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Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15501 - 15504
We report the synthesis of cobalt complexes of novel iminopyridine–oxazoline (IPO) ligands and their application to the asymmetric hydroboration of... 
Hydroboration | Chemical properties | Research | Metal catalysts | Olefins
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 18, pp. 5855 - 5858
A bis­(imino)­pyridine cobalt-catalyzed hydroboration of terminal alkynes with HBPin (Pin = pinacolate) with high yield and (Z)-selectivity for synthetically... 
Hydroboration | Catalysis | Research | Chemical properties | Cobalt
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2017, Volume 53, Issue 34, pp. 4726 - 4729
A bipyridiyl-oxazoline cobalt catalyst BPOCoCl has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaO Bu as the... 
Selectivity | Hydroboration | Alkenes | Catalysts | Cobalt
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2016, Volume 52, Issue 89, pp. 13155 - 13158
Magnesium bis(hydridotriphenylborate), isolated as a solvent-separated ion pair [Mg(thf) ][HBPh ] , effectively catalyzed the hydroboration of several... 
Hydroboration | Magnesium | Catalysts | Substrates | Ion pairs | Carbon dioxide
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2018, Volume 54, Issue 10, pp. 1233 - 1236
Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane heteroleptic lithium... 
Bimetals | Hydroboration | Ketones | Aluminum | Lithium | Catalysis | Aldehydes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 2, pp. 652 - 656
N-Heterocyclic phosphenium triflates (NHP-OTf) 1 serve as efficient catalysts for the regio- and chemoselective hydroboration of pyridines under ambient... 
Pyridine | Hydroboration | Analysis | Electric properties
Journal Article
New journal of chemistry, ISSN 1144-0546, 01/2018, Volume 42, Issue 20, pp. 16456 - 16459
A highly selective anti-Markovnikov hydroboration reaction of alkenes with bis(pinacolato)diboron catalyzed by 4-cyanopyridine has been described. This... 
Hydroboration | Alkenes
Journal Article
ACS catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 1244 - 1247
Rapid, clean hydroboration of ketones and aldehydes with HBpin is achieved using the homoleptic rare-earth catalyst La­[N­(SiMe3)2]3 (LaNTMS). The reaction... 
lanthanide | ketone/aldehyde reduction | chemoselective hydroboration | homogeneous catalysis | carbonyl hydroboration | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
Journal Article
Catalysis science & technology, ISSN 2044-4753, 5/2014, Volume 4, Issue 6, pp. 1699 - 179
This review summarizes the transformation of alkynes using a copper hydride (Cu-H) or boryl copper (Cu-B) species as the active species. The semihydrogenation,... 
Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology | Hydroboration | Synthesis | Alkenes | Transformations | Hydrides | Catalysis | Copper | Alkynes
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2015, Volume 51, Issue 77, pp. 14477 - 14480
A β-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC,... 
Hydroboration | Amines | Magnesium | Catalysis | Catalysts
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 12/2013, Volume 49, Issue 95, pp. 11230 - 11232
The highly chemo-, regio-, and stereoselective synthesis of alkyl- and vinyl boronic esters with good functional group tolerance has been developed using in... 
Hydroboration | Synthesis | Alkenes | Esters | Tolerances | Functional groups | Alkynes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2009, Volume 48, Issue 33, pp. 6062 - 6064
An existing challenge is the development of efficient regioselective catalytic systems that are compatible with stable hydroboration reagents and can be... 
pinacolborane | copper | asymmetric catalysis | hydroboration | styrene | Pinacolborane | Hydroboration | Copper | Asymmetric catalysis | Styrene
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2014, Volume 53, Issue 12, pp. 3241 - 3244
Journal Article
Letters in organic chemistry, ISSN 1570-1786, 05/2017, Volume 14, Issue 4, pp. 243 - 247
Journal Article
Journal of organometallic chemistry, ISSN 0022-328X, 01/2021, Volume 931
Catalytic dehydrogenative diboration (DHDB) of alkyne with HBpin was achieved using [Ir(COD)Cl]2 and other related Ir precursors under CO atmosphere. The... 
hydroboration | alkynes | catalysis | Iridium | diboration
Journal Article
Journal of organic chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 23, pp. 12857 - 12862
We report an operationally convenient room temperature hydroboration of aldehydes and ketones employing Fe­(acac)3 as precatalyst. The hydroboration of... 
Iron compounds | Hydroboration | Ketones | Analysis | Chemical properties | Aldehydes | Electric properties
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2020, Volume 56, Issue 46, pp. 6205 - 6208
This contribution reports on the reactivity of isothiocyanates towards the boranes B(C6F5)3 and HB(C6F5)2. The reactions of alkyl-substituted isothiocyanates... 
Hydroboration | Thiocyanates | Boranes | Crystallography | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2011, Volume 50, Issue 12, pp. 2778 - 2782
Hooray for hydroboration! The products afforded by the title reaction depend on the substitution pattern on the double bond moiety of 1,3‐enyne substrates (see... 
copper | asymmetric catalysis | hydroboration | enynes | boron
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2016, Volume 52, Issue 35, pp. 5916 - 5919
A new method has been developed for the Markovnikov hydroboration of alkyl-substituted terminal alkenes. Notably, the use of a bulky bisphosphine-copper(i)... 
Hydroboration | Terminals | Alkenes | Catalysts | Compatibility | Functional groups
Journal Article
ACS catalysis, ISSN 2155-5435, 06/2015, Volume 5, Issue 6, pp. 3238 - 3259
Organoborane compounds present a class of versatile synthetic intermediate for myriad organic transformations. The direct addition of a B–H bond across... 
boranes | CO 2 reduction | hydroboration | transition metal catalysis | main group catalysis | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
Journal Article
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