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Organometallics, ISSN 0276-7333, 05/2012, Volume 31, Issue 10, pp. 3825 - 3828
Iron complexes formulated as Fe­(terpy)­X2 (terpy = 2,2′:6′,2″-terpyridine derivatives; X = Cl, Br) were prepared and their catalytic activities for... 
CHEMISTRY, ORGANIC | HYDROGENATION | HYDROSILATION | ALKYNES | SILYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
1992, ISBN 9780080402727, xi, 754
Book
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2008, Issue 14, pp. 1701 - 1703
The Lewis acid B(C6F5)(3) has been found to be an efficient catalyst for the direct hydrogenation of imines and the reductive ring-opening of aziridines with... 
HYDROSTANNATION | ACTIVATION | DIHYDROGEN | MECHANISM | B(C6F5)-CATALYZED HYDROSILATION | ORGANOCATALYTIC TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 6, pp. 1390 - 1393
A Cu-catalyzed highly Z-stereoselective hydroboration of alkynes with 1,8-naphthalene­diaminato­borane (HB­(dan)) is developed. DPEphos... 
FORMAL HYDROBORATION | CONVENIENT SYNTHESIS | SELECTIVE HYDROBORATION | MECHANISM | HYDROSILYLATION | ESTERS | CHEMISTRY, ORGANIC | RUTHENIUM | REGIO | STRYKERS REAGENT | HYDROSILATION
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2014, Volume 50, Issue 40, pp. 5270 - 5272
In the presence of B(C6F5)(3) five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak... 
CATALYSIS | ETHERS | REDUCTION | MECHANISM | SILANES | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 05/2019, Volume 48, Issue 17, pp. 5534 - 5540
The utility of a bipyridine periodic mesoporous organosilica, BPy-PMO, as a support material of a hydrosilylation catalyst was investigated in the... 
OXIDATION | HYDROSILATION | SILICA | ALKYNES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chem. Sci, ISSN 2041-6520, 2014, Volume 5, Issue 3, pp. 959 - 964
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2016, Volume 6, Issue 1, pp. 290 - 300
The demand for economical and environmentally benign catalysts for important chemical transformations has recently initiated great efforts on nonprecious... 
selectivity | hydrosilylation | alkyne | cobalt | alkene | NICKEL-COMPLEXES | MECHANISM | SILICON HYDRIDES | CHEMISTRY, PHYSICAL | IRON CATALYSTS | REGIOSELECTIVE HYDROSILYLATION | ELECTRONIC-STRUCTURES | HOMOGENEOUS CATALYSIS | BOND ACTIVATION | HYDROSILATION | METAL-COMPLEXES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 49, pp. 18308 - 18310
Organofluorophosphonium salts of the formula [(C6F5)3–x Ph x PF][B(C6F5)4] (x = 0, 1) exhibit Lewis acidity derived from a low-lying σ* orbital at P opposite... 
ACTIVATION | CARBON | MECHANISM | COMPLEXES | SILICON | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | B(C6F5)-CATALYZED HYDROSILYLATION | Organofluorine compounds | Chemical properties | Research | Olefins | Isomerization
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 04/2016, Volume 35, Issue 7, pp. 1030 - 1035
The hydrosilylation/reduction of tertiary and secondary phosphine oxides to phosphines is catalyzed by B(C6F5)(3) or electrophilic fluorophosphonium cations... 
REAGENT | HYDROGENATION | MECHANISM | CONVERSION | HYDROSILYLATION | SECONDARY | CHEMISTRY, ORGANIC | HYDROSILATION | TRIPHENYLPHOSPHINE | TERTIARY | SELECTIVITY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2015, Volume 137, Issue 41, pp. 13244 - 13247
Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. We report a Co catalyst for... 
HYDROBORATION | TRANSITION-METAL-COMPLEXES | SILICON HYDRIDES | OLEFINIC DOUBLE BONDS | ISOMERIZATION | HOMOGENEOUS CATALYSIS | RECENT PROGRESS | IRON CATALYSTS | STEREOSELECTIVE HYDROSILYLATION | HYDROSILATION REACTION | CHEMISTRY, MULTIDISCIPLINARY | Metal catalysts | Usage | Isomerization
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 11/2017, Volume 50, Issue 11, pp. 2842 - 2852
Conspectus In recent years, interest in homogeneous manganese catalyst development has intensified because of the earth-abundant and nontoxic nature of this... 
KETONE HYDROSILYLATION | ASYMMETRIC HYDROSILYLATION | ORGANIC-SYNTHESIS | ENANTIOSELECTIVE EPOXIDATION | HYDROGENATION | REDUCTION | WELL-DEFINED MANGANESE | COMPLEXES | HYDROSILATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14523 - 14526
Chemoselective hydrosilylation of functionalized alkenes is difficult to achieve using base‐metal catalysts. Reported herein is that well‐defined... 
silanes | chemoselectivity | nickel | pincer ligands | alkenes | HYDROBORATION | IRON CATALYSTS | NONACTIVATED ALKYL-HALIDES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE COMPLEX | LIGANDS | HOMOGENEOUS CATALYSIS | RECENT PROGRESS | HYDROSILATION | GRIGNARD-REAGENTS | METAL-COMPLEXES | Nickel
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 03/2010, Volume 132, Issue 9, pp. 3038 - 3046
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(C=CH2)CMe(NAr)(2)]; Ar = 2,6-(PrC6H3)-Pr-i) versus its LSi ->... 
HYDROGEN | DIHYDROGEN | AMMONIA | OLEFIN-METATHESIS CATALYSTS | CARBENES | COMPOUND | REACTIVITY | GERMYLENE | HYDROSILATION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Yang, ZZ and Yu, B and Zhang, HY and Zhao, YF and Ji, GP and Ma, ZS and Gao, X and Liu, ZM
GREEN CHEMISTRY, ISSN 1463-9262, 2015, Volume 17, Issue 8, pp. 4189 - 4193
B(C6F5)(3) was proven to be an efficient metal-free catalyst for the methylation of amines using CO2 as a C1 building block in the presence of hydrosilanes... 
COMPLEX | MECHANISM | REDUCTION | MOLECULAR-HYDROGEN | CATALYTIC METHYLATION | HYDROSILATION | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Science, ISSN 2041-6520, 2015, Volume 6, Issue 12, pp. 7143 - 7149
Combined experimental and theoretical analysis of the carbonyl hydrosilylation catalysed by an iron(0) pincer complex reveals an unprecedented mechanism of... 
KETONES | SILYLENE | HYDROGENATION | LIGANDS | REDUCTION | REACTIVITY | RUTHENIUM | HYDROSILATION | INSIGHT | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 34, pp. 12108 - 12118
The aryl-substituted bis­(imino)­pyridine cobalt methyl complex, (MesPDI)­CoCH3 (MesPDI = 2,6-(2,4,6-Me3C6H2-NCMe)2C5H3N), promotes the catalytic... 
ELECTRONIC-STRUCTURES | CARBONYL-COMPLEXES | HYDROGENATION | IRON CATALYSTS | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | ANTI-HYDROSILYLATION | RUTHENIUM COMPLEX | TERMINAL ALKENES | SIGMA-BOND METATHESIS | VINYL-SILANES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2014, Volume 136, Issue 50, pp. 17414 - 17417
A three-coordinate cobalt­(I) complex exhibits high catalytic efficiency and selectivity as well as good functional group compatibility in alkyne... 
MECHANISM | LIGANDS | ISOMERIZATION | RECENT PROGRESS | IRON | INTERNAL ALKYNES | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALKENE HYDROGENATION | C COUPLING REACTIONS | METAL-COMPLEXES | Hydrogen | Chemical properties | Electric properties
Journal Article
by Li, W and Werner, T
ORGANIC LETTERS, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2568 - 2571
The Michael reaction is a widely used reaction for the C-C coupling of electron-poor olefins and C(sp(3))-H pronucleophiles. Herein we report the Michael... 
KETONES | HYDROGENATION | DIHYDROGEN | MECHANISM | CONSTRUCTION | CHEMISTRY, ORGANIC | HYDROSILATION | PARALLEL SYNTHESIS | SILYLATION | CATALYSTS | CONJUGATE ADDITION
Journal Article
Chemical Communications, ISSN 1359-7345, 08/2012, Volume 48, Issue 63, pp. 7844 - 7846
Unsaturated cyclic ethers can be mildly and selectively reduced with catalytic amounts of B(C6F5)(3) in the presence of an alkylsilane. The allylic position is... 
HYDROSILATION | MECHANISM | CLEAVAGE | RING-EXPANSION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
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