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Macromolecules, ISSN 0024-9297, 04/2018, Volume 51, Issue 7, pp. 2621 - 2629
We report that the anionic polymerization of P-mesityl and m-xylyl-substituted phosphaalkenes follows an unusual addition–isomerization mechanism.... 
MONOMERS | POLYMER SCIENCE | BLOCK-COPOLYMERS | BEHAVIOR | PHOSPHINE POLYMERS | P=C BONDS | ACRYLAMIDE | CARBON-CARBON BONDS | PHOSPHAALKENES | EXCHANGE | HYDROGEN-TRANSFER POLYMERIZATION
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 05/2011, Volume 40, Issue 5, pp. 2189 - 2198
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a lot of investigations have focused on the kinetics of this process.... 
MODEL ALKOXYAMINES | ON BOND HOMOLYSIS | METHYL-METHACRYLATE | SG1-BASED ALKOXYAMINES | HYDROGEN-TRANSFER | RATE CONSTANTS | FREE-RADICAL POLYMERIZATION | RATE ENHANCEMENT | INITIATING ALKOXYAMINE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-CENTERED RADICALS
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 12/2019, Volume 57, Issue 24, pp. 2415 - 2419
ABSTRACT Anionic hydrogen‐transfer homopolymerization of N‐isopropylacrylamide (NIPAAm) was carried out using t‐BuOK as an initiator in DMF under microwave... 
N‐isopropylacrylamide | microwave irradiation | hydrogen‐transfer polymerization | lower critical solution temperature | anionic polymerization | Acrylamide | Isopropylacrylamide | Hydrogen | Irradiation | Polymerization | Anionic polymerization | Copolymerization | Temperature control | Polymers
Journal Article
Polymer Chemistry, ISSN 1759-9954, 10/2018, Volume 9, Issue 38, pp. 4716 - 4723
This paper reports a new type of click chemistry via a phosphazene bases-catalyzed oxa-Michael addition of an alcohol to an acrylate. The studies on the... 
DIVINYL SULFONE | POLYMER SCIENCE | HYPERBRANCHED POLYMERS | ALLYL PENDENT GROUPS | ANIONIC-POLYMERIZATION | INITIATING SYSTEM | CHEMISTRY | ACRYLIC-ACID | RING-OPENING POLYMERIZATION | METHACRYLATE | HYDROGEN-TRANSFER POLYMERIZATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2016, Volume 138, Issue 6, pp. 2021 - 2035
Journal Article
Polymer Chemistry, ISSN 1759-9954, 07/2013, Volume 4, Issue 13, pp. 3744 - 3754
The mechanism of the nitroxide mediated polymerization (NMP) is well understood, however less is known about the side-reactions that interfere and in certain... 
MODEL ALKOXYAMINES | RATE COEFFICIENTS | POLYMER SCIENCE | BOND HOMOLYSIS | METHYL-METHACRYLATE | PENULTIMATE UNIT | BUTYL ACRYLATE | FREE-RADICAL POLYMERIZATION | HYDROGEN-TRANSFER REACTION | END-GROUP FIDELITY | THERMAL-DECOMPOSITION | Addition polymerization | Quantum chemistry | Styrenes | Polymerization | Mathematical models | Models | Modelling | Failure
Journal Article
Macromolecules, ISSN 0024-9297, 03/2016, Volume 49, Issue 6, pp. 2039 - 2045
Mechanistic insights into bulk hydrogen-transfer polymerization of acrylamide initiated by t-BuONa are proposed in this study where attention is particularly... 
POLY-BETA-ALANINE | THERMAL-DEGRADATION | BASE-CATALYZED POLYMERIZATION | MONOMERS | POLYMER SCIENCE | TRANSITION POLYMERIZATION | RING-OPENING POLYMERIZATION | DERIVATIVES | ISOCYANATE | HYDROGEN-TRANSFER POLYMERIZATION | NYLON-3 | Polymers | Chemical Sciences
Journal Article
Industrial & Engineering Chemistry Research, ISSN 0888-5885, 04/2017, Volume 56, Issue 15, pp. 4207 - 4219
Aliphatic polyesters are important biodegradable polymers with wide applications. Polyesters prepared by ring-opening polymerization often have a limited range... 
PHTHALIC-ANHYDRIDE | ENGINEERING, CHEMICAL | PROTON-TRANSFER POLYMERIZATION | ALTERNATING COPOLYMERIZATION | CYCLIC ANHYDRIDES | BAEYER-VILLIGER OXIDATION | RING-OPENING POLYMERIZATION | N-HETEROCYCLIC CARBENES | L-LACTIC ACID | HYDROGEN-TRANSFER POLYMERIZATION | TRICYCLIC ANHYDRIDES ACCESS
Journal Article
Polymer Chemistry, ISSN 1759-9954, 01/2019, Volume 10, Issue 1, pp. 106 - 113
The alkoxyamine 3-(((2-cyanopropan-2-yl)oxy)(cyclohexyl)amino)-2,2-dimethyl-3-phenylpropanenitrile (Dispolreg 007) has recently emerged as a robust regulator... 
POLYMER SCIENCE | TERMINATION RATE COEFFICIENTS | LENGTH-DEPENDENT TERMINATION | ON BOND HOMOLYSIS | POLY(METHYL METHACRYLATE) | BLOCK-COPOLYMERS | METHYL-METHACRYLATE | REVERSIBLE COMBINATION | HYDROGEN-TRANSFER | FREE-RADICAL POLYMERIZATION | ALPHA-CARBON
Journal Article
Organometallics, ISSN 0276-7333, 11/2001, Volume 20, Issue 24, pp. 5076 - 5083
The reaction of 2,2‘-methylenebis(4-chloro-6-isopropyl-3-methylphenol) (MCIMP-H2) with 1.2 molar equiv of AlMe3 in THF yields [(MCIMP)AlMe(THF)] (1), which... 
ARYLOXIDE COMPOUNDS | LACTIDE POLYMERIZATION | EPSILON-CAPROLACTONE | ALKOXIDES | LEWIS-ACID | HYDROGEN-TRANSFER | LIVING POLYMERIZATION | CHEMISTRY, ORGANIC | POLY(LACTIC ACID) | IMMORTAL POLYMERIZATIONS | ALUMINUM PORPHYRINS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
POLYMER CHEMISTRY, ISSN 1759-9954, 01/2020, Volume 11, Issue 2, pp. 593 - 604
The SG1-mediated solution polymerization of methyl methacrylate (MMA) and oligo(ethylene glycol) methacrylate (OEGMA, M-n = 300 g mol(-1)) in the presence of a... 
SIDE-CHAINS | POLYMER SCIENCE | FACILE SYNTHESIS | 2-HYDROXYETHYL ACRYLATE | METHYL-METHACRYLATE | AMPHIPHILIC BLOCK-COPOLYMERS | CLICK CHEMISTRY | HYDROGEN-TRANSFER | FREE-RADICAL POLYMERIZATION | SURFACE | CONTROL AGENTS
Journal Article
Macromolecules, ISSN 0024-9297, 05/2015, Volume 48, Issue 9, pp. 2909 - 2915
In radical polymerization of acrylic monomers, intramolecular transfer to polymer, and the reactions of the resulting midchain radical, can have a strong... 
SEMIBATCH EMULSION POLYMERIZATION | POLYMER SCIENCE | N-BUTYL ACRYLATE | METHYL-METHACRYLATE | INTRAMOLECULAR CHAIN TRANSFER | ALKYL ACRYLATES | HYDROGEN-TRANSFER | STRUCTURAL-PROPERTIES | PROPAGATING RADICALS | COMPETITIVE PROCESSES | SECONDARY REACTIONS
Journal Article
Macromolecules, ISSN 0024-9297, 01/2010, Volume 43, Issue 1, pp. 107 - 116
Anionic polymerization of a series of N,N -dialkylmethacrylamides such as N-methacryloylazetidine (M4), N-methacryloylpyrrolidine (M5), and... 
MONOMERS | POLYMER SCIENCE | NITROGEN INVERSION | METALLOCENE CATALYSTS | METHYL-METHACRYLATE | SUBSTITUTED ACRYLAMIDES | RADICAL POLYMERIZATION | FUNCTIONAL-GROUPS | AZIRIDINES | HYDROGEN-TRANSFER POLYMERIZATION | AMIDES
Journal Article
Russian Chemical Reviews, ISSN 0036-021X, 2018, Volume 87, Issue 4, pp. 328 - 349
Controlled, or pseudoliving, radical polymerization provides unique opportunities for the synthesis of structurally diverse polymers with a narrow molecular... 
MODEL ALKOXYAMINES | RATE COEFFICIENTS | METHYL-METHACRYLATE | RATE CONSTANTS | FRAGMENTATION CHAIN-TRANSFER | ATOM-TRANSFER | HYDROGEN-TRANSFER REACTION | C-ON BOND | INITIATING ALKOXYAMINE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-CENTERED RADICALS
Journal Article