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1. Full Text Ruthenium-Catalyzed C–H Bond Oxygenations with Weakly Coordinating Ketones
by Thirunavukkarasu, Vedhagiri S and Ackermann, Lutz
Organic Letters, ISSN 1523-7060, 12/2012, Volume 14, Issue 24, pp. 6206 - 6209
Ruthenium complexes enabled first C(sp2)–H bond oxygenations of aromatic ketones with excellent functional group tolerance, and broad scope as well as high... 
DIRECTING GROUP | HYDROXYLATED ARENES | FUNCTIONALIZATION | PALLADIUM | ACTIVATION | CHEMISTRY, ORGANIC | ALKOXYLATION | DIRECT ARYLATIONS | CLEAVAGE | OXIDATIVE ALKENYLATION | WATER
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2. Full Text Ortho- and Para-Selective Ruthenium-Catalyzed C(sp2)–H Oxygenations of Phenol Derivatives
by Liu, Weiping and Ackermann, Lutz
Organic Letters, ISSN 1523-7060, 07/2013, Volume 15, Issue 13, pp. 3484 - 3486
Versatile ruthenium catalysts allowed for efficient direct oxygenations of aryl carbamates under remarkably mild reaction conditions. In addition to... 
H BOND ACTIVATION | HYDROXYLATED ARENES | FUNCTIONALIZATION | CLEAVAGES | PALLADIUM | CONSTRUCTION | CHEMISTRY, ORGANIC | ALKOXYLATION | DIRECT ARYLATIONS | CONTAINING HETEROCYCLES | C-H
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3. Protonated Arenes as Solid Proton Conducting Electrolytes
by Stasko, Daniel
2004, AD-a427 843.
The goal of this project was to utilize weakly coordinating anion technology to produce new materials for use as proton conducting electrolytes. The main focus... 
boranes | diffraction | hydronium ions | protonated arenes | hydroxylated boranes | wca(weakly coordinating anions) | pem(polymer electrolyte membranes) | thermal stability | ice | acid stability | electrolytes | high temperature | fuel cell electrolytes | proton conductors | oxonium ions | ionomers | conductivity | arenium ions | fuel cells | protons | anions
Government Document
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4. Full Text Ruthenium-Catalyzed C–H Oxygenation on Aryl Weinreb Amides
by Yang, Fanzhi and Ackermann, Lutz
Organic Letters, ISSN 1523-7060, 02/2013, Volume 15, Issue 3, pp. 718 - 720
Versatile ruthenium catalysts enabled unprecedented C–H bond oxygenations of aryl Weinreb amides with ample scope under exceedingly mild reaction conditions,... 
DIRECTING GROUP | HYDROXYLATED ARENES | METHOXY-N-METHYLAMIDES | ACTIVATION | BOND FUNCTIONALIZATIONS | CHEMISTRY, ORGANIC | DIRECT ARYLATIONS | CONTAINING HETEROCYCLES | CLEAVAGE | ALKYNE ANNULATIONS | OXIDATIVE ALKENYLATION | Oxidation-Reduction | Aldehydes - chemical synthesis | Stereoisomerism | Amides - chemistry | Molecular Structure | Catalysis | Ruthenium - chemistry
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5. Full Text Tuning the Reactivity of Peroxo Anhydrides for Aromatic C–H Bond Oxidation
by Pilevar, Afsaneh and Hosseini, Abolfazl and Šekutor, Marina and Hausmann, Heike and Becker, Jonathan and Turke, Kevin and Schreiner, Peter R
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2018, Volume 83, Issue 17, pp. 10070 - 10079
Phenol moieties are key structural motifs in many areas of chemical research from polymers to pharmaceuticals. Herein, we report on the design and use of a... 
HYDROXYLATED ARENES | MALONOYL PEROXIDES | DIELS-ALDER REACTIONS | PHTHALOYL PEROXIDE | CHEMISTRY, ORGANIC | CYCLIC DIACYL PEROXIDES | DIARYLIODONIUM SALTS | SELECTIVE SYNTHESIS | HYDROGEN-PEROXIDE | BENZOYL PEROXIDE | SYN-DIHYDROXYLATION
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6. Full Text Silver-Catalyzed C(sp2)–H Functionalization/C–O Cyclization Reaction at Room Temperature
by Dai, Jian-Jun and Xu, Wen-Tao and Wu, Ya-Dong and Zhang, Wen-Man and Gong, Ying and He, Xia-Ping and Zhang, Xin-Qing and Xu, Hua-Jian
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2015, Volume 80, Issue 2, pp. 911 - 919
Silver-catalyzed C(sp2)–H functionalization/C–O cyclization has been developed. The scalable reaction proceeds at room temperature in an open flask. The... 
HYDROXYLATED ARENES | RADICAL CONDITIONS | CROSS-COUPLING REACTIONS | ONE-POT SYNTHESIS | C-H OXYGENATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | ARYLBORONIC ACIDS | CARBOXYLIC-ACIDS | BENZOIC-ACIDS | Temperature | Cyclization | Silver - chemistry | Silver Nitrate - chemistry | Molecular Structure | Catalysis | Kinetics | Lactones - chemistry
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7. A highly efficient metal-free approach to meta- and multiple-substituted phenols via a simple oxidation of cyclohexenones
by Liang, Yu-Feng and Song, Song and Ai, Lingsheng and Li, Xinwei and Jiao, Ning
Green Chemistry, ISSN 1463-9262, 12/2016, Volume 18, Issue 24, pp. 6462 - 6467
A novel and efficient metal-free approach to substituted phenols has been disclosed from simple and readily available cyclohexenones and cyclohexenone... 
Equivalence | Oxidants | Reagents | Dimethyl sulfoxide | Oxidizing agents | Phenols | Handles | Oxidation
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8. Full Text Metal-free regioselective C-3 acetoxylation of N-substituted indoles: Crucial impact of nitrogen-substituent
by Soni, Vineeta and Patel, Ulhas N and Punji, Benudhar
RSC Advances, ISSN 2046-2069, 2015, Volume 5, Issue 71, pp. 57472 - 57481
A metal-free method for the regioselective C-3 acetoxylation of the N-substituted indoles with PhI(OAc)(2) is described under mild reaction conditions. This... 
DIRECTING GROUP | HYDROXYLATED ARENES | FUNCTIONALIZATION | CATALYZED DIRECT | ARYLATION | C-H OXYGENATION | ALKOXYLATION | BOND ACTIVATION | CONTAINING HETEROCYCLES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY
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9. Full Text A highly efficient metal-free approach to: Meta - And multiple-substituted phenols via a simple oxidation of cyclohexenones
by Liang, Yu-Feng and Song, Song and Ai, Lingsheng and Li, Xinwei and Jiao, Ning
Green Chemistry, ISSN 1463-9262, 2016, Volume 18, Issue 24, pp. 6462 - 6467
A novel and efficient metal-free approach to substituted phenols has been disclosed from simple and readily available cyclohexenones and cyclohexenone... 
HYDROXYLATED ARENES | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | FACILE SYNTHESIS | AROMATIC ETHERS | ARYL HALIDES | OXIDASE CATALYSIS | DIMETHYL-SULFOXIDE | CATALYZED AEROBIC DEHYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | METHYL KETONES | MOLECULAR-OXYGEN
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10. Full Text Accessing Drug Metabolites via Transition‐Metal Catalyzed C−H Oxidation: The Liver as Synthetic Inspiration
by Genovino, Julien and Sames, Dalibor and Hamann, Lawrence G and Touré, B. Barry
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 46, pp. 14218 - 14238
Can classical and modern chemical C−H oxidation reactions complement biotransformation in the synthesis of drug metabolites? We have surveyed the literature in... 
C−H functionalization | biotransformation | chemotransformation | drug discovery | drug metabolites | HYDROXYLATED ARENES | LEAD DIVERSIFICATION | UDENFRIEND SYSTEM | FUNGAL PEROXYGENASES | C-H functionalization | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | BENZYLIC OXIDATION | CYTOCHROME-P450 ENZYMES | ORGANIC-COMPOUNDS | LATE-STAGE FUNCTIONALIZATION | ACTIVE METABOLITE | Microfluidic Analytical Techniques | Transition Elements - chemistry | Biological Products - chemistry | Pharmaceutical Preparations - metabolism | Electrochemical Techniques | Oxidation-Reduction | Pharmaceutical Preparations - chemistry | Biological Products - metabolism | Catalysis | Hydrogen - chemistry | Carbon - chemistry | Electrochemical reactions | Metabolites | Liver | Electrochemistry | Oxidation-reduction reaction | Drug discovery | Pharmaceutical industry | Microfluidics | Oxidation
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11. Metal-free regioselective C-3 acetoxylation of N-substituted indoles: crucial impact of nitrogen-substituent
by Soni, Vineeta and Patel, Ulhas N and Punji, Benudhar
RSC Advances, 07/2015, Volume 5, Issue 71, pp. 57472 - 57481
A metal-free method for the regioselective C-3 acetoxylation of the N-substituted indoles with PhI(OAc) sub(2) is described under mild reaction conditions.... 
Functional groups | Indoles
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12. Full Text Human Liver Microsomes Atropselectively Metabolize 2,2′,3,4′,6-Pentachlorobiphenyl (PCB 91) to a 1,2-Shift Product as the Major Metabolite
by Uwimana, Eric and Li, Xueshu and Lehmler, Hans-Joachim
Environmental Science & Technology, ISSN 0013-936X, 05/2018, Volume 52, Issue 10, pp. 6000 - 6008
Polychlorinated biphenlys (PCBs) and their hydroxylated metabolites (OH-PCBs) have been implicated in neurodevelopmental disorders. Several neurotoxic PCBs,... 
ENVIRONMENTAL SCIENCES | CHIRAL POLYCHLORINATED-BIPHENYLS | ENANTIOSELECTIVE FORMATION | GAS-CHROMATOGRAPHY | PRENATAL EXPOSURE | FOOD-WEB | ENGINEERING, ENVIRONMENTAL | TISSUE-SLICES | ARENE OXIDE | HYDROXYLATED METABOLITES | 3-MONTH-OLD INFANTS | MASS-SPECTROMETRY
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13. Full Text Effects of thiol antioxidants on the atropselective oxidation of 2,2′,3,3′,6,6′-hexachlorobiphenyl (PCB 136) by rat liver microsomes
by Wu, Xianai and Wu, Xianai and Lehmler, Hans-Joachim and Lehmler, Hans-Joachim
Environmental Science and Pollution Research, ISSN 0944-1344, 2/2016, Volume 23, Issue 3, pp. 2081 - 2088
Chiral polychlorinated biphenyl (PCB) congeners, such as PCB 136, are atropselectively metabolized to various hydroxylated PCB metabolites (HO-PCBs). The... 
Cytochrome P450 enzymes | Environmental Health | Ecotoxicology | Environment, general | NAC | Hepatic microsomes | Enantioselective | Biotransformation | Environment | Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution | PCB 136 | Environmental Chemistry | Atmospheric Protection/Air Quality Control/Air Pollution | Glutathione | 4-CHLOROBIPHENYL PCB3 | CYTOCHROME-P450 3A4 | CEREBELLAR GRANULE CELLS | HYDROXYLATED POLYCHLORINATED-BIPHENYLS | ESTER BINDING | SULFATED METABOLITES | ENVIRONMENTAL SCIENCES | BEAR URSUS-MARITIMUS | IN-VITRO | TISSUE-SLICES | ARENE OXIDE | Hydroxylation | Oxidation-Reduction | Glutathione - metabolism | Stereoisomerism | Antioxidants - metabolism | Microsomes, Liver - metabolism | Rats | Male | Polychlorinated Biphenyls - metabolism | Microsomes, Liver - chemistry | Sulfhydryl Compounds - metabolism | Animals | Polychlorinated Biphenyls - chemistry | Antioxidants | Enzymes | Cysteine | Thiols | Metabolites | Liver | Quinone | Polychlorinated biphenyls | Chemical properties | Sulfates | Enantiomers | Pollution studies | Polychlorinated biphenyls--PCB | Biosynthesis | Food chains | Index Medicus | biotransformation | hepatic microsomes | cytochrome P450 enzymes | enantioselective
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14. Full Text Synthesis of highly hydroxylated aromatics by evolved biphenyl dioxygenase and subsequent dihydrodiol dehydrogenase
by Shindo, Kazutoshi and Shindo, Yuko and Hasegawa, Tomoko and Osawa, Ayako and Kagami, Osamu and Furukawa, Kensuke and Misawa, Norihiko
Applied Microbiology and Biotechnology, ISSN 0175-7598, 7/2007, Volume 75, Issue 5, pp. 1063 - 1069
The evolved bphA1 (2049) gene, in which nine amino acids from the Pseudomonas pseudoalcaligenes KF707 BphA1 were changed to those from the Burkholderia... 
Biotechnology | Biphenyl dioxygenase | Microbiology | Microbial Genetics and Genomics | Dihydrodiol dehydrogenase | Chemistry and Materials Science | Hydroxylated aromatics | dihydrodiol dehydrogenase | DIHYDROXYLATION | ENHANCED DEGRADATION | BIOTECHNOLOGY & APPLIED MICROBIOLOGY | hydroxylated aromatics | GENES | ARENES | biphenyl dioxygenase | DIRECTED EVOLUTION | STRAIN | Amino Acid Sequence | Hydrocarbons, Aromatic - metabolism | Animals | Escherichia coli - enzymology | Hydroxylation | Escherichia coli - genetics | Molecular Sequence Data | Rats | Oxidoreductases - physiology | Directed Molecular Evolution | Dioxygenases - physiology | Studies
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15. Regioselective versatility of monooxygenase reactions catalyzed by CYP2B6 and CYP3A4: Examples with single substrates
by Erratico, Claudio A and Deo, Anand K and Bandiera, Stelvio M
Advances in Experimental Medicine and Biology, ISSN 0065-2598, 2015, Volume 851, pp. 131 - 149
Hepatic microsomal cytochrome P450 (CYP) enzymes have broad and overlapping substrate specificity and catalyze a variety of monooxygenase reactions, including... 
Polybrominated diphenyl ethers | Cytochrome P450 | Hydroxylated metabolites | Human CYP2B6 | Human CYP3A4 | BDE-47 and BDE-99 | Oxidative biotransformation | Lithocholic acid | MEDICINE, RESEARCH & EXPERIMENTAL | BILE-ACID | HUMAN CYTOCHROME P4502B6 | IN-VITRO METABOLISM | HUMAN LIVER-MICROSOMES | PREGNANE-X-RECEPTOR | DISRUPTOR PESTICIDE-METHOXYCHLOR | CONSTITUTIVE ANDROSTANE RECEPTOR | BROMINATED FLAME RETARDANTS | 2,2',4,4'-TETRABROMODIPHENYL ETHER | BIOLOGY | Hydroxylation | Humans | Lithocholic Acid - metabolism | Substrate Specificity | Halogenated Diphenyl Ethers - chemistry | Cytochrome P-450 CYP2B6 - metabolism | Lithocholic Acid - chemistry | Halogenated Diphenyl Ethers - metabolism | Animals | Cytochrome P-450 CYP3A - metabolism | Cytochrome P-450 CYP3A - chemistry | Microsomes, Liver - enzymology | Catalysis | Cytochrome P-450 CYP2B6 - chemistry
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16. SnCl4-promoted ethenylation reaction of hydroxylated heteroarenes
by Akamatsu, Kensuke and Amemiya, Ryo and Yamaguchi, Masahiko
Heterocycles, ISSN 0385-5414, 08/2004, Volume 63, Issue 8, pp. 1839 - 1847
Reaction of hydroxylated heteroarenes and acetylene in the presence of SnCl4 and Bu3N (or Et3N) gives the corresponding ethenylated arenes. The reaction takes... 
SnCl4 | carbostannylation | PHENOLS | ethenylation | CHEMISTRY, ORGANIC | hydroxylated heteroarene | acetylene | ORTHO-VINYLATION
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17. Full Text Biotransformation of BDE-47 to Potentially Toxic Metabolites Is Predominantly Mediated by Human CYP2B6
by Feo, ML and Gross, MS and McGarrigle, BP and Eljarrat, E and Barcelo, D and Aga, DS and Olson, JR
ENVIRONMENTAL HEALTH PERSPECTIVES, ISSN 0091-6765, 04/2013, Volume 121, Issue 4, pp. 440 - 446
BACKGROUND: Previous studies have indicated that cytochrome P450s (CYPs) are involved in the metabolism of polybrominated diphenyl ether (PBDE) flame... 
human liver microsomes | HOMEOSTASIS | THYROID-HORMONE | PBDES | BDE metabolites | hydroxylated metabolites | POLYBROMINATED DIPHENYL ETHERS | NEUROTOXICITY | PBDE metabolism | MASS-SPECTROMETRY | ENVIRONMENTAL SCIENCES | PUBLIC, ENVIRONMENTAL & OCCUPATIONAL HEALTH | BDE-47 | CYP2B6 | POLYMORPHISMS | BROMINATED FLAME RETARDANTS | TOXICOLOGY | PC12 CELLS | EXPOSURE | Recombinant Proteins - metabolism | Gas Chromatography-Mass Spectrometry | Oxidation-Reduction | Environmental Pollutants - pharmacokinetics | Flame Retardants - pharmacokinetics | Humans | Microsomes, Liver - metabolism | Cytochrome P-450 Enzyme System - metabolism | Environmental Exposure | Aryl Hydrocarbon Hydroxylases - metabolism | Tandem Mass Spectrometry | Halogenated Diphenyl Ethers - pharmacokinetics | Kinetics | Oxidoreductases, N-Demethylating - metabolism | Cytochrome P-450 CYP2B6 | Fish | Chemical contaminants | Metabolites | Fire resistant materials | Rodents | Human | Toxicology | Toxic | Liver | Ethers | Metabolism | Recombinant | Research
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18. Full Text Measurement of Polybrominated Diphenyl Ethers and Metabolites in Mouse Plasma after Exposure to a Commercial Pentabromodiphenyl Ether Mixture
by Xinghua Qiu and Minerva Mercado-Feliciano and Robert M. Bigsby and Ronald A. Hites
Environmental Health Perspectives, ISSN 0091-6765, 7/2007, Volume 115, Issue 7, pp. 1052 - 1058
Background: Previous studies have shown that polybrominated diphenyl ethers (PBDEs) behave as weak estrogens in animal and cell culture bioassays. In vivo... 
Halogenated diphenyl ethers | Metabolites | Gavage | Congeners | Environmental health | Animal social behavior | Biochemical pathways | Research | Ethers | Blood | Blood plasma | DE-71 | Bromophenols | Polybrominated diphenyl ethers | Hydroxylated PBDEs | BDE-153 | Hydroxylation | hydroxylation | PBDES | RATS | polybrominated diphenyl ethers | IDENTIFICATION | hydroxylated PBDEs | DISPOSITION | BLUE MUSSELS | ENVIRONMENTAL SCIENCES | IN-VITRO | TOXICOKINETICS | PUBLIC, ENVIRONMENTAL & OCCUPATIONAL HEALTH | BALTIC SEA | BROMINATED FLAME RETARDANTS | MICE | TOXICOLOGY | bromophenols | Mice | Animals | Gas Chromatography-Mass Spectrometry | Polybrominated Biphenyls - blood | Health aspects
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19. Full Text Metabolism and metabolites of polychlorinated biphenyls
by Grimm, Fabian A and Hu, Dingfei and Kania-Korwel, Izabela and Lehmler, Hans-Joachim and Ludewig, Gabriele and Hornbuckle, Keri C and Duffel, Michael W and Bergman, Åke and Robertson, Larry W
Critical Reviews in Toxicology, ISSN 1040-8444, 03/2015, Volume 45, Issue 3, pp. 245 - 272
Abstract The metabolism of polychlorinated biphenyls (PCBs) is complex and has an impact on toxicity, and thereby on the assessment of PCB risks. A large... 
PCB methyl sulfones | hydroxylated PCBs | PCB sulfates | human exposure | reactive intermediates | polychlorobiphenylols | Polychlorobiphenylols | Hydroxylated PCBs | Reactive intermediates | Human exposure | SPRAGUE-DAWLEY RATS | METHYL SULFONE METABOLITES | IN-UTERO EXPOSURE | THYROXINE TRANSPORT PROTEIN | POLYBROMINATED DIPHENYL ETHERS | RAT-LIVER MICROSOMES | CAPILLARY GAS-CHROMATOGRAPHY | HYDROXYSTEROID SULFOTRANSFERASE SULT2A1 | TOXICOLOGY | HYDROXYLATED PCB METABOLITES | THYROID-HORMONE LEVELS | Environmental Exposure - adverse effects | Animals | Polychlorinated Biphenyls - toxicity | Environmental Pollutants - pharmacokinetics | Humans | Polychlorinated Biphenyls - blood | Polychlorinated Biphenyls - pharmacokinetics | Environmental Exposure - analysis | Environmental Pollutants - metabolism | Environmental Pollutants - toxicity | Polychlorinated Biphenyls - metabolism | Index Medicus
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