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intramolecular alkane arylation (57) 57
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Chemical Society Reviews, ISSN 0306-0012, 10/2011, Volume 40, Issue 10, pp. 4902 - 4911
Transition-metal-catalyzed C-H bond arylation has recently emerged as a powerful tool for the functionalization of organic molecules that may complement or... 
METHOXY GROUPS | AROMATIC KETONES | COUPLING REACTIONS | PD(OAC)-CATALYZED DOMINO REACTIONS | SITE-SELECTIVE SP | INTRAMOLECULAR ALKANE ARYLATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | PROTON-ABSTRACTION MECHANISM | BENZYLIC ARYLATION | Organic chemistry | Chemical Sciences
Journal Article
Organic Letters, ISSN 1523-7060, 04/2014, Volume 16, Issue 8, pp. 2248 - 2251
An example of using readily available, less reactive aryl bromides as arylating reagents in the Pd(II)-catalyzed intermolecular arylation of unactivated... 
DIRECTING GROUP | FUNCTIONALIZATION | C(SP)-H BONDS | PALLADIUM | AROMATIC CARBOXAMIDES | COUPLING REACTIONS | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | INTRAMOLECULAR ALKANE ARYLATION | C-H BONDS | CATALYZED DIRECT ARYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2012, Volume 51, Issue 51, pp. 12842 - 12845
Activated: The title reaction proceeds efficiently with 1 mol % of palladium and gives tetrahydroquinolines in excellent enantioselectivities (see scheme). The... 
CH activation | cyclopropanes | palladium | tetrahydroquinolines | asymmetric catalysis | C-H activation | DEPROTONATION | METALATION | MECHANISM | ACIDS | FUSED INDOLINES | C?H activation | INTRAMOLECULAR ALKANE ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C(SP)-H ACTIVATION | BONDS | DERIVATIVES | ARCHITECTURES | Activated | Palladium | Organic compounds
Journal Article
Chemical science, ISSN 2041-6520, 02/2017, Volume 8, Issue 2, pp. 1344 - 1349
The first efficient palladium(0)-catalyzed enantioselective C(sp )-H activation reaction using a catalytic chiral base and an achiral phosphine ligand is... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 5, pp. 2006 - 2014
Density functional theory (DFT) computations (BP86 and M06-L) have been utilized to elucidate the detailed mechanism of a palladium-catalyzed reaction... 
H BOND ACTIVATION | TRANSITION-ELEMENTS | CROSS-COUPLING REACTIONS | COMPUTATIONAL PERSPECTIVE | ALPHA-AMINO-ACIDS | CARBON-HYDROGEN BONDS | INTRAMOLECULAR ALKANE ARYLATION | HECK REACTION | AB-INITIO PSEUDOPOTENTIALS | CHEMISTRY, MULTIDISCIPLINARY | PROTON-ABSTRACTION MECHANISM
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 05/2012, Volume 41, Issue 9, pp. 3651 - 3678
Rhodium(III)-catalyzed direct functionalization of C-H bonds under oxidative conditions leading to C-C, C-N, and C-O bond formation is reviewed. Various arene... 
FUNCTIONALIZATION | RHODIUM | OLEFINATION | COUPLING REACTIONS | INTERNAL ALKYNES | INTRAMOLECULAR ALKANE ARYLATION | CLEAVAGE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | BENZOIC-ACIDS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 04/2017, Volume 50, Issue 4, pp. 1114 - 1123
The catalytic activation and functionalization of unactivated C­(sp3)–H bonds of alkyl groups has undergone intense development in recent years. In particular,... 
DIRECTING GROUP | METHOXY GROUPS | MECHANISM | BOND FUNCTIONALIZATIONS | GAMMA-LACTAMS | COUPLING PROCESSES | INTRAMOLECULAR ALKANE ARYLATION | C-H ACTIVATION | CHIRAL MONODENTATE PHOSPHINES | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION
Journal Article
Chemical Science, ISSN 2041-6520, 2017, Volume 8, Issue 2, pp. 1344 - 1349
The first efficient palladium(0)-catalyzed enantioselective C(sp3)-H activation reaction using a catalytic chiral base and an achiral phosphine ligand is... 
BRONSTED ACID | FUNCTIONALIZATION | COOPERATIVE CATALYSIS | AMINO-ACIDS | GAMMA-LACTAMS | INDOLINES | ALPHA-ALLYLATION | PALLADIUM CATALYSIS | INTRAMOLECULAR ALKANE ARYLATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | Phosphates | Phosphoric acid | Level (quantity) | Asymmetry | Ligands | Activation | Catalysis | Phosphines
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11827 - 11833
This report describes a carboxylate ligand exchange strategy that was used to achieve a Catellani reaction consisting of amination/unactivated aliphatic C–H... 
C-H activation | norbornene | palladium | amination | ligand exchange | CMD | arylation | DOMINO REACTION | ACTIVATION | ENANTIOSELECTIVE SYNTHESIS | BOND FUNCTIONALIZATIONS | EFFICIENT SYNTHESIS | CHEMISTRY, PHYSICAL | TOSYLHYDRAZONE INSERTION REACTION | C-H FUNCTIONALIZATION | INTRAMOLECULAR ALKANE ARYLATION | ARYL IODIDES | TETRASUBSTITUTED HELICAL ALKENES
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2014, Volume 136, Issue 42, pp. 14834 - 14844
The mechanism of the Ni-dcype-catalyzed C-H/C-O coupling of benzoxazole and naphthalen-2-yl pivalate was studied. Special attention was devoted to the base... 
DENSITY FUNCTIONALS | PALLADIUM | MOLECULAR CALCULATIONS | METHOXY GROUPS | EFFECTIVE CORE POTENTIALS | ARYL ESTERS | BOND ACTIVATION | INTRAMOLECULAR ALKANE ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | PROTON-ABSTRACTION MECHANISM | H ACTIVATION
Journal Article
Synthesis, ISSN 0039-7881, 06/2014, Volume 46, Issue 11, pp. 1421 - 1439
Abstract Within this review, recent developments in the field of C(sp 3 )–H activation catalyzed by palladium are discussed. Both intra­- and intermolecular... 
review | alkylation | organometallic reagents | palladacycles | homogeneous catalysis | arylation | DIRECTING GROUP | ALPHA-ARYLATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | ORGANIC MATERIALS | INTRAMOLECULAR ALKANE ARYLATION | C-H BONDS | COUPLING REACTIONS | CARBAMOYL CHLORIDE | ARYL CHLORIDES | CARBOXYLIC-ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2011, Volume 47, Issue 41, pp. 11483 - 11485
The first example of the enantioselective methyl C-H activation by an intramolecular ArPdX species and subsequent cyclisation was developed. Palladium... 
FUNCTIONALIZATION | HYDROGENATION | ACIDS | BONDS | INTRAMOLECULAR ALKANE ARYLATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | INSERTIONS | Phosphines - chemistry | Cyclization | Stereoisomerism | Indoles - chemistry | Palladium - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 08/2012, Volume 14, Issue 16, pp. 4270 - 4273
Synthesis of the indole skeleton was achieved using a Pd-catalyzed cascade process consisting of isocyanide insertion and benzylic C(sp3)–H activation. It was... 
FUNCTIONALIZATION | ROUTE | MECHANISM | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | INTRAMOLECULAR ALKANE ARYLATION | 2,3-DISUBSTITUTED INDOLES | C-H BONDS | ARYL CHLORIDES | CARBOXYLIC-ACIDS | Nitriles - chemistry | Indoles - chemical synthesis | Alkynes - chemistry | Molecular Structure | Catalysis | Indoles - chemistry | Palladium - chemistry
Journal Article
by Giri, R and Lan, Y and Liu, P and Houk, KN and Yu, JQ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/2012, Volume 134, Issue 34, pp. 14118 - 14126
The origin of the high levels of reactivity and diastereoselectivity (>99:1 dr) observed in the oxazoline-directed, Pd(II)-catalyzed sp(3) C-H bond iodination... 
FUNCTIONALIZATION | OXIDATION | MILD CONDITIONS | CHIRAL OXAZOLINES | GAS-PHASE | INTRAMOLECULAR ALKANE ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON-HYDROGEN | METAL-COMPLEXES | PROTON-ABSTRACTION MECHANISM | CARBOXYLIC-ACIDS
Journal Article
Synthesis, ISSN 0039-7881, 06/2012, Volume 44, Issue 12, pp. 1778 - 1791
Journal Article
by Li, H and Lia, BJ and Shi, ZJ
CATALYSIS SCIENCE & TECHNOLOGY, ISSN 2044-4753, 2011, Volume 1, Issue 2, pp. 191 - 206
Palladium-catalysis has been broadly applied to sp(2) C-H activation. Recently, palladium-catalyzed sp(3) C-H activation has also been considered as an... 
C(SP)-H BONDS | AEROBIC OXIDATIVE AMINATION | HOMOALLYLIC OXIDATION | ORGANOMETALLIC CHEMISTRY | ALLYLIC ALKYLATION | METHYL-GROUPS | CHEMISTRY, PHYSICAL | PYRIDINE N-OXIDES | ORGANOPALLADIUM(IV) CHEMISTRY | CARBON-HYDROGEN BONDS | INTRAMOLECULAR ALKANE ARYLATION
Journal Article