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by Zhao, D and Zhu, MX and Wang, Y and Shen, Q and Li, JX
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 10/2013, Volume 11, Issue 37, pp. 6246 - 6249
An efficient and selective Pd(0)-catalyzed sp(3) C-H bond arylation-oxidation of 4-methylquinazolines is reported. The method enables the introduction of... 
DIRECTING GROUP | CROSS-COUPLING PROCESSES | TOLUENE DERIVATIVES | BOND ARYLATION | ARYL HALIDES | CHEMISTRY, ORGANIC | PHASE-II | QUINAZOLINE DERIVATIVES | 2-METHYL AZAARENES | INTRAMOLECULAR ALKANE ARYLATION | CATALYZED DIRECT ARYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2016, Volume 138, Issue 8, pp. 2712 - 2723
Directed C–H functionalization of heterocycles through an exocyclic directing group (DG) is challenging due to the interference of the endocyclic... 
PD-MEDIATED ACTIVATION | TRANSITION-ELEMENTS | CROSS-COUPLING REACTIONS | REDUCTIVE-ELIMINATION PATHWAY | CARBON-HYDROGEN BONDS | AMINO-ACID LIGAND | INTRAMOLECULAR ALKANE ARYLATION | AB-INITIO PSEUDOPOTENTIALS | CHEMISTRY, MULTIDISCIPLINARY | PROTON-ABSTRACTION MECHANISM | MOLECULAR-OXYGEN
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2012, Volume 51, Issue 9, pp. 2238 - 2242
Journal Article
Israel Journal of Chemistry, ISSN 0021-2148, 12/2010, Volume 50, Issue 5‐6, pp. 630 - 651
Journal Article
Organic Letters, ISSN 1523-7060, 01/2012, Volume 14, Issue 1, pp. 398 - 401
Journal Article
Organic Letters, ISSN 1523-7060, 04/2011, Volume 13, Issue 7, pp. 1816 - 1819
Polycyclic molecules were obtained in good yields by double C(sp2)−H/C(sp3)−H arylations mediated by a single palladium/phosphine catalyst. Both double... 
BENZYLIC CARBON | FUNCTIONALIZATION | C(SP)-H BOND ACTIVATION | HETEROARENES | BIARYL | CHEMISTRY, ORGANIC | CONDENSED N-HETEROCYCLES | INTRAMOLECULAR ALKANE ARYLATION | ESTABLISHMENT | C-H ACTIVATION | ARYL CHLORIDES | Organic chemistry | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 19, pp. 4945 - 4949
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 27, pp. 9540 - 9543
We report a novel Pd-catalyzed alkyne-directed dual C–H activation of bis-biaryl alkynes, which produced important and useful products, 9,9′-bifluorenylidene... 
POLYMERS | CELLS | HYDROCARBONS | ANNULATION | BONDS | BIS(BIARYL)ACETYLENES | INTRAMOLECULAR ALKANE ARYLATION | ELECTRON-ACCEPTOR | CHEMISTRY, MULTIDISCIPLINARY | HYDROARYLATION | CYCLIZATION | Palladium | Research | Chemical properties | Catalysis | Chemical synthesis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2011, Volume 50, Issue 51, pp. 12236 - 12239
Simplified access: Substituted benzolactones can be obtained in one step by a Pd‐catalyzed ligand‐accelerated C(sp3)H bond‐activation/C(sp3)O bond‐formation... 
CH activation | palladium | benzolactones | homogeneous catalysis | amino acids | C-H activation | C(SP)-H BONDS | MECHANISM | C-H OLEFINATION | C?H activation | INTRAMOLECULAR ALKANE ARYLATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | AMINO-ACIDS | CARBON-CARBON | ARYL | BENZOIC-ACIDS | Activation | Palladium | Bonding | Avoidance | Functional groups
Journal Article
Organic Letters, ISSN 1523-7060, 04/2016, Volume 18, Issue 8, pp. 1932 - 1935
Perfluoroalkylated indoles are valuable compounds in drug discovery. A Pd(0)-catalyzed C­(sp3)–H functionalization enables access to... 
ACTIVATION | FACILE SYNTHESIS | HETEROCYCLES | ONE-POT SYNTHESIS | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | C-H FUNCTIONALIZATION | INTRAMOLECULAR ALKANE ARYLATION | OXIDATIVE TRIFLUOROMETHYLATION | DERIVATIVES | INDOLES
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 07/2015, Volume 5, Issue 7, pp. 4300 - 4308
New binepine ligands have been synthesized, and characterized and have been shown to induce high diastereo- and enantioselectivity in the intramolecular... 
PHOSPHEPINE | HYDROGENATION | chiral phosphines | INDOLINES | CHEMISTRY, PHYSICAL | C-C coupling C-H activation | asymmetric catalysis | CATALYST | INTRAMOLECULAR ALKANE ARYLATION | FUNCTIONALIZATION | C(SP)-H ACTIVATION | palladium | CHIRAL MONODENTATE PHOSPHINES | DERIVATIVES | ACCESS
Journal Article