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intramolecular alkane arylation (57) 57
chemistry, multidisciplinary (51) 51
c-h activation (39) 39
catalysis (32) 32
palladium (32) 32
chemistry, organic (31) 31
functionalization (24) 24
proton-abstraction mechanism (21) 21
index medicus (20) 20
activation (18) 18
c-h bonds (16) 16
cross-coupling reactions (15) 15
derivatives (15) 15
chemistry, inorganic & nuclear (14) 14
carbon-hydrogen bonds (12) 12
mechanism (12) 12
ligands (11) 11
palladium - chemistry (11) 11
coupling reactions (10) 10
arylation (9) 9
c-h functionalization (9) 9
cyclization (9) 9
ch activation (9) 9
molecular structure (9) 9
unactivated c-h bonds (9) 9
aryl chlorides (8) 8
asymmetric-synthesis (7) 7
bond activation (7) 7
bonding (7) 7
enantioselective synthesis (7) 7
olefination (7) 7
stereoselective-synthesis (7) 7
alkylation (6) 6
amination (6) 6
asymmetric catalysis (6) 6
carboxylic-acids (6) 6
catalysts (6) 6
catalyzed direct arylation (6) 6
chemical sciences (6) 6
chemistry, physical (6) 6
directing group (6) 6
homogeneous catalysis (6) 6
synthesis (6) 6
transition-metal-complexes (6) 6
[ chim.orga ] chemical sciences/organic chemistry (5) 5
article (5) 5
aryl halides (5) 5
asymmetry (5) 5
c?h activation (5) 5
carbon - chemistry (5) 5
chemical reactions (5) 5
chemical synthesis (5) 5
h bond activation (5) 5
heterocycles (5) 5
indolines (5) 5
multidisciplinary sciences (5) 5
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palladium catalysis (5) 5
ruthenium (5) 5
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alkenes - chemistry (4) 4
amines (4) 4
analysis (4) 4
bonds (4) 4
chemical properties (4) 4
chemistry (4) 4
cleavage (4) 4
c–h functionalization (4) 4
c−h activation (4) 4
direct arylation (4) 4
efficient synthesis (4) 4
functional groups (4) 4
gamma-lactams (4) 4
intermolecular direct arylation (4) 4
methoxy groups (4) 4
n-heterocyclic carbenes (4) 4
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rhodium (4) 4
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ab-initio pseudopotentials (3) 3
acid (3) 3
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arenes (3) 3
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carboxylic acids (3) 3
catalyzed intramolecular arylation (3) 3
ch activation (3) 3
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The Journal of Organic Chemistry, ISSN 0022-3263, 02/2014, Volume 79, Issue 3, pp. 1356 - 1367
The diastereoselective addition of an allylic indium intermediate to chiral o-bromophenyl sulfinyl imine 4 proceeded with good levels of diastereoselectivity.... 
GALIPEA-OFFICINALIS | 1-BENZAZEPINE DERIVATIVES | ASYMMETRIC-SYNTHESIS | MEDIATED ALLYLATION | HYDROGENATION | CYCLIZATION REACTIONS | AMINES | BUTANESULFINYL IMINES | CHEMISTRY, ORGANIC | CARBOAMINATION | ALKALOIDS
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8710 - 8753
Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of transition metal and lanthanide systems. Although the C–H bond is weaker... 
ION-PAIR ACIDITIES | TRANSITION-METAL-COMPLEXES | ELECTRON-DEFICIENT POLYFLUOROARENES | CARBON-FLUORINE BOND | INTRAMOLECULAR OXIDATIVE ADDITION | SOLID ARGON MATRIX | GAS-PHASE REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION | PROTON-ABSTRACTION MECHANISM | METHYL-FLUORIDE
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2011, Volume 40, Issue 38, pp. 9911 - 9920
Rhodation of trimethylene-bridged diimidazolium salts induces the intramolecular activation of an alkane-type C-H bond and yields mono-and dimetallic complexes... 
PALLADIUM | IRIDIUM(III) COMPLEXES | METAL CENTERS | ORGANOMETALLIC CHEMISTRY | DONOR LIGANDS | CATALYZED INTRAMOLECULAR ARYLATION | N-HETEROCYCLIC CARBENES | C-H ACTIVATION | METATHESIS | PROTON-ABSTRACTION MECHANISM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry Letters, ISSN 0366-7022, 11/2010, Volume 39, Issue 11, pp. 1118 - 1126
The cleavage of aromatic C–H bonds promoted by a metal and an intramolecular base has been described over 50 years ago. Herein, discussion of selected... 
CROSS-COUPLING REACTIONS | INTERMOLECULAR DIRECT ARYLATION | INTRAMOLECULAR ARYLATION | AZINE N-OXIDES | SITE-SELECTIVE SP | BOND ACTIVATION | C-H ACTIVATION | ELECTROPHILIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION | PROTON-ABSTRACTION MECHANISM
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2013, Volume 54, Issue 46, pp. 6226 - 6229
Carboxylic acid additives have been shown to significantly improve the yield of an intramolecular Buchwald–Hartwig N-arylation reaction. Carboxylic acid... 
Intramolecular N-arylation | 2-Aminopyrrole | Buchwald–Hartwig reaction | Pyrrolo[3,2-b]benzo[1,4]thiazine | Carboxylic acid additive | N-arylation | Intramolecular | Buchwald-Hartwig reaction | PALLADIUM | CHEMISTRY, ORGANIC | INDOLES | Palladium | Additives | Phenylacetic acid | Tetrahedrons | Carboxylic acids | Acetic acid | Rings (mathematics)
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 11/2013, Volume 5, Issue 1, pp. 29 - 39
Remarkable recent progress has been accomplished in direct C-H functionalizations for the formation of C-N and C-O bonds through the use of readily accessible... 
Accessibility
Journal Article
Dalton Transactions, ISSN 1477-9226, 1/2014, Volume 43, Issue 8, pp. 321 - 334
Transition-metal catalysed C-H bond functionalisation of arenes and heteroarenes has undergone a tremendous amount of development in the last decade with... 
CARBON-HYDROGEN-BOND | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | INTRAMOLECULAR ARYLATION | SQUARE-PLANAR COMPLEXES | SIGMA-ARYL COMPLEXES | MIXED-LIGAND SYSTEMS | AROMATIC-COMPOUNDS | MOLECULAR HYDROGEN | PROTON-ABSTRACTION MECHANISM | CHEMISTRY, INORGANIC & NUCLEAR | Bonding | Metalorganic compounds
Journal Article
Dalton Transactions, ISSN 1477-9226, 2009, Issue 30, pp. 5820 - 5831
Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom... 
LIGAND BIFUNCTIONAL CATALYSIS | REDUCTIVE-ELIMINATION | MOLECULAR CATALYSTS | TRANSITION-METAL-COMPLEXES | DIHYDROGEN ACTIVATION | CATALYZED INTRAMOLECULAR ARYLATION | OXIDATIVE-ADDITION | CARBON-HYDROGEN BONDS | PROTON-ABSTRACTION MECHANISM | METHANE ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 39, pp. 9206 - 9232
Journal Article
by Hu, R and Chen, FJ and Zhang, XF and Zhang, M and Su, WP
NATURE COMMUNICATIONS, ISSN 2041-1723, 08/2019, Volume 10, Issue 1, pp. 3681 - 10
Journal Article