins
Journal Article