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by Geng, X and Wang, C and Huang, C and Bao, Y and Zhao, P and Zhou, Y and Wu, YD and Feng, LL and Feng, AX
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 1, pp. 140 - 144
We report an I-2/FeCl3-co-promoted formal [2 + 2+1] annulation of aryl methyl ketones, 2-aminobenzyl alcohols, and p-toluenesulfonylmethyl isocyanide (TosMIC)... 
TOSYLMETHYL ISOCYANIDE | METHYLENE ISOCYANIDES | CYCLOADDITION | ONE-POT SYNTHESIS | SULFONYLMETHYL ISOCYANIDES | CHEMISTRY, ORGANIC | TANDEM REACTION | P-TOLUENESULFONYLMETHYL ISOCYANIDE | DERIVATIVES TOTAL-SYNTHESIS | ALDOL-TYPE CONDENSATION | DUAL ROLES
Journal Article
Synthesis, ISSN 0039-7881, 09/2018, Volume 50, Issue 18, pp. 3549 - 3570
Abstract The formation of the key short-lived intermediate nitrilium ion in the Passerini and Ugi reactions was recognized early in the discovery of these... 
review | multicomponent reactions | isocyanides | Ugi reaction | Passerini reaction | nitrilium ions | 3,4-DIHYDROQUINOXALIN-2-AMINE DERIVATIVES | ONE-POT SYNTHESIS | 3-COMPONENT REACTION | ALKYL ISOCYANIDES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | ALPHA-ADDITION | COMBINATORIAL SYNTHESIS | ISOCYANIDE-BASED MCR | BUTYL ISOCYANIDE | MULTICOMPONENT REACTION
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2014, Volume 70, Issue 18, pp. 3005 - 3010
[4+1] Cycloaddition reaction between isocyanides and N-acylimine derivatives generated from N-acyl N,O-acetals acting as isocyanophiles has been developed.... 
Aminooxazole | Aminothiazole | Isocyanide
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 09/2019, Volume 1192, pp. 252 - 257
A series of four isostructural Os(II) complexes, OsHCl(CO)(L)(PPh3)2 with mutually trans triphenylphosphines and a stereospecifically introduced ligand L trans... 
Phosphine ligands | Structure | Isocyanide | Osmium
Journal Article
2012, ISBN 3527330437, xviii, 605
The efficacy of isocyanide reactions in the synthesis of natural or naturallike products has resulted in a renaissance of isocyanide chemistry. Now isocyanides... 
Isocyanides | Synthesis | Chemistry, Organic
Book
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 18, pp. 5910 - 5913
Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to isocyanides with diverse substitution patterns. The o-anisylsulfanyl... 
CHEMISTRY | CHEMISTRY, ORGANIC | MULTICOMPONENT REACTIONS | TRITYL ISOCYANIDE | METHYL ISOCYANIDE | STABILITY
Journal Article
Chemical Society reviews, ISSN 0306-0012, 03/2017, Volume 46, Issue 5, pp. 1295 - 1357
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring functional group can finely tune the reactivity of the isocyano... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 03/2017, Volume 46, Issue 5, pp. 1295 - 1357
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring functional group can finely tune the reactivity of the isocyano... 
CONVENIENT SYNTHESIS | ASYMMETRIC ALDOL REACTION | ONE-POT SYNTHESIS | PROMOTED 3-COMPONENT SYNTHESIS | C BOND FORMATION | TERT-BUTYL ISOCYANIDE | UGI 4-COMPONENT | MULTICOMPONENT SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ALPHA-METALATED ISOCYANIDES | ACID-CATALYZED REACTIONS | Synthesis | Deviation | Manuscripts | Functional groups | Flavours
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2580 - 2583
A novel iodine-catalyzed functionalization of a variety of olefins and alkynes and direct decarboxylative functionalization of cinnamic and propiolic acids... 
AEROBIC DIFUNCTIONALIZATION | TOSYLMETHYL ISOCYANIDE | SULFINIC ACIDS | ROOM-TEMPERATURE | VINYL SULFONES | CHEMISTRY, ORGANIC | BETA-KETO SULFONES | BOND FORMATION | P-TOLUENESULFONYLMETHYL ISOCYANIDE | INDIUM(III) CHLORIDE | ALLYLIC SULFONYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 2019, Volume 21, Issue 13, pp. 5269 - 5272
A novel multicomponent Ugi-type reaction for the synthesis of indole carboxamide amino amides from aldehydes, amines, isocyanides, and indole-N-carboxylic... 
CHEMISTRY, ORGANIC | CAGES | PEPTIDOMIMETICS | DIVERSITY | ISOCYANIDE
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 12/2019, Volume 84, Issue 24, pp. 16299 - 16307
Considering aryl azides as electrophilic partners for the TosMIC mediated Van Leusen reaction, a novel multicomponent synthesis of 4-tosyl-1-arylimidazoles is... 
TOSYLMETHYL ISOCYANIDE | CYCLOADDITION | TRIAZOLE DERIVATIVES | ALKYNE-AZIDE | 1,2,3-TRIAZOLE | CHEMISTRY | CHEMISTRY, ORGANIC | P-TOLUENESULFONYLMETHYL ISOCYANIDE | IMIDAZOLES | DUAL ROLES | THIAZOLES
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2013, Volume 11, Issue 42, pp. 7393 - 7399
A new reaction model, tandem Michael addition/formal isocyanide insertion into the acyl C-C bond, has been developed. Thus, a series of 2-acylpyrroles and... 
TOSYLMETHYL ISOCYANIDE | CATALYZED 3-COMPONENT REACTION | COMPLEX CATALYST | OLIGOSUBSTITUTED PYRROLES | SYNTHETIC REACTIONS | SULFONYLMETHYL ISOCYANIDES | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | ISOCYANIDE INSERTION | H ACTIVATION
Journal Article
Dyes and Pigments, ISSN 0143-7208, 05/2020, Volume 176, p. 108195
This manuscript reports the synthesis and liquid crystal behavior of isocyanoazulene gold(I) complexes [AuX (CN-Az)] (Az = azulene; X = halide, perhalophenyl... 
Gold | Azulene | Organometallic dyes | Isocyanide | Liquid crystals
Journal Article
Dyes and Pigments, ISSN 0143-7208, 05/2020, Volume 176, p. 108206
A type of novel triphenylamine (TPA)-based diisocyanide derivative, 4-isocyano-N-(4-isocyanophenyl)-N-(4-methoxyphenyl)aniline (M1), was successfully... 
Polyamide | Benzoxazine-isocyanide-chemistry (BIC) | Electrochromism | Triphenylamine
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 07/2019, Volume 48, Issue 28, pp. 10412 - 10416
Crystallographic and DFT examination of the metalloligands [AuAr(CNPy-4)] (Ar = C6F5 (1), C6F3Cl2-3,5 (2)) and their silver complexes... 
ISOCYANIDE COMPLEX | AGGREGATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Acta Crystallographica Section C, ISSN 2053-2296, 09/2019, Volume 75, Issue 9, pp. 1259 - 1265
Treatment of bis(mesitylene)niobium(0) with 6–7 equivalents of 2,6‐dimethylphenyl isocyanide (CNXyl) affords two products with the empirical formula Nb(CNXyl)n... 
squarate | low‐valent | 2,6‐dimethylphenyl isocyanide | 2,6‐diisopropylphenyl isocyanide | niobium | crystal structure | squaramidinate | isocyanide | Tetrahydrofuran | Mesitylene | Ligands | Dimers | Argon | Crystallography | Niobium | Monomers | Diamagnetism
Journal Article
Synthetic Communications, ISSN 0039-7911, 02/2019, Volume 49, Issue 4, pp. 515 - 521
In an attempt to further exploit multicomponent reactions in the field of 1,4 naphthoquinone-based compounds, we describe an Ugi-type multicomponent approach... 
multicomponent reactions | quinones | isocyanide chemistry | Enols | ISOCYANIDES | ISONITRILE | CHEMISTRY, ORGANIC
Journal Article