X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
iminoboryl complexes (16) 16
boron (13) 13
reactivity (13) 13
platinum (12) 12
chemistry, inorganic & nuclear (11) 11
chemistry (8) 8
chemistry, multidisciplinary (8) 8
ligands (6) 6
transition-metal-complexes (6) 6
oxidative addition (5) 5
borylene complexes (4) 4
chemistry, organic (4) 4
palladium (4) 4
bonds (3) 3
boryl complexes (3) 3
chemical properties (3) 3
ligand (3) 3
solid argon (3) 3
transition-metal (3) 3
agostic interaction (2) 2
bonding (2) 2
bromides (2) 2
chemical bonds (2) 2
compound (2) 2
crystal-structure (2) 2
crystallography (2) 2
cyclobutadiene (2) 2
cyclooligomerization (2) 2
density functionals (2) 2
double-bond (2) 2
h bond activation (2) 2
halide-complexes (2) 2
hydroboration (2) 2
infrared-spectra (2) 2
intermediate (2) 2
ligands er e (2) 2
molecular-structure (2) 2
molecular-structures (2) 2
oxoboryl complexes (2) 2
oxygen (2) 2
platinum iminoboryl complexes (2) 2
regular 2-component hamiltonians (2) 2
rhodium (2) 2
spectroscopy (2) 2
synthesis (2) 2
1,2-dipolar addition (1) 1
1,2‐dipolar addition (1) 1
11b nmr chemical shift (1) 1
2+2+2 cycloaddition (1) 1
3 unsymmetrical alkynes (1) 1
abstraction (1) 1
abstraction chemistry (1) 1
acetylene (1) 1
activation (1) 1
adducts (1) 1
alpha,omega-diynes (1) 1
aminoborylene complexes (1) 1
analog (1) 1
analogs (1) 1
analysis (1) 1
arsenic double-bond (1) 1
atoms (1) 1
b nmr chemical shift (1) 1
b-11 nmr chemical shift (1) 1
b-tl (1) 1
b=b double-bond (1) 1
basis-sets (1) 1
block metals (1) 1
bor (1) 1
boranes (1) 1
boron atom (1) 1
boron atoms (1) 1
boron heterocycles (1) 1
boron temporary tether (1) 1
boroxines (1) 1
boryl (1) 1
boryl complexes platinum (1) 1
borylene:alylene (1) 1
bromide abstraction (1) 1
bromine (1) 1
c bond-cleavage (1) 1
carbenes (1) 1
carbon (1) 1
carbon-monoxide (1) 1
catalysis (1) 1
chelation (1) 1
chemical bonding (1) 1
chemical compounds (1) 1
chloroboranes (1) 1
complex (1) 1
computation (1) 1
configurations (1) 1
coordination chemistry (1) 1
coordination compounds (1) 1
coordination modes (1) 1
coordination sphere (1) 1
crystal (1) 1
cyclization (1) 1
cyclotrimerization (1) 1
decomposition reactions (1) 1
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Science (American Association for the Advancement of Science), ISSN 0036-8075, 2010, Volume 328, Issue 5976, pp. 345 - 347
.... Here, we report formation of the oxoboryl complex fn7A7s-[(Cy₃P)₂ BrPt(B=O)] (Cy being cyclohexyl) by means of reversible liberation of trimethylsilylbromide from the boron-bromine oxidative addition product of dibromo... 
Spectroscopy | Boron | Oxygen | Platinum | Atoms | Bromides | Ligands | Infrared radiation | Reports | Chemical bonding | Ellipsoids | INFRARED-SPECTRA | SOLID ARGON | HBO | MOLECULE | MULTIDISCIPLINARY SCIENCES | REACTIVITY | INTERMEDIATE | BORANES | MATRIX-ISOLATION | IMINOBORYL COMPLEXES | Oxides | Platinum compounds | Chemical properties | Chemical bonds | Molecular chemistry | Chemical compounds
Journal Article
Transition Metal Chemistry, ISSN 0340-4285, 2/2018, Volume 43, Issue 1, pp. 91 - 102
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 8, pp. 2240 - 2244
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2008, Volume 14, Issue 26, pp. 7858 - 7866
Journal Article
Inorganic chemistry, ISSN 0020-1669, 04/2012, Volume 51, Issue 8, pp. 4597 - 4605
...) oxoboryl complex, simplified to PtBr(BO)(PMe3)2, were theoretically investigated with the density functional theory method. The BO... 
B=B DOUBLE-BOND | SIGMA-BOND | ELEMENTS | BORON | STABLE COMPOUND | TRIPLE BOND | BASIS-SETS | MULTIPLE BONDS | IMINOBORYL COMPLEXES | ARSENIC DOUBLE-BOND | CHEMISTRY, INORGANIC & NUCLEAR | Thermal properties | Measurement | Usage | Metal bonding | Analysis | Density functionals | Palladium | Chemical properties | Electron-electron interactions | Surface energy
Journal Article
Organometallics, ISSN 0276-7333, 2014, Volume 34, Issue 11, pp. 2343 - 2347
The abstraction of halido ligands from Pt-II diphosphine boryl complexes has previously been shown to yield one of two isomeric products... 
REACTIVITY | CHEMISTRY, ORGANIC | LIGANDS | IMINOBORYL COMPLEXES | BORYLENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
European journal of inorganic chemistry, ISSN 1434-1948, 2015, Volume 2015, Issue 15, pp. 2592 - 2595
The first iminoboryl complex with a non‐phosphine donor ligand has been isolated and fully characterized... 
Main group elements | Boron | Iminoboryl ligands | Platinum complexes | CYCLOBUTADIENE | ANALOGS | OXOBORYL COMPLEXES | COMPOUND | REACTIVITY | ADDUCTS | CHEMISTRY, INORGANIC & NUCLEAR | LIGANDS | CARBENES | BONDS | CHEMISTRY | Ligands | Spectroscopy | Hydroboration | Synthesis | Platinum | Carbenes | Phosphines
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2015, Volume 51, Issue 84, pp. 15465 - 15468
The results present a new elimination reaction, the 1,2-alkylborane elimination, as a new route to silylene complexes... 
PLATINUM IMINOBORYL COMPLEXES | HYDROBORATION | ACTIVATION | CYCLOBUTADIENE | SINGLE-ELECTRON-TRANSFER | BORON | TRANSITION-METAL | REACTIVITY | CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | DOUBLE-BOND
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2010, Volume 49, Issue 34, pp. 5993 - 5996
Journal Article
Organometallics, ISSN 0276-7333, 03/2012, Volume 31, Issue 5, pp. 1897 - 1907
A reactivity study on a series of platinum boryl complexes was performed. The first stable base adducts of cationic haloboryl complexes of the form trans-[Pt{B(Br)(NMe2)}(NCMe)(PCy3)2... 
H BOND ACTIVATION | FUNCTIONALIZATION | BLOCK METALS | BORON | CHEMISTRY, ORGANIC | LIGAND | OXIDATIVE ADDITION | AGOSTIC INTERACTION | IMINOBORYL COMPLEXES | TRANSITION-METAL-BORYL | HALIDE-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2010, Volume 46, Issue 35, pp. 6473 - 6475
X-Ray and IR data of unprecedented oxoboryl species indicate a significant alteration in the B equivalent to O bond strength underlining the novel oxoboryl complexes' close relationship with the well... 
C BOND-CLEAVAGE | ABSTRACTION | TRANSITION-METAL-COMPLEXES | MASS SPECTROMETRIC DETERMINATION | COORDINATION SPHERE | CARBON-MONOXIDE | CHEMISTRY | PLATINUM | IMINOBORYL COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | BORYLENE COMPLEXES
Journal Article
Organometallics, ISSN 0276-7333, 01/2010, Volume 29, Issue 1, pp. 142 - 148
Geometry, electronic structure, and bonding analysis of the terminal neutral borylene complexes of cobalt, rhodium, and iridium [(η5-C5H5)(CO)M(BNMe2)] (I, M... 
ABSTRACTION CHEMISTRY | REGULAR 2-COMPONENT HAMILTONIANS | BORON | TRANSITION-METAL-COMPLEXES | LIGANDS ER E | REACTIVITY | CHEMISTRY, ORGANIC | IMINOBORYL COMPLEXES | B-TL | STATE METHOD | AMINOBORYLENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2012, Volume 51, Issue 40, pp. 10034 - 10037
...‐butyliminoborane has been achieved by a metal‐mediated formal [2+2+2] cycloaddition reaction. A 1,2‐azaborete pianostool complex was identified as an reaction intermediate. 
acetylene | boron | cyclization | boron heterocycles | rhodium | PLATINUM IMINOBORYL COMPLEXES | MOLECULAR-STRUCTURE | REACTIVITY | CRYSTAL | 2+2+2 CYCLOADDITION | CHEMISTRY, MULTIDISCIPLINARY | 3 UNSYMMETRICAL ALKYNES | BORON TEMPORARY TETHER | ALPHA,OMEGA-DIYNES | CHEMISTRY | CYCLOTRIMERIZATION | Acetylene
Journal Article
Polyhedron, ISSN 0277-5387, 08/2012, Volume 43, Issue 1, pp. 131 - 139
Electronic, molecular structure and bonding analyses of the group 8 borylene and alylene complexes [(η5-C5H5)M(PMe3)2(EX)]+ and [(η5-C5H5)M(CO)2(AlX)]+ (E=B, Al; M=Fe, Ru, Os; X=Mes, NMe2... 
NBO | Borylene:Alylene | EDA | Structure | Bonding | M-GA BONDS | TRANSITION-STATE METHOD | CRYSTALLOGRAPHY | CHEMISTRY, INORGANIC & NUCLEAR | DIHALOGALLYL COMPLEXES | ENERGY DECOMPOSITION ANALYSIS | REGULAR 2-COMPONENT HAMILTONIANS | SPONTANEOUS HALIDE EJECTION | SUBSTITUENT-FREE GALLIUM | LIGANDS ER E | DONOR-ACCEPTOR COMPLEXES | IMINOBORYL COMPLEXES
Journal Article