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Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 30, pp. 10708 - 10717
The full mechanism of the hydroboration of CO2 by the highly active ambiphilic organocatalyst 1-Bcat-2-PPh2–C6H4 (Bcat = catecholboryl) was determined using... 
HOMOGENEOUS HYDROGENATION | FORMIC-ACID | N-HETEROCYCLIC CARBENE | CARBON-DIOXIDE FIXATION | CATALYTIC-REDUCTION | MOLECULAR-ORBITAL METHODS | CONVERSION | COMPLEXES | HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | BASE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2008, Volume 47, Issue 32, pp. 5997 - 6000
Just ask silicon: An experimentally straightforward yet effective Walden‐type analysis showcases the usefulness of silanes with a stereogenic silicon center as... 
hydrosilylation | Lewis acids | reaction mechanisms | silicon | nucleophilic substitution | Hydrosilylation | Silicon | Nucleophilic substitution | Reaction mechanisms
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2012, Volume 134, Issue 29, pp. 12266 - 12280
On the basis of a kinetic study and other evidence, we propose a mechanism of activation and operation of a highly active system generated from the precatalyst... 
TETRADENTATE LIGAND | KETONES | N-N-P | DEHYDROGENATION | HYDROSILYLATION | RESOLUTION | RUTHENIUM COMPLEXES | CATALYTIC TRANSFER HYDROGENATION | HOMOGENEOUS CATALYSIS | SCALE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 19, pp. 6912 - 6915
New experimental findings suggest partial revision of the currently accepted mechanism of the carbonyl hydrosilylation catalyzed by the iridium(III) pincer... 
KETONES | HYDROSILATION | REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | B(C6F5)-CATALYZED HYDROSILYLATION | HYDRIDE | Racemization | Electron configuration | Research | Iridium | Analysis | Silane
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2014, Volume 20, Issue 3, pp. 839 - 845
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2011, Volume 133, Issue 17, pp. 6487 - 6489
A 1:1:1 reaction between complex (Tp)(ArN)Mo(H)(PMe3) (3), silane PhSiD3, and carbonyl substrate established that hydrosilylation catalyzed by 3 is not... 
KETONE HYDROSILYLATION | ENANTIOSELECTIVE HYDROSILYLATION | LIGANDS | ASYMMETRIC HYDROSILYLATIONS | COMPLEXES | CARBONYL-COMPOUNDS | ARYL KETONES | ALDEHYDES | CHIRAL TITANOCENE CATALYST | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | Deuterium | Chemical reactions | Chemical properties | Analysis | Electric properties
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2010, Volume 46, Issue 41, pp. 7831 - 7833
Complex (Cp)(ArN=)Mo(H)(PMe3) (2, Ar = 2,6-diisopropylphenyl) catalyzes the hydrosilylation of carbonyls by an unexpected associative mechanism. Complex 2 also... 
IMIDO COMPLEXES | KETONES | ENANTIOSELECTIVE HYDROSILYLATION | ACTIVATION | VALENT | DFT | REDUCTION | MOLYBDENUM | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | SIGMA-BOND METATHESIS
Journal Article
Chemical Science, ISSN 2041-6520, 07/2015, Volume 6, Issue 7, pp. 4324 - 4334
The nature of the hydrosilane activation mediated by ruthenium(II) thiolate complexes of type [(R3P)-Ru(SDmp)](+)[BAr4F]- is elucidated by an in-depth... 
RHENIUM COMPLEXES | COORDINATED DINITROGEN | BASE-FREE | RUTHENIUM COMPLEXES | CARBONYL-COMPOUNDS | CATALYTIC HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | DITANTALUM COMPLEX | HYDRIDE COMPLEXES | B(C6F5)-CATALYZED HYDROSILYLATION | LIGAND COOPERATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2017, Volume 56, Issue 29, pp. 8393 - 8397
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2005, Volume 127, Issue 44, pp. 15374 - 15375
The rhenium oxo complex [Re(O)(hoz)2][TFPB], 1 (where hoz = 2-(2‘-hydroxyphenyl)-2-oxazoline(−) and TFPB = tetrakis(pentafluorophenyl)borate) catalyzes the... 
KETONES | IONIC HYDROGENATIONS | MOLYBDENUM | HYDROSILYLATION | HOMOGENEOUS CATALYSIS | BOND | CHEMISTRY, MULTIDISCIPLINARY | CATIONS | Oxo compounds | Carbonyl compounds | Chemical properties | Hydroxylation | Structure | Observations
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 44, pp. 14079 - 14084
The reduction of CO groups with silanes catalyzed by electron‐deficient boranes follows a counterintuitive mechanism in which the SiH bond is activated by... 
hydrosilylation | Lewis acids | reaction mechanisms | silicon | boron | FREE HYDROGEN ACTIVATION | CARBON | B(C6F5)-CATALYZED HYDROSILATION | REACTIVITY | FRUSTRATED LEWIS PAIRS | CYCLIC SILANES | H-2 | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC HYDROGENATION | CONFIGURATIONS | Schiff bases | Silicon | Chemical tests and reagents | Silane | Atoms & subatomic particles
Journal Article
Journal of Computational Chemistry, ISSN 0192-8651, 07/2019, Volume 40, Issue 19, pp. 1772 - 1779
Usually, an extra catalyst (for example, the transition metal complexes) need to be used in catalyzing hydroboration, which involved the cost, environment, and... 
anti‐ or Markovnikov hydroboration | external electric field | greener catalyst | PATH | COMPLEX | HYDROGENATION | HYDROSILYLATION | ALDEHYDES | ALKYNES | HYDROTHIOLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | SOLVENT-FREE | OLEFINS | anti- or Markovnikov hydroboration | Schiff bases | Electric fields
Journal Article