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chemistry, inorganic & nuclear (1079) 1079
imido complexes (731) 731
chemistry, organic (519) 519
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chemistry (328) 328
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imido ligands (64) 64
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1. Full Text CH Bond Activation by f‐Block Complexes
by Arnold, Polly L and McMullon, Max W and Rieb, Julia and Kühn, Fritz E
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 1, pp. 82 - 100
Most homogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small molecules to value‐added products. Organometallic... 
actinides | polarity reversal catalysis | radical addition | asymmetric catalysis | rare earths | Actinides | Polarity reversal catalysis | Rare earths | Asymmetric catalysis | Radical addition | BETA-HYDRIDE ELIMINATION | RARE-EARTH-METALS | LANTHANIDE COMPLEXES | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, MULTIDISCIPLINARY | NUCLEOPHILIC CARBENE COMPLEXES | RAY CRYSTAL-STRUCTURES | IMIDO COMPLEX | URANYL-ION | CARBON MULTIPLE-BOND | TERMINAL URANIUM NITRIDE | Metals, Rare Earth - chemistry | Actinoid Series Elements - chemistry | Hydrocarbons - chemistry | Catalysis | Oxidation-Reduction | Coordination Complexes - chemistry | Methane | Transition metals | Catalysts | Periodic table | Lanthanides | Cleavage | Transformations | Bonding
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2. Full Text An isolated nitridyl radical-bridged {Rh(N.)Rh} complex
by Gloaguen, Yann and Rebreyend, Christophe and Lutz, Martin|info:eu-repo/dai/nl/304828971 and Kumar, Pravin and Huber, Martina and Vandervlugt, Jarl Ivar and Schneider, Sven and Debruin, Bas
Angewandte Chemie - International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 26, pp. 6814 - 6818
Photochemical activation of [(PNNH)Rh(N3)] (PNNH=6-di-(tert- butyl)phosphinomethyl-2,2′-bipyridine) complex2 produced the paramagnetic (S=1/2),... 
radicals | non‐innocent ligands | EPR spectroscopy | nitrogen donors | rhodium | non-innocent ligands | IMIDO COMPLEXES | VALENT IRON | IRIDIUM | OXO | REACTIVITY | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURES | TERMINAL NITRIDO | LIGAND | COBALT | Electron Spin Resonance Spectroscopy | Carbon Monoxide | Free Radicals - chemistry | Pyridines - chemistry | Molecular Conformation | Crystallography, X-Ray | Magnetics | Coordination Complexes - chemistry | Iridium - chemistry | Rhodium - chemistry | Cytokinins | Telomerase | Humidity | Spectroscopy | Computation | Photochemical | Activation | Carbon monoxide | Crystallography | Radicals
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3. Full Text Arene CH Amination at Nickel in Terphenyl–Diphosphine Complexes with Labile Metal–Arene Interactions
by Herbert, David E and Lara, Nadia C and Agapie, Theodor
Chemistry – A European Journal, ISSN 0947-6539, 11/2013, Volume 19, Issue 48, pp. 16453 - 16460
The meta ‐terphenyl diphosphine, m ‐P 2 , 1 , was utilized to support Ni centers in the oxidation states 0, I, and II. A series of complexes bearing different... 
insertion reactions | CH activation | amination | arenes | group transfer | IMIDO COMPLEXES | NITRENE TRANSFER | ACTIVATION | NITROGEN-ATOM-TRANSFER | BOND AMINATION | REACTIVITY | IRON | CHEMISTRY, MULTIDISCIPLINARY | HYDROGEN | CH activation | IMIDOIRON(III) COMPLEX | 3-COORDINATE NICKEL | Terphenyl Compounds - chemistry | Phosphines - chemistry | Amination | Nickel - chemistry | Oxidation-Reduction | Molecular Structure | Azides - chemistry | Valence | Aromatic compounds | Insertion | Ligands | Nickel | Sulfur | Bonding | Bearing | insertion react | C-H activation | Arene compl
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4. Full Text Thorium-phosphorus triamidoamine complexes containing Th-P single-and multiple-bond interactions
by Wildman, Elizabeth P and Balázs, Gábor and Wooles, Ashley J and Scheer, Manfred and Liddle, Stephen T
Nature Communications, ISSN 2041-1723, 09/2016, Volume 7, Issue 1, p. 12884
Despite the burgeoning field of uranium-ligand multiple bonds, analogous complexes involving other actinides remain scarce. For thorium, under ambient... 
RAY-ABSORPTION SPECTROSCOPY | MULTIDISCIPLINARY SCIENCES | URANIUM COMPLEXES | REACTIVITY | ACTINIDE PHOSPHINIDENE COMPLEXES | LIGAND | DENSITY-FUNCTIONAL THEORY | URANYL-ION | CARBENE COMPLEXES | IMIDO ANALOGS | ELECTRONIC-STRUCTURE
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5. Full Text Investigation of Uranium Tris(imido) Complexes: Synthesis, Characterization, and Reduction Chemistry of [U(NDIPP)3(thf)3]
by Anderson, Nickolas H and Yin, Haolin and Kiernicki, John J and Fanwick, Phillip E and Schelter, Eric J and Bart, Suzanne C
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 32, pp. 9386 - 9389
Addition of KC 8 to trivalent [UI 3 (thf) 4 ] in the presence of three equivalents of 2,6‐diisopropylphenylazide (N 3 DIPP) results in the formation of the... 
imido | magnetic properties | uranium | multiple bonds | reduction | IMIDO COMPLEXES | HYDROGENATION | ANALOGS | REACTIVITY | BIS(IMIDO) | CHEMISTRY, MULTIDISCIPLINARY | X rays | Crystal structure | Pictures | Spectroscopy | Reduction | Uranium | Synthesis | Magnetization | X-rays | Dimers
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6. Full Text Accurate spin-state energies for iron complexes
by Swart, Marcel
Journal of Chemical Theory and Computation, ISSN 1549-9618, 12/2008, Volume 4, Issue 12, pp. 2057 - 2066
A critical assessment of the OPBE functional is made for its performance for the geometries and spin-states of iron complexes. In particular, we have examined... 
METHANE MONOOXYGENASE | IMIDO COMPLEXES | SHIELDING CONSTANTS | TRANSITION-METAL-COMPLEXES | CROSSOVER COMPLEX | STRUCTURAL MODEL | EXACT EXCHANGE | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY | GENERALIZED GRADIENT APPROXIMATION | ELECTRONIC-STRUCTURE
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7. Full Text Slow magnetic relaxation in a family of trigonal pyramidal iron(II) pyrrolide complexes
by Harman, W. Hill and Harris, T. David and Freedman, Danna E and Fong, Henry and Chang, Alicia and Rinehart, Jeffrey D and Ozarowski, Andrew and Sougrati, Moulay T and Grandjean, Fernande and Long, Gary J and Long, Jeffrey R and Chang, Christopher J
Journal of the American Chemical Society, ISSN 0002-7863, 12/2010, Volume 132, Issue 51, pp. 18115 - 18126
We present a family of trigonal pyramidal iron(II) complexes supported by tris(pyrrolyl-alpha-methyl)amine ligands of the general formula... 
HIGH-SPIN MOLECULES | IMIDO COMPLEXES | ORBITAL ANGULAR-MOMENTUM | TRANSITION-METAL IONS | ELECTRON-PARAMAGNETIC-RESONANCE | NITRIDO COMPLEX | SPECTROSCOPIC CHARACTERIZATION | SINGLE-MOLECULE MAGNETS | 3-COORDINATE NICKEL | CHEMISTRY, MULTIDISCIPLINARY | HIGH-VALENT IRON | Electron Spin Resonance Spectroscopy | Anisotropy | Spectroscopy, Mossbauer | Iron - chemistry | Crystallography, X-Ray | Magnetics | Coordination Complexes - chemistry | Pyrrolidines - chemistry | X-ray crystallography | Iron compounds | Chemical synthesis | Structure | Analysis | Magnetic properties
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8. Full Text Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring‐Closing Metathesis (RCM) Reactions Catalyzed by Mo‐ or W‐Based Monoaryloxide Pyrrolide (MAP) Complexes: Applications to Total Syntheses of Epilachnene, Yuzu Lactone, Ambrettolide, Epothilone C, and Nakadomarin A
by Wang, Chenbo and Yu, Miao and Kyle, Andrew F and Jakubec, Pavol and Dixon, Darren J and Schrock, Richard R and Hoveyda, Amir H
Chemistry – A European Journal, ISSN 0947-6539, 02/2013, Volume 19, Issue 8, pp. 2726 - 2740
The first broadly applicable set of protocols for efficient Z ‐selective formation of macrocyclic disubstituted alkenes through catalytic ring‐closing... 
olefin metathesis | synthesis | tungsten | catalysis | macrocyclic | alkenes | molybdenum | macrocyclic Z alkenes | IMIDO ALKYLIDENE COMPLEXES | ALKYNE METATHESIS | ENANTIOSELECTIVE SYNTHESIS | OLEFIN CROSS-METATHESIS | MACROLIDES | CHEMISTRY, MULTIDISCIPLINARY | MICROTUBULE-STABILIZING AGENTS | NATURAL-PRODUCT SYNTHESIS | ENYNE METATHESIS | (-)-NAKADOMARIN | Molybdenum - chemistry | Carbolines - chemical synthesis | Macrocyclic Compounds - chemistry | Cycloparaffins - chemistry | Epothilones - chemistry | Stereoisomerism | Alkaloids - chemical synthesis | Epothilones - chemical synthesis | Macrocyclic Compounds - chemical synthesis | Ruthenium - chemistry | Biological Products - chemical synthesis | Biological Products - chemistry | Carbolines - chemistry | Lactones - chemical synthesis | Bridged-Ring Compounds - chemistry | Cyclization | Cycloparaffins - chemical synthesis | Molecular Structure | Catalysis | Kinetics | Bridged-Ring Compounds - chemical synthesis | Alkaloids - chemistry | Lactones - chemistry | Chemical synthesis | Molybdenum | Olefins | Isomerization | Macrocyclic compounds | Alkenes | Catalysts | Decomposition reactions | Metathesis | Selectivity | RCM
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9. Full Text Terminal Imido Rhodium Complexes
by Geer, Ana M and Tejel, Cristina and López, José A and Ciriano, Miguel A
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 22, pp. 5614 - 5618
Compounds of the late transition metals with MX multiple bonds (X=CR 2 , NR, O) represent a synthetic challenge, partly overcome by preparative chemists, but... 
cycloaddition | structure elucidation | azides | multiple bonds | rhodium | SPIN-CROSSOVER | MECHANISM | REACTIVITY | H BOND AMINATION | IRON | CHEMISTRY, MULTIDISCIPLINARY | COBALT(III) IMIDO | LIGANDS | NICKEL | CATALYZED OLEFIN AZIRIDINATION | NITRENE COMPLEXES | Rhodium | Nitrogen | Cycloaddition | Transition metals | Chemists | Nitrogen atoms | Protonation | Ligands | Terminals | Imides
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10. Full Text Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo-Metalated Amides
by Bell, Nicola L and Maron, Laurent and Arnold, Polly L
Journal of the American Chemical Society, ISSN 0002-7863, 08/2015, Volume 137, Issue 33, pp. 10492 - 10495
Molecules containing actinide nitrogen multiple bonds are of current interest as simple models for new actinide nitride nuclear fuels, and for their potential... 
NITROGEN MULTIPLE BOND | ACTIVATION | IMIDO METALLOCENE | ANALOGS | INTERMOLECULAR HYDROAMINATION | REACTIVITY | TERMINAL ALKYNES | LIGAND | URANYL-ION | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE | Chemical bonds | Chemical properties | Research | Thorium | Physics | Chemical Physics
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11. Full Text Terminal gold-oxo complexes
by Cao, Rui and Anderson, Travis M and Piccoli, Paula M. B and Schultz, Arthur J and Koetzle, Thomas F and Geletii, Yurii V and Slonkina, Elena and Hedman, Britt and Hodgson, Keith O and Hardcastle, Kenneth I and Fang, Xikui and Kirk, Martin L and Knottenbelt, Sushilla and Kögerler, Paul and Musaev, Djamaladdin G and Morokuma, Keiji and Takahashi, Masashi and Hill, Craig L
Journal of the American Chemical Society, ISSN 0002-7863, 09/2007, Volume 129, Issue 36, pp. 11118 - 11133
In contradiction to current bonding paradigms, two terminal Au-oxo molecular complexes have been synthesized by reaction of AuCl3 with metal oxide-cluster... 
IMIDO COMPLEXES | COBALT(III) IMIDO | NONHEME OXOIRON(IV) COMPLEXES | THIOETHER-OXIDATION | ALKOXO COMPLEXES | CATALYTIC-OXIDATION | OXYGEN-ATOM TRANSFER | AMBIENT-TEMPERATURE | 3-COORDINATE NICKEL | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | Gold - chemistry | Oxygen - chemistry | Thermogravimetry | Electrochemistry | Calorimetry, Differential Scanning | Crystallography, X-Ray | Molecular Structure | Magnetics | Spectrum Analysis | Hydrogen-Ion Concentration | Oxo compounds | Nuclear magnetic resonance spectroscopy | Usage | Gold compounds | Chemical properties | Magnetic properties
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12. Full Text M E and M E complexes of iron and cobalt that emphasize three-fold symmetry (E = O, N, NR)
by Saouma, Caroline T and Peters, Jonas C
Coordination Chemistry Reviews, ISSN 0010-8545, 2011, Volume 255, Issue 7, pp. 920 - 937
► Mid-to-late transition metal complexes that feature terminal, multiply bonded ligands. ► Review of 4- and 5-coordinate L M(E) and L′L M(E) species (E = oxo,... 
Atom and group transfer | Metal-to-ligand multiple bond | Oxos | Nitrides | Imides | IMIDO COMPLEXES | NITRENE TRANSFER | MOLECULAR-STRUCTURE | C-H ACTIVATION | NITROGEN ATOM-TRANSFER | RAY CRYSTAL-STRUCTURE | METAL-OXO COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | SPECTROSCOPIC CHARACTERIZATION | SPIN OXOIRON(IV) COMPLEX | ELECTRONIC-STRUCTURE | Atom and Group transfer
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13. Full Text New C-N and C-C bond forming reactions catalyzed by titanium complexes
by Odom, Aaron L
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2005, Issue 2, pp. 225 - 233
Titanium(IV) complexes with two basic dimethylamido ligands can be efficient catalysts for alkyne hydroamination by primary amines. Readily prepared pyrrolyl... 
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