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intramolecular arylcyanation (51) 51
chemistry, multidisciplinary (40) 40
catalysis (21) 21
nickel (21) 21
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activation (17) 17
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construction (7) 7
index medicus (7) 7
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3,3-disubstituted oxindoles (6) 6
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arylcyanation (6) 6
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cyanation (5) 5
efficient synthesis (5) 5
homogeneous catalysis (5) 5
nitriles (5) 5
tert-cyclobutanols (5) 5
trimethylsilyl cyanide (5) 5
allylic alkylation (4) 4
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carbon (4) 4
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lewis acid (4) 4
opening metathesis polymerization (4) 4
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Organic Letters, ISSN 1523-7060, 12/2014, Volume 16, Issue 24, pp. 6420 - 6423
A diastereoselective Pd-catalyzed arylcyanation/heteroarylcyanation of chiral N-allylcarboxamides using Zn(CN)(2) as the cyanide source is reported.... 
ALKENES | CROSS-COUPLING REACTIONS | NICKEL | ARYL HALIDES | CHEMISTRY, ORGANIC | CYANATION | INTRAMOLECULAR ARYLCYANATION | BOND ACTIVATION | CASCADE CYCLIZATION | ALKYNES | WATER
Journal Article
Chemical Communications, ISSN 1359-7345, 1/2011, Volume 47, Issue 4, pp. 11 - 115
Reactions cleaving carbon-carbon bonds with the assistance of transition metals as the catalyst have provided various molecular transformations that are... 
ACTIVATION | INSERTION | NICKEL | C-CN BOND | 8-MEMBERED RINGS | CONSTRUCTION | INTRAMOLECULAR ARYLCYANATION | ALKYNES | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2015, Volume 51, Issue 35, pp. 7540 - 7542
Nickel-catalysed P-H/C-CN cross coupling reactions take place efficiently under mild reaction conditions affording the corresponding sp(2)C-P bonds. This... 
PHOSPHORUS | CARBOCYANATION | PHOSPHONATION | ARYL HALIDES | CONSTRUCTION | INTRAMOLECULAR ARYLCYANATION | DIPHENYLPHOSPHINE | PHOSPHINE OXIDES | CARBON-CYANO | CHEMISTRY, MULTIDISCIPLINARY | H ARYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2015, Volume 137, Issue 46, pp. 14578 - 14581
A method for the catalytic enantioselective diarylation of alkenes is presented. The method allowed for the synthesis of highly enantioenriched... 
ETHYLENE | SYNERGISTIC CATALYSIS | STEREOCENTERS | CARBOBORATION | CASCADE | OLEFINS | INTRAMOLECULAR ARYLCYANATION | LIGAND | ALLENES | CARBOAMINATION | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Research | Chemical properties | Catalysis | Olefins
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2011, Volume 47, Issue 4, pp. 1100 - 1105
Reactions cleaving carbon-carbon bonds with the assistance of transition metals as the catalyst have provided various molecular transformations that are... 
Carbon-carbon composites | Construction | Transition metals | Synthesis | Chemical bonds | Cleavage | Transformations | Carbon
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 42, pp. 13759 - 13769
Conventional organic synthesis has been mainly based upon the reactivities of pi-bonds and polar sigma-bonds. Carbon-carbon single bonds are nonpolar and... 
TERT-CYCLOBUTANOLS | CYANO BONDS | ENANTIOSELECTIVE SYNTHESIS | CARBON-CARBON BOND | HOMOALLYL ALCOHOLS | ARYL HALIDES | NICKEL COMPLEXES | INTRAMOLECULAR ARYLCYANATION | OXIDATIVE ADDITION | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Chemical reactions | Usage | Chemical synthesis | Metal catalysts | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2014, Volume 136, Issue 20, pp. 7217 - 7220
When a carbenoid species generated from a tosylhydrazone is reacted with a cyclobutanol in the presence of a chiral rhodium catalyst, a C-C single bond of the... 
FUNCTIONALIZATION | ACTIVATION | MECHANISM | LEWIS-ACID | COMPLEXES | INTRAMOLECULAR ARYLCYANATION | DIAZO-COMPOUNDS | BENZOCYCLOBUTENOLS | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | DIAZOESTERS | Cyclic hydrocarbons | Usage | Catalysts | Rhodium | Influence | Chemical properties | Enantiomers | Carbon compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 42, pp. 14730 - 14733
A strategy for the catalytic diarylation of alkenes is presented. The method involves the migratory insertion of alkenes into an Ar-Cu complex to generate a... 
ARYL HALIDES | ESTERS | INTRAMOLECULAR ARYLCYANATION | COPPER | ALKYNES | COPPER(I)-CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | SUZUKI-MIYAURA | 3-COMPONENT CARBOBORATION | CYCLIZATION | Copper compounds | Chemical properties | Olefins | Benzene
Journal Article
Organic Letters, ISSN 1523-7060, 04/2016, Volume 18, Issue 7, pp. 1678 - 1681
A transition-metal-free procedure to access to functionalized 2-benzylphenyl ketones is described by direct insertion of arynes into benzylic C-C bonds. This... 
CYCLOADDITION | ACTIVATION | CARBOCYANATION | CARBON-CARBON BOND | CONSTRUCTION | CHEMISTRY, ORGANIC | OLEFINS | INTRAMOLECULAR ARYLCYANATION | SELECTIVE SYNTHESIS | RH-CATALYZED CARBOACYLATION | CLEAVAGE
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 13, pp. 3338 - 3341
The development of enantioselective carbon carbon bond couplings catalyzed by nonprecious metals is highly desirable in terms of cost efficiency and,... 
CARBON CENTERS | ACTIVATION | ASYMMETRIC-SYNTHESIS | CROSS-COUPLINGS | HYDROGENATION | LIGANDS | PRODUCTS | COUPLING REACTION | CHEMISTRY, ORGANIC | OLEFINS | INTRAMOLECULAR ARYLCYANATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2010, Volume 132, Issue 15, pp. 5340 - 5341
A rhodium-catalyzed enantioselective insertion into the C-C bond of tert-cyclobutanols and subsequent proto-demetalation provides access to methyl substituted... 
TERT-CYCLOBUTANOLS | CYANOAMIDATION | ADDITION/RING-OPENING REACTION | ACTIVATION | ENANTIOSELECTIVE SYNTHESIS | STEREOCENTERS | COMPLEXES | ELIMINATIONS | INTRAMOLECULAR ARYLCYANATION | ASYMMETRIC ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | Rhodium | Analysis | Methyl groups | Organometallic compounds | Substitution reactions | Butanol | Chemical properties | Structure
Journal Article
Organic Letters, ISSN 1523-7060, 08/2009, Volume 11, Issue 15, pp. 3374 - 3377
The Suzuki-Miyaura coupling of aryl nitriles with aryl/alkenyl boronic esters is reported. With this method, the cyano group could be applied as a protecting... 
FUNCTIONALIZATION | ETHERS | NICKEL | COMPLEXES | CHLORIDES | CHEMISTRY, ORGANIC | INTRAMOLECULAR ARYLCYANATION | O ACTIVATION | ARYLBORONIC ACIDS | GRIGNARD-REAGENTS | UNSYMMETRICAL BIARYLS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 11, pp. 3001 - 3005
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2014, Volume 53, Issue 6, pp. 1674 - 1678
A tunable rhodium‐catalyzed intramolecular alkyne insertion reaction proceeding through the CC cleavage of benzocyclobutenones is described. Selective... 
CC functionalization | cyclization | synthetic methods | alkynes | rhodium | C-C functionalization | CC functionalization | ACTIVATION | INSERTION | CARBON-CARBON BOND | INTRAMOLECULAR ARYLCYANATION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CYCLOBUTENONES | CYCLOADDITION | C-C BOND | OLEFINS | SUBSTITUTED PHENOLS
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 30, pp. 7567 - 7571
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2018, Volume 140, Issue 39, pp. 12364 - 12368
A Ni-catalyzed enantioselective reductive diarylation of activated alkenes by domino cyclizative/ cross-coupling of two aryl bromides is developed. This... 
3,3-DISUBSTITUTED OXINDOLES | TRANSIENT METALLACYCLES | NICKEL CATALYSIS | ARYL HALIDES | QUATERNARY STEREOCENTERS | CARBONYL-COMPOUNDS | ALKYL ELECTROPHILES | CN BOND ACTIVATION | INTRAMOLECULAR ARYLCYANATION | UNACTIVATED OLEFINS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2012, Volume 134, Issue 49, pp. 20005 - 20008
Journal Article