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ir-f-binaphane (47) 47
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CHEMICAL SCIENCE, ISSN 2041-6520, 04/2019, Volume 10, Issue 16, pp. 4509 - 4514
The secondary amine participating asymmetric reductive amination remains an unsolved problem in organic synthesis. Here we show for the first time that... 
ENANTIOSELECTIVE HYDROGENATION | ALKYL-ARYL KETONES | IDENTIFICATION | IR-F-BINAPHANE | SALTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2005, Volume 44, Issue 45, pp. 7424 - 7427
A little goes a long way: A 1 mol % loading of the chiral phosphoric acid catalyst 2 converts aromatic and aliphatic imines such as 1 into the corresponding... 
imines | chiral amines | asymmetric catalysis | hydrogenation | rhomogeneous catalysis | Imines | Rhomogeneous catalysis | Chiral amines | Asymmetric catalysis | Hydrogenation | ACTIVATION | ALKYLATION | ALPHA,BETA-UNSATURATED ALDEHYDES | HYDROSILYLATION | TRICHLOROSILANE | IR-F-BINAPHANE | CHEMISTRY, MULTIDISCIPLINARY | KETONES | ENANTIOSELECTIVE REDUCTIVE AMINATION | DERIVATIVES | METAL-FREE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2009, Volume 74, Issue 7, pp. 2780 - 2787
The enantioselective hydrogenation of 2-benzylquinolines and 2-functionalized and 2,3-disubstituted quinolines was developed by using the... 
N-IMINOPYRIDINIUM YLIDES | HOMOGENEOUS HYDROGENATION | ASYMMETRIC TRANSFER HYDROGENATION | LIGANDS | REDUCTION | COMPLEXES | CHEMISTRY, ORGANIC | OLEFINS | IR-F-BINAPHANE | HETEROAROMATIC-COMPOUNDS | DERIVATIVES | Mechanical properties | Quinoline | Iridium | Chemical properties | Research | Structure | Hydrogenation
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 09/2008, Volume 12, Issue 13, pp. 1093 - 1115
Reductive amination is one of the most useful and versatile methods for the preparation of amines in chemistry and biology. The present review focuses on the... 
Organocatalyst | Reductive Amination | SODIUM TRIACETOXYBOROHYDRIDE | ASYMMETRIC TRANSFER HYDROGENATION | HIGHLY ENANTIOSELECTIVE HYDROGENATION | ALPHA-AMINO | REDUCING AGENT | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | N-ALKYLATION | ZINC BOROHYDRIDE | IR-F-BINAPHANE | SECONDARY-AMINES
Journal Article
Synthesis, ISSN 0039-7881, 07/2019, Volume 51, Issue 13, pp. 2713 - 2719
Abstract Catalyzed by the complex generated in situ from iridium and the chiral ferrocene ligand, tert -butyl (4-oxo-4-arylbutyl)carbamate substrates were... 
special topic | CATALYSIS | ROUTE | ASYMMETRIC-SYNTHESIS | HYDROGENATION | chiral ligand | IMINES | CHEMISTRY, ORGANIC | asymmetric catalysis | IR-F-BINAPHANE | DISCOVERY | iridium | intramolecular reductive amination | AMINES | STEREOCENTERS | arylpyrrolidine
Journal Article
Organic Letters, ISSN 1523-7060, 03/2006, Volume 8, Issue 5, pp. 999 - 1001
l-Pipecolinic acid derived formamides have been developed as highly efficient and enantioselective Lewis basic organocatalysts for the reduction of N-aryl... 
KETONES | ASYMMETRIC TRANSFER HYDROGENATION | AMINATION | LIGANDS | HYDROSILYLATION | BONDS | CHEMISTRY, ORGANIC | ALDOL REACTIONS | TRICHLOROSILANE | CATALYST | IR-F-BINAPHANE
Journal Article
Organic Letters, ISSN 1523-7060, 08/2011, Volume 13, Issue 16, pp. 4348 - 4351
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 12/2007, Volume 40, Issue 12, pp. 1278 - 1290
Journal Article
Organic Letters, ISSN 1523-7060, 11/2010, Volume 12, Issue 21, pp. 5075 - 5077
An enantioselective hydrogenation of simple fluorinated imines has been developed using Pd(OCOCF3)2/(R)-Cl-MeO-BIPHEP as a catalyst, and up to 94% ee was... 
BIOMIMETIC TRANSAMINATION | KETONES | ARYL BORONIC ACIDS | ONE-POT SYNTHESIS | ALLYLIC AMINES | CHEMISTRY, ORGANIC | N-H IMINES | ASYMMETRIC HYDROGENATION | IR-F-BINAPHANE | ACYCLIC IMINES | REDUCTIVE AMINATION | Amines - chemistry | Stereoisomerism | Halogenation | Imines - chemistry | Molecular Structure | Catalysis | Hydrogenation | Palladium - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 09/2013, Volume 15, Issue 17, pp. 4354 - 4357
Journal Article
Organic Letters, ISSN 1523-7060, 05/2006, Volume 8, Issue 11, pp. 2289 - 2292
An iridium(I) complex of (S,S)-1,2-bis(tert-butylmethylphosphino)ethane with tetrakis(3,5-bis(trifluoromethyl)phenyl)borate as the counterion catalyzes the... 
ALKENES | DIPHOSPHINE | CHEMISTRY, ORGANIC | OLEFINS | ASYMMETRIC HYDROGENATION | OXAZOLINE LIGANDS | IR-F-BINAPHANE | DERIVATIVES | REDUCTIVE AMINATION | ARYLIMINES | RHODIUM(I)
Journal Article
Synlett, ISSN 0936-5214, 2/2005, Volume 2005, Issue 2, pp. 203 - 211
Abstract A longstanding problem in enantioselective catalysis concerns the transformation of prochiral ketones into chiral amines. To date, this reaction is... 
account | CHIRAL LIGANDS | COMPLEXES | amines | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALDEHYDES | hydrogenation | IR-F-BINAPHANE | CATALYZED ASYMMETRIC HYDROGENATION | KETONES | IMINE HYDROGENATION | enantioselective catalysis | rhodium
Journal Article
Organic Letters, ISSN 1523-7060, 07/2006, Volume 8, Issue 14, pp. 3045 - 3048
l-Piperazine-2-carboxylic acid derived N-formamides have been developed as highly enantioselective Lewis basic catalysts for the hydrosilylation of N-aryl... 
KETONES | ASYMMETRIC TRANSFER HYDROGENATION | AROMATIC KETIMINES | BASES | LIGANDS | BONDS | CHEMISTRY, ORGANIC | ALDOL REACTIONS | TRICHLOROSILANE | IR-F-BINAPHANE | REDUCTIVE AMINATION
Journal Article