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hydrotrifluoromethylation (66) 66
chemistry, organic (44) 44
alkenes (35) 35
chemistry, multidisciplinary (30) 30
trifluoromethylation (28) 28
fluorine (27) 27
unactivated alkenes (26) 26
catalysis (24) 24
efficient (19) 19
photoredox catalysis (18) 18
oxytrifluoromethylation (16) 16
catalytic hydrotrifluoromethylation (15) 15
alkynes (14) 14
difunctionalization (14) 14
index medicus (14) 14
radical trifluoromethylation (14) 14
bond formation (13) 13
photocatalysis (13) 13
copper-catalyzed trifluoromethylation (12) 12
functionalization (12) 12
arenes (11) 11
molecular structure (11) 11
olefins (11) 11
oxidative trifluoromethylation (11) 11
alkene (10) 10
organic chemistry (10) 10
alkenes - chemistry (8) 8
electrophilic trifluoromethylation (8) 8
hydrocarbons, fluorinated - chemistry (8) 8
perfluoroalkylation (8) 8
radicals (8) 8
aryl (7) 7
chemistry (7) 7
construction (7) 7
fluorination (7) 7
light photoredox catalysis (7) 7
methylation (7) 7
photochemistry (7) 7
styrenes (7) 7
visible light (7) 7
3-component oxytrifluoromethylation (6) 6
acids (6) 6
bond-formation (6) 6
cyclization (6) 6
hydrocarbons, fluorinated - chemical synthesis (6) 6
medicinal chemistry (6) 6
organic-synthesis (6) 6
reagent (6) 6
reagents (6) 6
terminal alkenes (6) 6
allylic alcohols (5) 5
chemical sciences (5) 5
chemical-radical (5) 5
chemisches radikal (5) 5
chemistry, physical (5) 5
copper (5) 5
copper - chemistry (5) 5
generation (5) 5
heteroarenes (5) 5
heterocycles (5) 5
light (5) 5
photoredox (5) 5
trifluoromethylation reactions (5) 5
activated alkenes (4) 4
aminotrifluoromethylation (4) 4
bonds (4) 4
c-h trifluoromethylation (4) 4
carboxylic-acids (4) 4
complexes (4) 4
derivatives (4) 4
difluoroalkylation (4) 4
fluoroalkylation (4) 4
oxidation (4) 4
perfluoroalkyl iodides (4) 4
photoredox-catalyzed trifluoromethylation (4) 4
radical (4) 4
sodium trifluoromethanesulfinate (4) 4
transfer radical-addition (4) 4
usage (4) 4
visible-light (4) 4
alcohols (3) 3
aldehydes (3) 3
alpha,beta-unsaturated carboxylic-acids (3) 3
arylation (3) 3
aryltrifluoromethylation (3) 3
c-h (3) 3
c-h functionalization (3) 3
carbonyl-compounds (3) 3
catalyzed trifluoromethylation (3) 3
chemical properties (3) 3
chemistry, inorganic & nuclear (3) 3
complex (3) 3
enantioselective alpha-trifluoromethylation (3) 3
esters (3) 3
facile synthesis (3) 3
fluorine - chemistry (3) 3
hydrogen (3) 3
iodides (3) 3
light-radiation (3) 3
mild (3) 3
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Accounts of Chemical Research, ISSN 0001-4842, 10/2016, Volume 49, Issue 10, pp. 2284 - 2294
Owing to their unique biological, physical, and chemical properties, fluoroalkylated organic substances have attracted significant attention from researchers... 
ALKENES | HETEROARENES | HETEROCYCLES | HYDROTRIFLUOROMETHYLATION | PHOTOCATALYSIS | COMPLEXES | FLUORINE | ALKYNES | DIFLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 05/2013, Volume 15, Issue 9, pp. 2136 - 2139
Intermolecular aminotrifluoromethylation of alkenes catalyzed by [Ru(bpy)3]2+ under visible light irradiation has been explored. The present photocatalytic... 
DIFUNCTIONALIZATION | ORGANIC-SYNTHESIS | HETEROCYCLES | HYDROTRIFLUOROMETHYLATION | PHOTOCATALYSIS | PHOTOPHYSICS | CHEMISTRY, ORGANIC | PHOTOCHEMISTRY | ALDEHYDES | OXYTRIFLUOROMETHYLATION | ELECTROPHILIC TRIFLUOROMETHYLATION
Journal Article
Synlett, ISSN 0936-5214, 05/2018, Volume 29, Issue 8, pp. 1028 - 1032
Bromotrifluoromethane (CF3Br) is a simple, inexpensive and abundant industrial material employed as a trifluoromethylating reagent. However, only limited... 
bromotrifluoromethane | alkenes | visible-light-induced | hydrotrifluoromethylation | alkynes
Journal Article
Organic Letters, ISSN 1523-7060, 09/2015, Volume 17, Issue 18, pp. 4464 - 4467
A general visible light induced photoredox-catalyzed radical trifluoromethylation/cyclization cascade of β-aryl-β,γ-unsaturated hydrazones and oximes is... 
CATALYTIC HYDROTRIFLUOROMETHYLATION | DIFUNCTIONALIZATION | ALKENES | ALLYLIC ALCOHOLS | ACIDS | VISIBLE-LIGHT PHOTOREDOX | CHEMISTRY, ORGANIC | GENERATION | IN-SITU | 3+2 CYCLOADDITION | ATOM
Journal Article
by Wang, HQ and Zhang, JJ and Shi, JX and Li, F and Zhang, S and Xu, K
ORGANIC LETTERS, ISSN 1523-7060, 07/2019, Volume 21, Issue 13, pp. 5116 - 5120
The hydrotrifluoromethylation of benzyl-protected homoallylic alcohol and amine derivatives catalyzed by 2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile... 
VISIBLE-LIGHT | ALKENES | STYRENES | COMPLEX | HYDROTRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | FLUORINE | TRIFLUOROMETHYLATION
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 8/2014, Volume 43, Issue 18, pp. 6598 - 668
Journal Article
Organic Letters, ISSN 1523-7060, 06/2016, Volume 18, Issue 12, pp. 2962 - 2965
An electron-donor acceptor (EDA) complex between Togni's reagent and a tertiary amine has been introduced. The existence of this EDA complex was supported by... 
CATALYTIC HYDROTRIFLUOROMETHYLATION | CYCLOADDITION | LIGHT-IRRADIATION | CHARGE-TRANSFER COMPLEXES | IODOTRIFLUOROMETHYLATION | ALPHA-ALKYLATION | CHEMISTRY, ORGANIC | RADICAL TRIFLUOROMETHYLATION | EDA COMPLEXES | TRIFLUOROMETHYLATION REACTIONS | PERFLUOROALKYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 21, pp. 5188 - 5191
A palladium-catalyzed aryldifluoroalkylation of alkynes with ethyl difluoroiodoacetate and arylboronic acids as reaction partners is described. The alkyne... 
ETHYL BROMODIFLUOROACETATE | DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | HYDROTRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | DIFLUOROACETYLATION | OXIDATIVE TRIFLUOROMETHYLATION | DIFLUOROALKYLATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | UNACTIVATED ALKENES | BOND-FORMATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 08/2014, Volume 4, Issue 8, pp. 2530 - 2535
The use of organofluorine compounds, especially those with an incorporated trifluoromethyl moiety, has increased dramatically in both the pharmaceutical and... 
methylene blue | photoredox catalysis | trifluoromethylation | metal-free | laser flash photolysis | ARENES | CHEMISTRY, PHYSICAL | OXIDATIVE TRIFLUOROMETHYLATION | ALKENES | HETEROARENES | HYDROTRIFLUOROMETHYLATION | ENANTIOSELECTIVE ALPHA-TRIFLUOROMETHYLATION | EFFICIENT
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 4, pp. 1388 - 1391
Herein we report a novel, general protocol for distal heteroaryl ipso-migration and its application to the elusive heteroarylation of unactivated alkenes. A... 
DIFUNCTIONALIZATION | KETONES | CONCOMITANT 1,2-ARYL MIGRATION | HYDROTRIFLUOROMETHYLATION | ALPHA,ALPHA-DIARYL ALLYLIC ALCOHOLS | CATALYZED TRIFLUOROMETHYLATION | BOND FORMATION | TRANSFER RADICAL-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | Arylation | Chemical reactions | Usage | Chemical properties | Olefins
Journal Article
Chemical Communications, ISSN 1359-7345, 08/2013, Volume 49, Issue 66, pp. 7346 - 7348
Iron-catalyzed trifluoromethylation with concomitant 1,2-migration of an aryl group starting from diaryl allyl alcohol was achieved under mild conditions. This... 
HYDROTRIFLUOROMETHYLATION | PRODUCT | CONSTRUCTION | SEMIPINACOL REARRANGEMENT | FLUORINE | OXYTRIFLUOROMETHYLATION | ELECTROPHILIC TRIFLUOROMETHYLATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | Molecular Structure | Catalysis | Methylation | Iron - chemistry | Fluorine - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 29, pp. 10202 - 10205
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2015, Volume 51, Issue 67, pp. 13209 - 13212
The direct assembly of acrylonitriles and valuable 2H-azirines from readily available starting materials is described. This novel alkyne difunctionalization... 
ALKENES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | HYDROTRIFLUOROMETHYLATION | BONDS | C-H | Synthesis | Assembly | Acrylonitriles | Alkynes
Journal Article
by Liu, C and Lu, QQ and Huang, ZY and Zhang, J and Liao, F and Peng, P and Lei, AW
ORGANIC LETTERS, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 6034 - 6037
A novel strategy was developed to trigger center dot CF3 by using in situ generated peroxide in NMP under O-2 or air as the radical initiator. Radical... 
FUNCTIONALIZATION | DIFUNCTIONALIZATION | 3-COMPONENT OXYTRIFLUOROMETHYLATION | SODIUM TRIFLUOROMETHANESULFINATE | COPPER-CATALYZED TRIFLUOROMETHYLATION | ACIDS | HYDROTRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | GENERATION | OXIDATIVE TRIFLUOROMETHYLATION | EFFICIENT
Journal Article
by Zhu, N and Wang, F and Chen, PH and Ye, JX and Liu, GS
ORGANIC LETTERS, ISSN 1523-7060, 07/2015, Volume 17, Issue 14, pp. 3580 - 3583
A mild and efficient method for copper-catalyzed trifluoromethylazidation and trifluoromethylthiocyanation of allenes was explored. A series of CF3-containing... 
IN-VITRO | DESIGN | HYDROTRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | FLUORINE | ALKENES CONVENIENT ACCESS | PERFLUOROALKYL IODIDES | OXYTRIFLUOROMETHYLATION | ALKYNES | IDENTIFICATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 12, pp. 3247 - 3250
A copper-catalyzed chemo- and stereoselective oxidative bis-trifluoromethylthiolation of propiolic acid derivatives was achieved by using carboxylic acid as... 
DIFUNCTIONALIZATION | REAGENT | VISIBLE-LIGHT | 3-COMPONENT OXYTRIFLUOROMETHYLATION | SODIUM TRIFLUOROMETHANESULFINATE | FACILE SYNTHESIS | HYDROTRIFLUOROMETHYLATION | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | ALKYNES | UNACTIVATED ALKENES
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 06/2016, Volume 52, Issue 53, pp. 8275 - 8278
The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the... 
Azo compounds | Sodium | Alkenes | Photocatalysis | Azo
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 53, pp. 8275 - 8278
The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the... 
ORGANIC-SYNTHESIS | PHOTOREDOX-CATALYZED TRIFLUOROMETHYLATION | CYCLOADDITION REACTIONS | ARYL DIAZONIUM SALTS | HYDROTRIFLUOROMETHYLATION | VICINAL DIFUNCTIONALIZATION | AMINOTRIFLUOROMETHYLATION | RADICAL TRIFLUOROMETHYLATION | FLUORINE | FUNCTIONAL-GROUPS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 01/2019, Volume 21, Issue 1, pp. 138 - 141
Organic dye-catalyzed visible light induced hydroperfluoroalkylation of unactivated alkenes is described. Hydroperfluoroalkylation proceeds selectively and is... 
ASYMMETRIC FLUORINATION | IODIDES | HETEROARENES | RADICAL PERFLUOROALKYLATION | HYDROTRIFLUOROMETHYLATION | ARENES | CHEMISTRY, ORGANIC | OLEFINS | FLUOROALKYLATION REACTIONS | CYCLIZATION | TRIFLUOROMETHYLATION
Journal Article
Topics in Catalysis, ISSN 1022-5528, 6/2014, Volume 57, Issue 10, pp. 967 - 974
Journal Article
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