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hydrodefluorination (311) 311
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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 12, pp. 3328 - 3348
Journal Article
Chemical Society reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 4, pp. 765 - 774
Part of the renaissance in main group chemistry has been a result of the focus on reactivity. This has led to the development of applications in stoichiometric... 
Journal Article
Science, ISSN 0036-8075, 08/2008, Volume 321, Issue 5893, pp. 1168 - 1169
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 26, pp. 6663 - 6663
Hydrodefluorination reactions (HDF) of vinylic and aromatic C−F bonds by alanes in noncoordinating solvents can be catalyzed by O and N donors. We symbolized... 
aluminum hydrides | DFT | organocatalysts | homogeneous catalysis | hydrodefluorination
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2/2016, Volume 45, Issue 4, pp. 765 - 774
Part of the renaissance in main group chemistry has been a result of the focus on reactivity. This has led to the development of applications in stoichiometric... 
KETONES | ACTIVATION | MECHANISM | BONDS | CHEMISTRY | BORANE | SALTS | CHEMISTRY, MULTIDISCIPLINARY | B(C6F5)-CATALYZED HYDROSILYLATION | HYDRODEFLUORINATION | PAIRS | Lewis acid | Phosphorus | Catalysis
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 10/2018, Volume 13, Issue 19, pp. 2908 - 2915
The gallium hydrides (iBu)2GaH (1 a), LiGaH4 (1 b) and Me3N⋅GaH3 (1 c) hydrodefluorinate vinylic and aromatic C−F bonds when O and N donor molecules are... 
hydrides | density functional calculations | gallium | homogeneous catalysis | hydrodefluorination | COMPLEXES | PHOTOCATALYTIC HYDRODEFLUORINATION | CHEMISTRY, MULTIDISCIPLINARY | HYDROGALLATION REACTIONS | NUCLEOPHILIC AROMATIC-SUBSTITUTION | LEWIS-BASE-ADDUCTS | MAGNETIC-RESONANCE | CHEMISTRY | FLUORINE | METAL | TEMPERATURE CATALYTIC HYDRODEFLUORINATION | Catalysis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 03/2015, Volume 51, Issue 25, pp. 5359 - 5362
The syntheses of unsymmetrical N-heterocyclic carbenes (NHCs) that contain a single N-bound icosahedral carborane anion substituent are reported. Both anionic... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2012, Volume 18, Issue 34, pp. 10701 - 10714
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 1, pp. 163 - 166
We describe a new catalytic approach to selective functionalization of the strong C–F bonds in trifluoromethylaromatic (Ar–CF3) systems. In this approach,... 
F BOND-CLEAVAGE | ACTIVATION | REDUCTION | ACIDS | ION | GENERATION | CHEMISTRY, MULTIDISCIPLINARY | HYDRODEFLUORINATION | Argon | Fluorine | Analysis | Alkylation | Electric properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2016, Volume 138, Issue 16, pp. 5250 - 5253
The [Ni­(IMes)2]-catalyzed transformation of fluoroarenes into arylboronic acid pinacol esters via C–F bond activation and transmetalation with... 
FUNCTIONALIZATION | ROOM-TEMPERATURE | CROSS-COUPLING REACTIONS | ACTIVATION | H BORYLATION | ARYL HALIDES | COMPLEXES | ALKOXY DIBORON REAGENTS | FLUOROPYRIDINES | CHEMISTRY, MULTIDISCIPLINARY | HYDRODEFLUORINATION | Nickel compounds | Catalysis | Chemical synthesis | Analysis
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 05/2019, Volume 55, Issue 39, pp. 5599 - 5602
The readily-accessible, air-stable Lewis acid [(terpy) PPh][B(C6F5)(4)](2) 1 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The... 
TERPYRIDINE | ACTIVATION | HYDROGENATION | LEWIS-ACID | COMPLEXES | ELECTROPHILIC PHOSPHONIUM CATIONS | REACTIVITY | POLYMERIZATION | TETRAHYDROFURAN | CHEMISTRY, MULTIDISCIPLINARY | HYDRODEFLUORINATION
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2014, Volume 50, Issue 84, pp. 12619 - 12622
Taking advantage of two N-heterocyclic carbenes (NHCs), novel silyliumylidene ions 1a and 1b are prepared by a facile one-pot reaction of the corresponding... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 36, pp. 4589 - 4592
It has been reported that pulsed irradiation can improve photosynthetic activity and phytochemical production in plants. Intrigued and inspired by these... 
SYSTEM | LIGHT PHOTOREDOX CATALYSIS | ELECTRON | FACILE ACCESS | CHEMISTRY, MULTIDISCIPLINARY | HYDRODEFLUORINATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 27, pp. 9564 - 9567