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interrupted pummerer reaction (26) 26
chemistry, organic (22) 22
chemistry, multidisciplinary (14) 14
latent-active glycosylation (12) 12
remote activation (12) 12
interrupted pummerer (11) 11
aryl sulfoxides (9) 9
glycosylation (9) 9
index medicus (8) 8
nucleophilic ortho-allylation (8) 8
oligosaccharide synthesis (7) 7
pummerer reaction (7) 7
redox arylation (7) 7
alpha-arylation (6) 6
ortho-propargylation (6) 6
sulfoxides (6) 6
sulfur (6) 6
carbon bond formation (5) 5
catalysis (5) 5
donors (5) 5
biochemistry & molecular biology (4) 4
c-h alkylation (4) 4
chemistry (4) 4
glycosides (4) 4
organosulfur compounds (4) 4
ortho-alkynylbenzoates (4) 4
sulfoxide (4) 4
synthesis (4) 4
thioglycosides (4) 4
acetic anhydride (3) 3
alkynes (3) 3
beta-mannopyranosides (3) 3
building-blocks (3) 3
carbohydrate (3) 3
carbonyl-compounds (3) 3
charge-accelerated sulfonium (3) 3
chemical glycosylation (3) 3
derivatives (3) 3
dimethyl-sulfoxide (3) 3
functionalization (3) 3
glycosides - chemistry (3) 3
interrupted pummerer-type reaction (3) 3
leaving group (3) 3
natural-products (3) 3
pummerer-type reaction (3) 3
reactivity (3) 3
sulfonium (3) 3
activation (2) 2
anhydrides (2) 2
annulation (2) 2
annulation/cross-coupling strategy (2) 2
arenes (2) 2
aromatic compounds (2) 2
arylation (2) 2
batch (2) 2
benzofuran (2) 2
c-h functionalization (2) 2
carbohydrates (2) 2
chemical reactions (2) 2
chemistry, applied (2) 2
coupling reactions (2) 2
cyclisation (2) 2
cyclizations (2) 2
electrophilic activation (2) 2
hypervalent iodine reagent (2) 2
in-situ generation (2) 2
inhibitors (2) 2
interrupted pummerer-type反應 (2) 2
iron-catalyzed cyclopropanation (2) 2
isotopic labeling (2) 2
o-glycosylation (2) 2
oligosaccharides (2) 2
one-pot synthesis (2) 2
organic chemistry (2) 2
organic-synthesis (2) 2
palladium (2) 2
paper (2) 2
pentenyl glycosides (2) 2
phenols (2) 2
phenyliodine bis (2) 2
rearrangement (2) 2
regioselective synthesis (2) 2
salts (2) 2
sigmatrope umlagerung (2) 2
sigmatropic-rearrangement (2) 2
stereoselective-synthesis (2) 2
strategies (2) 2
substrates (2) 2
synpacts (2) 2
synthetic methods (2) 2
thioglycosyl donors (2) 2
thionium ion (2) 2
trifluoromethanesulfonic anhydride (2) 2
1,3,4,5,6,7,8-heptafluoro-2-naphthyl prop-2-ynyl ethers (1) 1
1,3-dicarbonyl compounds (1) 1
2-allylphenyl glycosides (1) 1
2-aryl-1 (1) 1
2-benzisothiazol-3-ones (1) 1
2-ethylsulfanylbenzoates (1) 1
2h (1) 1
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Synlett, ISSN 0936-5214, 01/2018, Volume 29, Issue 2, pp. 148 - 156
Abstract A latent/active glycosylation strategy is efficient for rapid ­assembly of oligosaccharides. We recently developed novel OPTB/OPSB and SPTB/SPSB... 
account | natural products | glycosylation | total synthesis | latent/active | carbohydrate | interrupted Pummerer reaction | sulfoxide | GLYCOSIDES | OXIDATION | REMOTE ACTIVATION | OXALYL CHLORIDE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | DONORS | ALCOHOLS | LATENT-ACTIVE GLYCOSYLATION | OLIGOSACCHARIDE SYNTHESIS | DIMETHYL-SULFOXIDE
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2017, Volume 58, Issue 24, pp. 2381 - 2384
Practical synthetic methods to latent disarmed -2-(2-propylthio)benzyl (SPTB) glycosides for interrupted Pummerer reaction mediated glycosylation have been... 
Interrupted Pummerer reaction | Glycosyl donor | Disarmed glycoside | Thioglycoside | EFFICIENT GLYCOSYLATION | S-BUT-3-YNYL THIOGLYCOSIDE DONORS | CATALYSIS | REMOTE ACTIVATION | O-GLYCOSYLATION | PROTOCOL | CHEMISTRY, ORGANIC | ACTIVE GLYCOSYLATION | STRATEGIES | OLIGOSACCHARIDE SYNTHESIS | CHEMISTRY | Drugstores | Pharmacy | Thiols
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2016, Volume 57, Issue 1, pp. 152 - 154
Herein we describe the synthesis of a series of novel, functionalised pyrrolothiazolo–pyrimidines, –pyridines and –pyrazines employing a short reaction... 
Medicinal chemistry | Cyclisation | Heterocycle | Drug discovery | Interrupted Pummerer | CHEMISTRY, ORGANIC | Pyrimidines | Pyridine
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 2/2019, Volume 92, Issue 2, pp. 302 - 311
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 2018, Volume 76, Issue 7, pp. 678 - 689
A sulfonium species generated from sulfoxide and acid anhydride is a useful reagent for organic synthesis owing to its powerful electrophilicity. Among the... 
Indole | Interrupted pummerer reaction | Sulfonium | sulfonium | INTRAMOLECULAR CAPTURE | ONE-POT CONSTRUCTION | indole | CONCISE TOTAL-SYNTHESIS | CONVENIENT METHOD | ARYLATION | CHEMISTRY, ORGANIC | DIMERIZATION | ARYL SULFOXIDES | REARRANGEMENT | DIMETHYL-SULFOXIDE | CHIRAL SULFOXIDES | interrupted Pummerer reaction
Journal Article
Journal of Carbohydrate Chemistry, ISSN 0732-8303, 10/2018, Volume 37, Issue 9, pp. 471 - 497
The collective total syntheses of nine natural phenylethanoid glycosides (PhEGs) together with proposed Incanoside B in a divergent mode were described. By... 
collective synthesis | structure revision | interrupted Pummerer reaction | Phenylethanoid glycosides | REMOTE ACTIVATION | CISTANCHIS HERBA | BIOCHEMISTRY & MOLECULAR BIOLOGY | CHEMISTRY, ORGANIC | LEONURUS-JAPONICUS | ACTEOSIDE | LATENT-ACTIVE GLYCOSYLATION | PHENYLPROPANOID GLYCOSIDES | VERBASCOSIDE | ESTERS | PLANTS | CONSTITUENTS
Journal Article
Tetrahedron, ISSN 0040-4020, 2009, Volume 65, Issue 12, pp. 2430 - 2435
A convenient synthesis of 3-arylbenzo[ ]thiophenes utilizing an interrupted Pummerer reaction of 2-(1-arylvinyl)phenyl ethyl sulfoxides is described. Thus,... 
Benzo[ b]thiophenes | Sulfoxides | Interrupted Pummerer reaction | Ring closure | Acetic anhydride | Benzo[b]thiophenes | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | HYPERVALENT IODINE(III) REAGENT | CYCLIZATION | Organosulfur compounds
Journal Article
Synthesis, ISSN 0039-7881, 09/2011, Volume 2011, Issue 18, pp. 2897 - 2906
Abstract An efficient procedure for the synthesis of three types of thienopyridines has been developed. Thus, 3-(1-arylethenyl)-2-(ethylsulfinyl)pyridines,... 
paper | thieno[3,2- c ]pyridines | acetic anhydride | thieno[2,3- b ]pyridines | thieno[2,3- c ]pyridines | interrupted Pummerer reaction | THIENOPYRIDINES | thieno[2,3-c]pyridines | CHEMISTRY, ORGANIC | INHIBITORS | thieno[2,3-b]pyridines | MICROWAVE-ASSISTED SYNTHESIS | DERIVATIVES | DISCOVERY | thieno[3,2-c]pyridines
Journal Article
by Chen, DF and Fu, YY and Cao, XJ and Luo, JY and Wang, F and Huang, SL
ORGANIC LETTERS, ISSN 1523-7060, 07/2019, Volume 21, Issue 14, pp. 5600 - 5605
A metal-free method for formal beta-arylation/heteroarylation of ketones through efficient cyclopropanol ring-opening cross-couplings with aryl sulfoxides at... 
NUCLEOPHILIC ORTHO-ALLYLATION | KETONES | PALLADIUM | INTERRUPTED PUMMERER | ALPHA-ARYLATION | BOND-FORMING REACTIONS | C-METHYLATED DIHYDROCHALCONES | CHEMISTRY, ORGANIC | PUMMERER REACTION CHEMISTRY | OXIDATIVE CYCLIZATION | DIRECT BETA-ARYLATION
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 10/2019, Volume 55, Issue 83, pp. 12495 - 12498
A metal-free alpha-C-H functionalization of cyclic 1,2-diketones with aryl sulfoxides has been developed. This regioselective arylation involves nucleophilic... 
NUCLEOPHILIC ORTHO-ALLYLATION | CARBON BOND FORMATION | AROMATIC PUMMERER REACTION | INTERRUPTED PUMMERER | COUPLING REACTIONS | BUILDING-BLOCKS | REGIOSELECTIVE SYNTHESIS | ARYL SULFOXIDES | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | ORTHO-PROPARGYLATION
Journal Article
Synlett, ISSN 0936-5214, 12/2019, Volume 30, Issue 20, pp. 2203 - 2208
Abstract The redox-neutral ortho -functionalizations of aryl/heteroaryl sulfoxides via interrupted Pummerer processes have been greatly advanced since its... 
synpacts | CHARGE-ACCELERATED SULFONIUM | C-H ALKYLATION | cyanoalkylation | INTERRUPTED PUMMERER | ALPHA-ARYLATION | electrophilic activation | CHEMISTRY, ORGANIC | SULFUR | ORTHO-PROPARGYLATION | NUCLEOPHILIC ORTHO-ALLYLATION | CARBON BOND FORMATION | sulfur chemistry | PUMMERER REACTION | REDOX ARYLATION | sulfoxides | sigmatropic rearrangement
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 3, pp. 338 - 341
Sulfur ylides are well-known to undergo sigmatropic rearrangement reaction. Herein, we describe a novel reactivity of sulfur ylides, which provides access to... 
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 01/2019, Volume 55, Issue 3, pp. 338 - 341
Sulfur ylides are well-known to undergo sigmatropic rearrangement reaction. Herein, we describe a novel reactivity of sulfur ylides, which provides access to... 
INTERRUPTED PUMMERER | CYCLIZATIONS | REACTIVITY | ARYL SULFOXIDES | BATCH | IRON-CATALYZED CYCLOPROPANATION | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Zhang, Z and He, P and Du, HG and Xu, JX and Li, PF
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 04/2019, Volume 84, Issue 7, pp. 4517 - 4524
A sulfur-mediated electrophilic cyclization reaction of aryl-tethered internal alkynes has been developed. Triflic anhydride-activated sulfoxides induced the... 
FUNCTIONALIZATION | C-H ALKYLATION | SULFOXIDES | ANNULATION | ARYLATION | ARENES | CHEMISTRY, ORGANIC | INTERRUPTED PUMMERER REACTION | DERIVATIVES | SALTS
Journal Article
by Luo, F and Lu, Y and Hu, MJ and Tian, JS and Zhang, L and Bao, WZ and Yan, C and Huang, X and Wang, ZX and Peng, B
ORGANIC CHEMISTRY FRONTIERS, ISSN 2052-4129, 06/2018, Volume 5, Issue 11, pp. 1756 - 1762
A general protocol for the synthesis of a-aryl-and heteroaryl nitriles has been developed. Specifically, the simple treatment of a mixture of aryl(heteroaryl)... 
NUCLEOPHILIC ORTHO-ALLYLATION | PUMMERER REACTION | INTERRUPTED PUMMERER | ALPHA-ARYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | REDOX ARYLATION | ANNULATION/CROSS-COUPLING STRATEGY | CLAISEN REARRANGEMENT SEQUENCE | STILLE REACTION | ORTHO-PROPARGYLATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2018, Volume 59, Issue 31, pp. 2951 - 2959
Journal Article
Synthesis, ISSN 0039-7881, 11/2011, Volume 2011, Issue 21, pp. 3429 - 3434
Abstract A convenient method for the synthesis of 3-acetoxy-N,N-dialkylbenzo[B]thiophene-2-carboxamides has been developed in three steps from... 
paper | acetic anhydride | sulfoxides | 2-ethylsulfanylbenzoates | 3-acetoxybenzo[b]thiophene-2-carboxamides | interrupted Pummerer reaction | PUMMERER REACTION | CHEMISTRY, ORGANIC | INHIBITORS
Journal Article
by Meng, LK and Wu, P and Fang, J and Xiao, Y and Xiao, X and Tu, GS and Ma, X and Teng, S and Zeng, J and Wan, Q
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2019, Volume 141, Issue 30, pp. 11775 - 11780
Herein, we reported on a highly efficient glycosylation reaction comprising two chronological meticulously designed catalytic cycles: (1) rhodium-catalyzed... 
SULFONIUM IONS | ADDITION-CYCLIZATION REACTIONS | GOLD(I)-CATALYZED GLYCOSYLATION | REMOTE ACTIVATION | TAGETITOXIN CORE | ORTHO-ALKYNYLBENZOATES | INTERRUPTED PUMMERER REACTION | C-GLYCOSIDES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION
Journal Article
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