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Polyhedron, ISSN 0277-5387, 03/2019, Volume 160, pp. 255 - 260
In this work, we found the reaction of ( -PhCH Se) Fe (CO) ( ) with the bisphosphine ligands can get different types of carbonyl substituted model complexes,... 
C[sbnd]Se homolysis | X-ray crystallography | Synthesis | Diiron diselenolato complexes | Bisphosphine | C–Se homolysis | C-Se homolysis | ELECTROCHEMICAL PROPERTIES | ACTIVE-SITE | STRUCTURAL-CHARACTERIZATION | IRON | CRYSTALLOGRAPHY | CHEMISTRY, INORGANIC & NUCLEAR | MODELS | PATHWAY | DERIVATIVES | HYDROGENASE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 30, pp. 7534 - 7534
Bond homolysis (BHo) is a fundamental concept in chemical‐bonding phenomena. To date, research studies on the BHo concept have provided crucial information for... 
bond homolysis | cyclopropane | radicals | puckered structures
Journal Article
Nature Communications, ISSN 2041-1723, 05/2015, Volume 6, Issue 1, p. 7237
Biopolymers such as DNA store information in their chains using controlled sequences of monomers. Here we describe a non-natural information-containing... 
ALKOXYAMINES | BOND HOMOLYSIS | MACROMOLECULES | DNA | MULTIDISCIPLINARY SCIENCES | BLOCK | GENERATION | TRANSFER RADICAL POLYMERIZATION | INFORMATION-STORAGE | LIQUID-PHASE SYNTHESIS | OLIGOMERS | Chemical Sciences
Journal Article
Journal of Computational Chemistry, ISSN 0192-8651, 09/2017, Volume 38, Issue 25, pp. 2186 - 2192
OO bond homolysis in hydrogen peroxide (H2O2) has been studied using theoretical methods of four conceptually different types: hybrid DFT (B3LYP, M06‐2X),... 
OO bond homolysis | hydrogen peroxide | radical pair minima
Journal Article
International Journal of Mass Spectrometry, ISSN 1387-3806, 04/2019, Volume 438, pp. 29 - 35
Information could be stored in the backbone of sequence-defined oligo(alkoxyamine amide)s based on coded amide moieties, and further retrieved by MS/MS... 
Ion mobility | MS/MS | Protomers | Theoretical calculations | Alkoxyamine | C–ON bond homolysis | POLYMERS | ALKOXYAMINES | C-ON bond homolysis | SPECTROSCOPY | INFORMATION | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | Amides | Chemical Sciences
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2019, Volume 58, Issue 29, pp. 9954 - 9958
A comparative study of the homoleptic [ M( CF3) 4] @ complexes of all three coinage metals ( M= Cu, Ag, Au) reveals that homolytic M @ C bond cleavage is... 
OXIDATION | radicals | trifluoromethyl substituents | COMPLEXES | coinage metals | CHEMISTRY | homolysis | CHEMISTRY, MULTIDISCIPLINARY | ligand | field inversion
Journal Article
Chemical and Pharmaceutical Bulletin, ISSN 0009-2363, 11/2009, Volume 57, Issue 11, pp. 1257 - 1266
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2016, Volume 49, Issue 8, pp. 1546 - 1556
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 2, pp. 190 - 193
An alkoxyamine was prepared from a cyclic aldonitrone nitroxide. The resulting alkoxyamine containing an aldonitrone functional substituent is relatively... 
POLAR | RADICAL POLYMERIZATION | ON BOND HOMOLYSIS | IMIDAZOLINE SERIES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 05/2011, Volume 40, Issue 5, pp. 2189 - 2198
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a lot of investigations have focused on the kinetics of this process.... 
MODEL ALKOXYAMINES | ON BOND HOMOLYSIS | METHYL-METHACRYLATE | SG1-BASED ALKOXYAMINES | HYDROGEN-TRANSFER | RATE CONSTANTS | FREE-RADICAL POLYMERIZATION | RATE ENHANCEMENT | INITIATING ALKOXYAMINE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-CENTERED RADICALS
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 06/2004, Volume 33, Issue 5, pp. 267 - 273
In this tutorial review applications of alkoxyamines as C-radical precursors for the conduction of tin-free radical reactions are presented. These processes... 
ORGANIC-SYNTHESIS | CYCLIZATIONS | HOMOLYSIS | KINETICS | CYCLIC ALKOXYAMINES | SYSTEMS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of Catalysis, ISSN 0021-9517, 07/2017, Volume 351, pp. 146 - 152
Journal Article
Macromolecules, ISSN 0024-9297, 11/2006, Volume 39, Issue 24, pp. 8274 - 8282
This article follows a previous study (Macromolecules 2005, 38, 5485) demonstrating that the nitroxide SG1-mediated polymerization of methyl methacrylate can... 
MODEL ALKOXYAMINES | POLYMER SCIENCE | BLOCK-COPOLYMERS | HOMOLYSIS | N-BUTYL ACRYLATE | KINETICS | LENGTH | DECOMPOSITION | SYSTEMS | OXYL | Polymers | Chemical Sciences
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2016, Volume 55, Issue 47, pp. 14798 - 14801
Bismuth diphenylphosphanides Bi(NONR)(PPh2) (NONR=[O(SiMe2NR)(2)], R=tBu, 2,6-iPr(2)C(6)H(3), Aryl) undergo facile decomposition via single-electron processes... 
bond homolysis | ELEMENTS | PHOSPHORUS | P-4 activation | phosphanides | COMPLEX | SINGLE | main-group radicals | CRYSTAL-STRUCTURE | PHOSPHIDE | CHEMISTRY, MULTIDISCIPLINARY | bismuth
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2007, Volume 129, Issue 34, pp. 10597 - 10601
Photolysis of aqueous NO3 - with λ ≥ 195 nm is known to induce the formation of NO2 - and O2 as the only stable products. The mechanism of NO3 - photolysis,... 
ACID | HOMOLYSIS | PULSE-RADIOLYSIS | FLASH-PHOTOLYSIS | DECOMPOSITION | CHEMISTRY | PHOTOCHEMISTRY | ION | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | WATER
Journal Article
Green Chemistry, ISSN 1463-9262, 10/2013, Volume 15, Issue 11, pp. 3116 - 3134
Advances in the field of transition-metal-free nitroxide-catalyzed aerobic oxidation processes are covered in this critical review. Along with the relevant... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | TERTIARY ALLYLIC ALCOHOLS | SELECTIVE OXIDATION | ELECTRON-TRANSFER | MILD CONDITIONS | SOLVENT-FREE | N-HYDROXYPHTHALIMIDE NHPI | BENZYLIC ALCOHOLS | MOLECULE-INDUCED HOMOLYSIS | BAEYER-VILLIGER OXIDATION | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 11/2019, Volume 21, Issue 21, pp. 8592 - 8597
Carbon-carbon bond fragmentations are useful methods for the functionalization of molecules. The value of such cleavage events is maximized when paired with... 
OXIDATION | CHALCOGENATION | HOMOLYSIS | PLATANIC ACID | SULFIDES | CHEMISTRY, ORGANIC | ALPHA-ALKOXY HYDROPEROXIDES | RADICALS | FRAGMENTATION | DERIVATIVES | DISULFIDES
Journal Article
Polymer Chemistry, ISSN 1759-9954, 02/2019, Volume 10, Issue 6, pp. 672 - 678
Dynamic covalent polymer networks combine intrinsic reversibility with the robustness of covalent bonds, creating chemically stable materials that are... 
TRANSITION | ALKOXYAMINES | POLYMER SCIENCE | GELS | HOMOLYSIS | NITROXIDES | CHEMISTRY | STEP | CHAINS | MICROSCOPY | SMART
Journal Article
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