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intramolecular cannizzaro reaction (23) 23
chemistry, multidisciplinary (17) 17
chemistry, organic (13) 13
catalysis (12) 12
aldehydes (8) 8
index medicus (7) 7
stereoisomerism (6) 6
chemistry, physical (5) 5
enantioselective hydrogenation (4) 4
highly efficient (4) 4
kinetic resolution (4) 4
aerobic oxidation (3) 3
asymmetric catalysis (3) 3
cannizzaro reaction (3) 3
carbonyl-compounds (3) 3
catalysts (3) 3
chemical properties (3) 3
cyclization (3) 3
efficient (3) 3
enantiomers (3) 3
formaldehyde (3) 3
friedel-crafts reaction (3) 3
generation (3) 3
hydrogen (3) 3
hydrogenation (3) 3
hydroxy carboxylic-acids (3) 3
materials science, multidisciplinary (3) 3
mechanism (3) 3
molecular structure (3) 3
nanoparticles (3) 3
room-temperature (3) 3
selective reductions (3) 3
001 surfaces (2) 2
acid (2) 2
addition-reaction (2) 2
amides (2) 2
amines (2) 2
analysis (2) 2
anatas (2) 2
anatase (2) 2
aromatic-aldehydes (2) 2
article (2) 2
asymmetry (2) 2
beta-keto (2) 2
biological evaluation (2) 2
bronsted acid (2) 2
c-h activation (2) 2
carbon (2) 2
catalyst-activity (2) 2
chemical synthesis (2) 2
chemistry, inorganic & nuclear (2) 2
chiral phosphoric-acid (2) 2
co2 selectivity (2) 2
copper (2) 2
copper - chemistry (2) 2
coupling reactions (2) 2
crossed cannizzaro reaction (2) 2
dehydrogenation (2) 2
diphosphine ligands (2) 2
dynamic kinetic resolution (2) 2
enantioselectivity (2) 2
energy & fuels (2) 2
esters (2) 2
expression (2) 2
formaldehyd (2) 2
glyoxalase-i enzyme (2) 2
hydrogen-production (2) 2
in-vitro (2) 2
katalytische aktivität (2) 2
ketoesters (2) 2
ketones (2) 2
kinetics (2) 2
mandelic acids - chemistry (2) 2
methanol (2) 2
methyl-o-chloromandelate (2) 2
molecular-oxygen (2) 2
nanofolie (2) 2
nanopartikel (2) 2
nanosheet (2) 2
natural products (2) 2
organic chemistry (2) 2
organocatalysis (2) 2
oxalyl chloride (2) 2
phenylglyoxal (2) 2
pyridinium chlorochromate (2) 2
quantenpunkt (2) 2
quantum-point (2) 2
quaternary carbon centers (2) 2
raumtemperatur (2) 2
recombinant escherichia-coli (2) 2
reduction (2) 2
research (2) 2
room-ambient-temperature (2) 2
secondary alcohols (2) 2
selective oxidation (2) 2
stereoselective-synthesis (2) 2
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structure (2) 2
tio2 (2) 2
titan-oxid (2) 2
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Journal of Fluorine Chemistry, ISSN 0022-1139, 2008, Volume 129, Issue 10, pp. 994 - 997
Double asymmetric induction was achieved in the reaction of anhydrous phenylglyoxal with d-(+)-menthol promoted by a ( S, S)- t-BuBox·copper(II)... 
Double asymmetric induction | Copper(II) hexafluoroantimonate | Intramolecular Cannizzaro reaction | Anhydrous | Phenylglyoxal | Bis(oxazoline) | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic Letters, ISSN 1523-7060, 12/2005, Volume 7, Issue 26, pp. 5893 - 5895
A room-temperature convenient Cannizzaro reaction prompted by magnesium bromide ethyl etherate and triethylamine is described for smooth conversion of aromatic... 
CHEMISTRY, ORGANIC | INTRAMOLECULAR CATALYSIS | ACID | AROMATIC-ALDEHYDES | ARYLGLYOXALS | EFFICIENT
Journal Article
Nano Energy, ISSN 2211-2855, 09/2014, Volume 8, pp. 103 - 109
Herein, we demonstrate that hollow Pd nanotubes could serve as a highly efficient and convenient catalyst for inhibiting Cannizzaro reaction and facilitating... 
Catalysis | Cannizzaro reaction | Hydrogen | Pd nanotube | ROOM-TEMPERATURE | PHYSICS, APPLIED | MECHANISM | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | INTRAMOLECULAR CANNIZZARO REACTION | NANOPARTICLES | NUCLEAR-WASTE | COUPLING REACTIONS | KINETICS | DEGRADATION | GENERATION | FORMALDEHYDE
Journal Article
Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5652 - 5655
An efficient organocatalytic asymmetric synthesis of α-hydroxyketones has been developed. Quinine-derived thiourea catalyzed the enantioselective... 
INTRAMOLECULAR CANNIZZARO REACTION | (R)-ALPHA-HYDROXY KETONES | CINCHONA ALKALOIDS | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | ASYMMETRIC BENZOIN CONDENSATION | CARBONYL-COMPOUNDS | STEREOSELECTIVE-SYNTHESIS | DYNAMIC KINETIC RESOLUTION | HIGHLY EFFICIENT | ELECTRON-RICH PHENOLS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2014, Volume 47, Issue 8, pp. 2260 - 2272
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2013, Volume 3, Issue 7, pp. 1573 - 1577
Amorphous, nonporous silica/alumina (SA) made by flame-spray pyrolysis (FSP) efficiently catalyzes the direct conversion of phenylglyoxal (PG) to alkyl... 
Brønsted acidity | Cannizzaro reaction | flame spray pyrolysis | phenylglyoxal | silica-alumina | INTRAMOLECULAR CANNIZZARO REACTION | GLYOXALASE-I ENZYME | TRANSFORMATION | Bronsted acidity | CHEMISTRY, PHYSICAL
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2006, Volume 128, Issue 14, pp. 4558 - 4559
N-heterocyclic carbenes derived from triazolium salts are effective catalysts between 10 and 15 mol % for the hydroacylation of activated ketones. The reducing... 
MECHANISTIC ASPECTS | CANNIZZARO REACTION | BOND ACTIVATION | AROMATIC-ALDEHYDES | HYDROSILATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON-HYDROGEN | METAL-COMPLEXES | INTRAMOLECULAR STETTER REACTION | TISHCHENKO REACTION | X-ray crystallography | Ketones | Analysis | Oxidation-reduction reaction | Chemical properties | Structure | Aldehydes
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2014, Volume 50, Issue 100, pp. 15987 - 15990
A new efficient and highly enantioselective direct asymmetric hydrogenation of alpha-keto acids employing the Ir/SpiroPAP catalyst under mild reaction... 
INTRAMOLECULAR CANNIZZARO REACTION | DIPHOSPHINE LIGANDS | RECOMBINANT ESCHERICHIA-COLI | HYDROXY CARBOXYLIC-ACIDS | ENANTIOSELECTIVE HYDROGENATION | SELECTIVE REDUCTIONS | KETOESTERS | METHYL (R)-O-CHLOROMANDELATE | BETA-KETO | FRIEDEL-CRAFTS REACTION | CHEMISTRY, MULTIDISCIPLINARY | Iridium | Catalysis | Asymmetry | Catalysts | Hydrogenation
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 12/2014, Volume 50, Issue 100, pp. 15987 - 15990
A new efficient and highly enantioselective direct asymmetric hydrogenation of α-keto acids employing the Ir/SpiroPAP catalyst under mild reaction conditions... 
Mandelic Acids - chemistry | Glyoxylates - chemistry | Stereoisomerism | Keto Acids - chemistry | Catalysis | Hydrogenation | Iridium - chemistry | Spiro Compounds - chemistry
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2019, Volume 2019, Issue 10, pp. 1964 - 1980
Journal Article
Journal of Materials Chemistry A, ISSN 2050-7488, 2016, Volume 4, Issue 3, pp. 796 - 800
Herein, we demonstrate that quantum-sized Pd dot-decorated ultrathin anatase TiO2 nanosheets with exposed (001) facets (2 wt%) exhibit a highly efficient... 
STORAGE | METHANOL | MECHANISM | ENERGY & FUELS | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | CO2 SELECTIVITY | INTRAMOLECULAR CANNIZZARO REACTION | DEHYDROGENATION | 001 SURFACES | GENERATION | FORMALDEHYDE | WATER
Journal Article
Journal of materials chemistry. A, Materials for energy and sustainability, ISSN 2050-7488, 01/2016, Volume 4, Issue 3, pp. 796 - 800
Herein, we demonstrate that quantum-sized Pd dot-decorated ultra-thin anatase TiO2 nanosheets with exposed (001) facets (2 wt%) exhibit a highly efficient... 
Nanoparticles | Anatase | Hydrogen | Palladium | Nanostructure | Titanium dioxide | Hydrogen production | Qunatum dots | Supplying
Journal Article
RSC Advances, ISSN 2046-2069, 2015, Volume 5, Issue 97, pp. 79699 - 79702
An economic, environmental and practical aerobic oxidation of benzylic alcohols and hetero aryl alcohols to the corresponding carbonyl compounds with good... 
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2015, Volume 2015, Issue 7, pp. 1569 - 1574
A copper‐catalyzed asymmetric oxidative cross‐coupling reaction of 2‐naphthols with aryl methyl ketones has been developed. This transformation provides an... 
C–C coupling | Synthetic methods | Copper | Cross‐coupling | Asymmetric catalysis | C-C coupling | Cross-coupling | ACTIVATION | STRATEGY | CHEMISTRY, ORGANIC | ALPHA-KETOAMIDES | H BOND FUNCTIONALIZATION | INTRAMOLECULAR CANNIZZARO REACTION | PHENOLS | C-C | AEROBIC OXIDATION | HYDROGEN-PEROXIDE | SYNTHETIC TOOLS | Thiophene | Catalysis | Ketones
Journal Article
ChemCatChem, ISSN 1867-3880, 10/2014, Volume 6, Issue 10, pp. 2970 - 2975
Flame‐derived silica–zirconia has been used for the promising one‐step catalytic conversion of phenylglyoxal (PG) to mandelates, important intermediates in... 
Lewis acids | nmr spectroscopy | acidity | silicon | zirconium | Zirconium | Acidity | Silicon | Nmr spectroscopy | SURFACE-ACIDITY | MIXED OXIDES | SOLID-STATE NMR | ZRO2-SIO2 | NUCLEAR-MAGNETIC-RESONANCE | CHEMISTRY, PHYSICAL | MOLECULAR-SIEVES | THEORETICAL CALCULATION | INTRAMOLECULAR CANNIZZARO REACTION | GLYOXALASE-I ENZYME | METAL-OXIDES
Journal Article