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Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 21, pp. 6695 - 6700
An operationally convenient and general method for hydroboration of alkenes, aldehydes, and ketones employing Co­(acac)3 as a precatalyst is reported. The... 
STYRENES | COMPLEXES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | MARKOVNIKOV-SELECTIVE HYDROBORATION | ARYL ALKENES | PINACOLBORANE | ISOMERIZATION-HYDROBORATION | ASYMMETRIC HYDROBORATION | TERMINAL SELECTIVITY | EFFICIENT HYDROBORATION
Journal Article
Synlett, ISSN 0936-5214, 07/2018, Volume 29, Issue 11, pp. 1421 - 1429
Abstract Incorporation of the boryl moiety across a carbon–carbon multiple bond is a powerful method for the synthesis of organoboron compounds. This kind of... 
account | cobalt | organoboronates | alkenes | alkynes | borylation | DEHYDROGENATIVE BORYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | RHODIUM(I)-CATALYZED HYDROBORATION | C-H ACTIVATION | ASYMMETRIC HYDROBORATION | SELECTIVE HYDROBORATION | 1,1-DISUBSTITUTED ARYL ALKENES | ISOMERIZATION-HYDROBORATION | ENANTIOSELECTIVE HYDROBORATION | METHANETRIBORONIC ESTERS
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 01/2018, Volume 42, Issue 20, pp. 16456 - 16459
A highly selective anti-Markovnikov hydroboration reaction of alkenes with bis(pinacolato)diboron catalyzed by 4-cyanopyridine has been described. This... 
Hydroboration | Alkenes
Journal Article
MOLECULES, ISSN 1420-3049, 09/2019, Volume 24, Issue 17, p. 3194
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2017, Volume 53, Issue 34, pp. 4726 - 4729
A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as... 
Selectivity | Hydroboration | Alkenes | Catalysts | Cobalt
Journal Article
RSC Advances, ISSN 2046-2069, 08/2015, Volume 5, Issue 90, pp. 73705 - 73713
The first ligand-free ferrous chloride catalyzed anti-Markovnikov hydroboration of un-activated aryl alkenes with bis(pinacolato) diboron (B(2)pin(2)) has been... 
REGIOSELECTIVE HYDROBORATION | CROSS-COUPLING REACTION | VINYL ARENES | RHODIUM-CATALYZED HYDROBORATION | BIS(IMINO)PYRIDINE IRON | RHODIUM(I)-CATALYZED HYDROBORATION | H BOND FUNCTIONALIZATION | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE HYDROBORATION | ALKYL-HALIDES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2017, Volume 2017, Issue 38, pp. 5814 - 5818
Cobalt(II) catalysts based on flexible PNP or NNN ligands were explored for the regioselective hydroboration of alkenes. A known CoII–PNP pincer complex was... 
N ligands | Hydroboration | Homogeneous catalysts | Alkenes | Regioselectivity | Cobalt | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | IRON | ASYMMETRIC HYDROBORATION | ALCOHOLS | 1,1-DISUBSTITUTED ALKENES | AMINES | MARKOVNIKOV-SELECTIVE HYDROBORATION | ARYL ALKENES | ISOMERIZATION-HYDROBORATION | C=N BONDS | Olefins
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2017, Volume 7, Issue 5, pp. 3730 - 3734
A chemoselective hydroboration protocol with terminal alkene substrates is reported using an electron-rich, low-valent cobalt pincer compound. The process is... 
catalysis | cobalt | nitrile | hydroboration | chemoselective | alkene | FORMAL HYDROBORATION | CONJUGATED DIENES | CHEMISTRY, PHYSICAL | IRON | ALKYNES | 1,1-DISUBSTITUTED ALKENES | SELECTIVE HYDROGENATION | PINCER COMPLEXES | PRIMARY AMINES | ARYL ALKENES | ENANTIOSELECTIVE HYDROBORATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 11, pp. 4035 - 4038
A simple silver salt (AgOAc)-catalyzed anti-Markov-nikov-selective hydroboration of alkenes, 1,3-dienes, and alkynes with pinacolborane (HBpin) has been... 
SELECTIVE HYDROBORATION | COBALT CATALYSTS | INSERTION | COUPLING REACTIONS | COMPLEXES | CHEMISTRY, ORGANIC | IRON | ALKYNES | ASYMMETRIC HYDROBORATION | ORGANOBORANES | ALKENE HYDROBORATION
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2016, Volume 52, Issue 35, pp. 5916 - 5919
A new method has been developed for the Markovnikov hydroboration of alkyl-substituted terminal alkenes. Notably, the use of a bulky bisphosphine-copper(I)... 
TERTIARY BORONIC ESTERS | REGIOSELECTIVE HYDROBORATION | VINYL ARENES | VINYLARENES | SECONDARY | REGIO | FLUORINATION | RHODIUM COMPLEXES | MONOBORYLATION | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | Hydroboration | Terminals | Alkenes | Catalysts | Compatibility | Functional groups
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 23, pp. 12857 - 12862
We report an operationally convenient room temperature hydroboration of aldehydes and ketones employing Fe­(acac)3 as precatalyst. The hydroboration of... 
SELECTIVE HYDROBORATION | CROSS-COUPLING REACTIONS | 1,1-DISUBSTITUTED ALKENES | ASYMMETRIC REDUCTION | ENANTIOSELECTIVE REDUCTION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | C-H ACTIVATION | HYDRIDE COMPLEXES | ORGANIC ELECTROPHILES | ALKENE HYDROBORATION | Iron compounds | Hydroboration | Ketones | Analysis | Chemical properties | Aldehydes | Electric properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14369 - 14372
Well‐defined manganese complexes based on inexpensive, readily available ligands, 2,2′:6′,2′′‐terpyridine and its derivatives have been prepared and employed... 
manganese catalysis | hydroboration | alkenes | carbonyl compounds | Markovnikov selectivity | COBALT CATALYSTS | HYDROSILYLATION | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL SELECTIVITY | CROSS-COUPLING REACTIONS | 1,1-DISUBSTITUTED ALKENES | ARYL ALKENES | ISOMERIZATION-HYDROBORATION | CARBON-DIOXIDE | GRIGNARD-REAGENTS | Ketones | Aldehydes | Catalysis
Journal Article
by Xi, Tuo and Lu, Zhan
ACS Catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 1181 - 1185
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2016, Volume 6, Issue 10, pp. 7217 - 7221
Two series of structurally related alkoxy-tethered NHC iron­(II) complexes have been developed as catalysts for the regioselective hydroboration of alkenes.... 
catalysis | iron | hydroboration | NHC ligands | Markovnikov selectivity | ROOM-TEMPERATURE | HYDROFUNCTIONALIZATION | 1,3,2-BENZODIOXABOROLE | HYDROSILYLATION | CHEMISTRY, PHYSICAL | ASYMMETRIC HYDROBORATION | EPSILON-CAPROLACTONE | HETEROCYCLIC CARBENE COMPLEXES | OLEFINS | RING-OPENING POLYMERIZATION | ALKENE HYDROBORATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 34, pp. 4726 - 4729
A bipyridiyl-oxazoline cobalt catalyst (BPOCoCl2)-B-tBu has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and... 
ALKENE ISOMERIZATION-HYDROBORATION | CHEMO | COMPLEXES | IRON | ALKYNES | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 6, pp. 1390 - 1393
A Cu-catalyzed highly Z-stereoselective hydroboration of alkynes with 1,8-naphthalene­diaminato­borane (HB­(dan)) is developed. DPEphos... 
FORMAL HYDROBORATION | CONVENIENT SYNTHESIS | SELECTIVE HYDROBORATION | MECHANISM | HYDROSILYLATION | ESTERS | CHEMISTRY, ORGANIC | RUTHENIUM | REGIO | STRYKERS REAGENT | HYDROSILATION
Journal Article
Organometallics, ISSN 0276-7333, 10/2016, Volume 35, Issue 20, pp. 3436 - 3439
First-row transition metal catalysis offers a cheaper, more environmentally sustainable alternative to second- and third-row transition metal catalysts. Nickel... 
PALLADIUM | CROSS-COUPLING REACTIONS | NONRIGID ORGANOMETALLIC MOLECULES | RHODIUM-CATALYZED HYDROBORATION | CHEMISTRY, ORGANIC | OLEFINS | PINACOLBORANE | ARYL | ASYMMETRIC HYDROBORATION | BORYLATION | ALKENE HYDROBORATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 05/2018, Volume 37, Issue 9, pp. 1462 - 1467
This paper describes a well-defined cobalt(II) half-sandwich complex bearing a phosphinoaminato ligand, Cp*Co(1,2-Ph2PC6H4NH) (1), that can activate... 
ALKENE ISOMERIZATION-HYDROBORATION | HYDROGENATION | PINCER COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | IRON CATALYST | METAL-LIGAND COOPERATION | ASYMMETRIC HYDROBORATION | ENANTIOSELECTIVE HYDROBORATION | TERMINAL SELECTIVITY | HYDRIDE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15501 - 15504
We report the synthesis of cobalt complexes of novel iminopyridine–oxazoline (IPO) ligands and their application to the asymmetric hydroboration of... 
ORGANIC-SYNTHESIS | STYRENES | DIHYDROXYLATION | HYDROGENATION | SUBSTITUTED VINYLARENES | OLEFINS | PINACOLBORANE | RHODIUM COMPLEXES | ASYMMETRIC HYDROBORATION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL SELECTIVITY | Hydroboration | Chemical properties | Research | Metal catalysts | Olefins
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 24, pp. 7840 - 7845
An NHC-supported Co­(I) catalyst has been developed for selective Markovnikov hydroboration of vinylarenes under mild reaction conditions. The hydroboration... 
REGIOSELECTIVE HYDROBORATION | ALKENE ISOMERIZATION-HYDROBORATION | COBALT CATALYSTS | COUPLING REACTIONS | CHEMISTRY, ORGANIC | CATALYTIC ASYMMETRIC HYDROBORATION | H BONDS | ALKYLBORONIC ESTERS | B-H | BORYLATION | ALKYL-HALIDES
Journal Article
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