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hydroxycyclopentadienyl ruthenium hydride (113) 113
chemistry, multidisciplinary (45) 45
asymmetric transfer hydrogenation (42) 42
chemistry, organic (42) 42
hydrogenation (42) 42
chemistry, inorganic & nuclear (38) 38
catalysis (32) 32
complexes (32) 32
ketones (28) 28
proton-transfer (27) 27
index medicus (26) 26
mechanism (25) 25
imines (22) 22
reduction (22) 22
alcohols (21) 21
dynamic kinetic resolution (19) 19
catalysts (18) 18
ligand bifunctional catalysis (18) 18
experimental support (17) 17
aromatic ketones (16) 16
chemistry, physical (15) 15
carbonyl-compounds (14) 14
formic-acid (14) 14
homogeneous catalysis (14) 14
hydrogen-transfer (13) 13
ruthenium (13) 13
molecular structure (12) 12
analysis (11) 11
chemical properties (11) 11
metal (11) 11
asymmetric hydrogenation (10) 10
enantioselective hydrogenation (10) 10
ligand (10) 10
ligands (10) 10
ruthenium - chemistry (10) 10
secondary alcohols (10) 10
transfer hydrogenation (10) 10
catalyzed transfer hydrogenation (9) 9
concerted transfer (9) 9
isotope effect evidence (9) 9
kinetics (9) 9
oxidation-reduction (9) 9
aerobic oxidation (8) 8
alcohol)-catalyzed transfer hydrogenation (8) 8
c-h activation (8) 8
efficient (8) 8
imines - chemistry (8) 8
schiff bases (8) 8
asymmetric catalysis (7) 7
effective core potentials (7) 7
hydrides (7) 7
ketones - chemistry (7) 7
molecular calculations (7) 7
organic-synthesis (7) 7
organometallic compounds - chemistry (7) 7
reactivity (7) 7
alcohols - chemistry (6) 6
asymmetry (6) 6
chemistry (6) 6
coordination (6) 6
crystallography, x-ray (6) 6
density functionals (6) 6
dihydrogen (6) 6
enantioselective synthesis (6) 6
fe-only hydrogenase (6) 6
homogeneous hydrogenation (6) 6
hydrogen-transfer reactions (6) 6
iron (6) 6
mediated 2+2+1 cycloadditions (6) 6
metal-diene complexes (6) 6
models, molecular (6) 6
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biomass (5) 5
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hydride (5) 5
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n-heterocyclic carbene (5) 5
oppenauer-type oxidation (5) 5
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transition-metal hydrides (5) 5
activation (4) 4
amines (4) 4
amines - chemistry (4) 4
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carbon-dioxide (4) 4
dehydrogenation (4) 4
hydrogen - chemistry (4) 4
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imin (4) 4
imine hydrogenation (4) 4
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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 42, pp. 12236 - 12273
Journal Article
Chemical Reviews, ISSN 0009-2665, 08/2016, Volume 116, Issue 15, pp. 8873 - 8911
This Review highlights stoichiometric reactions and elementary steps of catalytic reactions involving cooperative participation of transition-metal hydrides and main group Lewis acids... 
ACTIVE-SITE MODELS | DISSOCIATION FREE-ENERGIES | HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE | HOMOGENEOUS SYNGAS CONVERSION | CARBON-DIOXIDE REDUCTION | CATALYTIC OLEFIN HYDROGENATION | NICKEL-IRON HYDROGENASES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | ORGANOMETALLIC CROWN-ETHERS | RAY CRYSTAL-STRUCTURE
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2016, Volume 358, Issue 7, pp. 1054 - 1058
...Since its discovery in 1985, 1 the Shvo catalyst, which is a cyclopentadienone‐ligated dimeric ruthenium complex, {[Ph 4 (η 5 ‐C 4 CO)] 2 H}Ru 2 (CO) 4 (μ‐H... 
ketone | transfer hydrogenation | asymmetric catalysis | ruthenium complex | imine | Shvo’s catalyst | Shvo's catalyst | MECHANISM | IMINES | COMPLEXES | CHEMISTRY, ORGANIC | DYNAMIC KINETIC RESOLUTION | KETONES | REDUCTION | ALLYLIC ALCOHOLS | HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE | METAL | CHEMISTRY, APPLIED | PROTON-TRANSFER | Schiff bases | Ruthenium | Aniline | Ketones | Catalysts | Catalysis | Hydrogenation | Reduction | Synthesis | Asymmetry | Imines
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2014, Volume 53, Issue 16, pp. 4044 - 4055
Journal Article
Dalton Transactions, ISSN 1477-9226, 8/2010, Volume 39, Issue 32, pp. 7427 - 7436
The use of first-row transition metals for the catalytic reduction of carbonyl functionalities has become increasingly important in homogeneous catalysis. This... 
LIGAND BIFUNCTIONAL CATALYSIS | ASYMMETRIC TRANSFER HYDROGENATION | ENANTIOSELECTIVE HYDROSILYLATION | IRON(II) COMPLEXES | HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE | HOMOGENEOUS CATALYSIS | DONOR ABILITIES | ISOTOPE EFFECT EVIDENCE | DIHYDROGEN COMPLEXES | P-N-N | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2014, Volume 33, Issue 13, pp. 3433 - 3442
A computational approach (DFT-B3PW91) is used to address previous experimental studies (Chem. Commun. 2009, 6801) that showed that transfer hydrogenation of a... 
MECHANISTIC ASPECTS | FORMIC-ACID | KETONES | ASYMMETRIC TRANSFER HYDROGENATION | N-HETEROCYCLIC CARBENE | PENTAMETHYLCYCLOPENTADIENYL-RHODIUM | COORDINATION SPHERE | HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE | COMPLEXES | CHEMISTRY, ORGANIC | POLARIZATION FUNCTIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article