X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
homoallyl alcohols (198) 198
chemistry, organic (155) 155
chemistry, multidisciplinary (85) 85
aldehydes (71) 71
organic-synthesis (58) 58
allylation (45) 45
homoallyl alcohol (45) 45
carbonyl-compounds (39) 39
alcohols (38) 38
catalysis (37) 37
chemistry (34) 34
retro-allylation (33) 33
index medicus (31) 31
carbon-carbon bond (29) 29
ketones (29) 29
reagents (28) 28
aryl halides (26) 26
stereoselective synthesis (26) 26
complexes (25) 25
palladium (23) 23
asymmetric-synthesis (22) 22
chemistry, inorganic & nuclear (22) 22
halides (22) 22
cleavage (21) 21
carbonyl addition (19) 19
stereoisomerism (19) 19
enantioselective synthesis (18) 18
chemical properties (17) 17
cyclization (17) 17
derivatives (17) 17
molecular structure (17) 17
analysis (16) 16
rhodium (16) 16
activation (15) 15
chromium (15) 15
diastereoselective synthesis (15) 15
esters (15) 15
homoallyl ethers (15) 15
acid (13) 13
asymmetric catalysis (13) 13
chemistry, physical (13) 13
homoallyl (13) 13
homoallyl radical rearrangement (13) 13
homogeneous catalysis (13) 13
research (13) 13
letter (12) 12
catalysts (11) 11
lewis-acid (11) 11
silafunctional compounds (11) 11
alpha,alpha-disubstituted arylmethanols (10) 10
boron (10) 10
chemical reactions (10) 10
natural-products (10) 10
olefins (10) 10
synthesis (10) 10
trifluoromethyl (10) 10
alkylation (9) 9
c-c activation (9) 9
dehydration (9) 9
organometallic compounds - chemistry (9) 9
reduction (9) 9
stereochemistry (9) 9
stereoselective-synthesis (9) 9
tert-cyclobutanols (9) 9
allyl compounds - chemistry (8) 8
arylation (8) 8
carbonyl compounds (8) 8
chemical bonds (8) 8
chloride (8) 8
crotylmolybdenum complexes (8) 8
ethers (8) 8
facile (8) 8
ketone (8) 8
ligands (8) 8
organosilicon compounds (8) 8
1,4-butanediol (7) 7
alkynes (7) 7
allylstannanes (7) 7
asymmetric allylation (7) 7
chemical synthesis (7) 7
chiral synthesis (7) 7
construction (7) 7
enantioselective allylation (7) 7
indium (7) 7
lactones (7) 7
natural products (7) 7
one-pot synthesis (7) 7
reactivity (7) 7
tetrahydrofuran (7) 7
transition-metals (7) 7
water (7) 7
3-buten-1-ol (6) 6
aldehyde (6) 6
aldehydes - chemistry (6) 6
allyl compounds (6) 6
allylboration (6) 6
aqueous-media (6) 6
aromatic-aldehydes (6) 6
c-c bond (6) 6
carbon bond formation (6) 6
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


ACS Catalysis, ISSN 2155-5435, 11/2015, Volume 5, Issue 11, pp. 6458 - 6462
We demonstrate that a simple Co(III)-complex can efficiently catalyze the cleavage of unstrained C-C bonds via the beta-carbon elimination of secondary and... 
β-carbon elimination | alcohols | base metal | cobalt | C-C bond activation | ORGANIC-SYNTHESIS | RING-EXPANSION | ALKENE HYDROGENATION | CHEMISTRY, PHYSICAL | C-H ACTIVATION | MILD CONDITIONS | HOMOALLYL ALCOHOLS | N-TYPE REACTIONS | 7-MEMBERED RINGS | COBALT CATALYSIS | beta-carbon elimination | CARBOXYLIC-ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 90, pp. 12217 - 12220
Aerobic oxidative alpha-arylation of furans with boronic acids via Pd(II)-catalyzed C-C bond cleavage of primary furfuryl alcohols provides sustainable access... 
AZA-PIANCATELLI REARRANGEMENT | ACTIVATION | RHODIUM | HOMOALLYL ALCOHOLS | SINGLE BOND | RETRO-ALLYLATION | ACHMATOWICZ REARRANGEMENT | CARBON-CARBON BONDS | CATALYZED ALLYL TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | DEAROMATIZATION | Alcohol | Cleavage | Furans | Alcohols
Journal Article
Chemical Science, ISSN 2041-6520, 05/2012, Volume 3, Issue 5, pp. 1645 - 1649
An unprecedented example of sequential pyridinyl directed C-C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(III) catalysis is... 
H FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | QUATERNARY STEREOGENIC CENTERS | CARBON-CARBON BOND | HOMOALLYL ALCOHOLS | RETRO-ALLYLATION | ARYL HALIDES | REGIOSELECTIVE ARYLATION | OXYGEN ATMOSPHERE | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2012, Volume 53, Issue 51, pp. 6946 - 6949
Iron(III) -toluenesulfonate (tosylate) is an efficient catalyst for acetylation of alcohols, phenols, and aldehydes. The acetylation of 1° and 2° alcohols,... 
Phenols | Esters | Green chemistry | Diols | Iron and its compounds | Acylation | Alcohols | ORGANIC-SYNTHESIS | ACETYLATION | CHEMISTRY, ORGANIC | CHEMOSELECTIVE SYNTHESIS | IONIC LIQUID | DEPROTECTION | HIGHLY EFFICIENT | EFFICIENT CATALYST | SOLVENT-FREE | RECYCLABLE CATALYST | HOMOALLYL ETHERS | Iron | Green technology | Catalysts | Tetrahedrons | Acetylation | Aldehydes
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2017, Volume 58, Issue 26, pp. 2525 - 2529
An efficient, direct nucleophilic allylic substitution of α-, β- and γ-substituted alcohols with enamines, using the Pd(OAc) PPh catalyst system and ZnBr as a... 
Homoallyl ketone | Palladium | Allylic substitution | Enamine | Allylic alcohol | NUCLEOPHILES | GAMMA,DELTA-UNSATURATED KETONES | TRANSITION-METAL | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | 1,4-ADDITION | Ketones | Palladium catalysts | Acetates | Alcohols
Journal Article
Organometallics, ISSN 0276-7333, 06/2016, Volume 35, Issue 11, pp. 1876 - 1884
Unsymmetrical biaryls were synthesized by oxidative coupling reactions, between aromatic primary alcohols and arylboronic acids through the C-C bond cleavage... 
TERT-CYCLOBUTANOLS | HOMOALLYL ALCOHOLS | DIRECT FUNCTIONALIZATION | RING-EXPANSION | RETRO-ALLYLATION | C-C BOND | ARYL HALIDES | CHEMISTRY, ORGANIC | H BONDS | DERIVATIVES SYNTHESIS | CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 2014, Volume 4, Issue 7, pp. 1852 - 1868
The allylation of benzylic, allylic and propargylic alcohols by means of allyltrimethylsilane represents one of the most powerful, elegant and practical... 
BRONSTED ACID CATALYST | HOSOMI-SAKURAI REACTIONS | ONE-POT SYNTHESIS | LEWIS-ACID | PROPARGYLIC ALCOHOLS | CHEMISTRY, PHYSICAL | HOMOALLYL ETHERS | DIRECT COUPLING REACTION | KINESIN SPINDLE PROTEIN | VIVO ANTITUMOR-ACTIVITY | NUCLEOPHILIC-SUBSTITUTION-REACTIONS | Economics | Carbon-carbon composites | Synthesis | Formations | Trends | Catalysis | Bonding | Alcohols
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2008, Volume 130, Issue 15, pp. 5048 - 5049
Treatment of tertiary homopropargyl alcohol with aryl halide under palladium catalysis provided arylallenes regioselectively. The reaction includes... 
BOND-CLEAVAGE | ALLENES | HOMOALLYL ALCOHOLS | CHEMISTRY, MULTIDISCIPLINARY | ARYL HALIDES | ALLYLATION | X-ray crystallography | Optical properties | Analysis | Palladium | Chemical properties | Catalysis | Structure | Observations | Aliphatic compounds
Journal Article
ACTA CHIMICA SINICA, ISSN 0567-7351, 2017, Volume 75, Issue 12, pp. 1196 - 1201
The asymmetric carbonyl allylation of aldehydes with allylmetal reagents presents one of the most efficient and straightforward methods for the synthesis of... 
BRONSTED ACID | palladium catalysis | chiral phosphoric acid | allylic alcohol | ALKYLATION | carbonyl allylation | asymmetric catalysis | INDUCTION | CHEMISTRY, MULTIDISCIPLINARY | N-OXIDE | KETONES | HOMOALLYL ALCOHOLS | ENANTIOSELECTIVE ALLYLBORATION | METAL | UMPOLUNG | C-H
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2018, Volume 140, Issue 40, pp. 12705 - 12709
Herein, we report the redox-neutral allylation of aldehydes with readily available electron-rich allyl (hetero-) arenes, beta-alkyl styrenes and... 
ANTI-AMINOALLYLATION | ORGANIC-SYNTHESIS | HYDROGEN-ATOM TRANSFER | HOMOALLYL ALCOHOLS | 1,2-AMINO ALCOHOLS | TITANIUM TRICHLORIDE | CARBONYL-COMPOUNDS | RADICAL-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | ASYMMETRIC ALLYLATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2011, Volume 52, Issue 8, pp. 913 - 915
Pd/Et B and Pd/Et Zn systems promote the nucleophilic allylations of 2-aminotetrahydrofuran and 2-aminotetrahydropyran with allylic alcohols to provide... 
Umpolung | Carbohydrate | Palladium | Hemiacetal | Allylation | CONVENIENT SYNTHESIS | PI-ALLYLPALLADIUM | 2-TETRAHYDROPYRANYL ETHERS | LEWIS-ACID | ORGANOMETALLIC REAGENT | ONE-POT | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | AMPHIPHILIC ALLYLATION | HOMOALLYL ALCOHOLS | CATALYZED MULTICOMPONENT CONNECTION
Journal Article
Synthetic Communications, ISSN 0039-7911, 05/2011, Volume 41, Issue 11, pp. 1664 - 1671
The indium-mediated Barbier-type allylation reaction of aldehydes with allyl bromide, which gives corresponding homoallyl alcohols, was investigated. The... 
indium | allylation reaction | Aldehydes | aqueous reaction | homoallyl alcohols | Allylation reaction | Aqueous reaction | Homoallyl alcohols | Indium | CARBON BOND FORMATION | ORGANIC-REACTIONS | CHEMISTRY, ORGANIC | SUGARS | WATER
Journal Article
Chinese Journal of Chemistry, ISSN 1001-604X, 11/2014, Volume 32, Issue 11, pp. 1095 - 1098
An unprecedented protocol has been developed for the efficient synthesis of substituted tetrahydropyrans via a bismuth‐promoted Prins cyclization of imines... 
Lewis acid | tetrahydropyrans | homoallyl alcohol | imine | Prins cyclization | Homoallyl alcohol | Imine | Tetrahydropyrans | ALDIMINES | BIS-ARYLATION | ONE-POT | LEWIS ACIDITY | CHEMISTRY, MULTIDISCIPLINARY | CYANOBACTERIA | ENHANCEMENT | N-TOSYL | CONDENSATION | FRIEDEL-CRAFTS REACTION | DIPYRROMETHANES | Schiff bases
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2017, Volume 2017, Issue 23, pp. 3343 - 3354
trans ‐2,3‐Diaryl(heteroaryl)‐dihydropyrans were synthesized by an allylboration/ring‐closing‐metathesis sequence, using allylboranes formed in situ from the... 
Heterocycles | Dihydropyrans | Allylic compounds | Cyclization | Tetrahydropyrans | Metathesis | GLYCOSIDES | CATALYZED SYNTHESIS | C-GLYCOSYLATION | CHEMISTRY, ORGANIC | ALDEHYDES | CROSS-COUPLING APPROACH | ARYLBORONIC ACIDS | HOMOALLYL ALCOHOLS | ALLYL ALCOHOLS | ARYL | STEREOSELECTIVE-SYNTHESIS | Synthesis | Aromatic compounds | Decomposition reactions | Alcohols
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2010, Volume 49, Issue 44, pp. 8169 - 8172
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 01/2018, Volume 83, Issue 2, pp. 980 - 992
A reliable protocol to synthesize both racemic and chiral (E)-4-iodobut-3-en-1-ols from aldehydes or epoxides, respectively, containing various aromatic and... 
REAGENT | HOMOPROPARGYLIC ALCOHOLS | KETONE | RING-CLOSING METATHESIS | LACTONES | HOMOALLYL ALCOHOLS | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | MEDIATED REACTIONS | MACROCYCLIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 45, pp. 14106 - 14110
Journal Article