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iminyl radicals (146) 146
chemistry, organic (100) 100
chemistry, multidisciplinary (58) 58
cyclization (36) 36
generation (31) 31
derivatives (27) 27
photoredox catalysis (25) 25
oximes (22) 22
radicals (21) 21
nitriles (19) 19
alkenes (18) 18
index medicus (18) 18
iminyl radical (17) 17
oxime (17) 17
chemistry (16) 16
nitrogen (16) 16
organic-synthesis (15) 15
molecular structure (14) 14
organic chemistry (14) 14
ketones (13) 13
radical cyclization (13) 13
catalysis (12) 12
chemistry, applied (12) 12
cleavage (12) 12
ring-cleavage (12) 12
aminyl radicals (11) 11
cyclizations (11) 11
cyclobutanone o-benzoyloximes (11) 11
esters (11) 11
hydroxamic acid-derivatives (11) 11
nitrogen-centered radicals (11) 11
synthesis (11) 11
visible light (11) 11
chemistry, physical (10) 10
metal-free (10) 10
amination (9) 9
centered radicals (9) 9
chemical properties (9) 9
cyclisation (9) 9
efficient synthesis (9) 9
electron-transfer (9) 9
free radicals (9) 9
functionalization (9) 9
heteroarenes (9) 9
iminyl-radical formation (9) 9
oxidative cyclization (9) 9
oxime esters (9) 9
oximes - chemistry (9) 9
unactivated alkenes (9) 9
c bond-cleavage (8) 8
intramolecular addition (8) 8
quinolines (8) 8
regioselective synthesis (8) 8
vinyl azides (8) 8
active methine group (7) 7
c-h bonds (7) 7
c-h functionalization (7) 7
carbamyl radicals (7) 7
chemical sciences (7) 7
heterocycles (7) 7
iminyl (7) 7
light-radiation (7) 7
n-heterocycles (7) 7
radical reactions (7) 7
reduction (7) 7
alkaloids (6) 6
amidyl radicals (6) 6
analysis (6) 6
aromatic compounds (6) 6
dioxime oxalates (6) 6
intramolecular cyclization (6) 6
o-phenyl oximes (6) 6
pyrrole (6) 6
substitution (6) 6
tetrabutylammonium iodide (6) 6
transformation (6) 6
[ chim.orga ] chemical sciences/organic chemistry (5) 5
acids (5) 5
acyl oximes (5) 5
aldoxime esters (5) 5
alkene (5) 5
amides (5) 5
amines (5) 5
aryl radicals (5) 5
azides (5) 5
bond formation (5) 5
catalysts (5) 5
chain reactions (5) 5
chemical-radical (5) 5
chemisches radikal (5) 5
cyclobutanone oxime esters (5) 5
dihydropyrroles (5) 5
ethers (5) 5
free radicals - chemistry (5) 5
functionalisation (5) 5
funktionalisierung (5) 5
group migration (5) 5
h cyanoalkylation (5) 5
inhibitors (5) 5
olefins (5) 5
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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 3, pp. 738 - 743
A room‐temperature, visible‐light‐driven N‐centered iminyl radical‐mediated and redox‐neutral C−C single bond cleavage/radical addition cascade reaction of... 
iminyl radicals | photoredox catalysis | N-centered radicals | nitriles | heterocycles | ORGANIC-SYNTHESIS | NITROGEN-CENTERED RADICALS | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | FUNCTIONALIZATION | ACID-DERIVATIVES | ELECTRON-TRANSFER | H BONDS | GENERATION | CYCLOBUTANONES | Nitriles | Esters | Carbon-carbon composites | Oximes | Oxime esters | Alkenes | Ketones | Chemical bonds | Cleavage | Cascade chemical reactions | Ethers | Alkynes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2018, Volume 24, Issue 2, pp. 312 - 316
Visible‐light‐induced generation of α‐iminyl radicals was accomplished using α‐bromo cyclic N‐sulfonylimines and photoredox catalysts such as erythrosine B or... 
α-iminyl radical | radical reactions | imines | photoredox catalysis | visible light | DYE | ELECTRON-TRANSFER | ALPHA,BETA-UNSATURATED ALDEHYDES | ALLYLATION | alpha-iminyl radical | KETIMINES | CHEMISTRY, MULTIDISCIPLINARY | VISIBLE-LIGHT IRRADIATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2018, Volume 360, Issue 18, pp. 3601 - 3606
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 6, pp. 1692 - 1696
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2009, Volume 15, Issue 32, pp. 7830 - 7840
Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon‐ and heteroatom‐centered radicals, both in intra‐... 
aminyl radicals | iminyl radicals | radicals | azides | synthetic methods | Azides | Synthetic methods | Aminyl radicals | Radicals | Iminyl radicals | AROMATIC AZIDES | TRIBUTYLTIN HYDRIDE | NITRIC-OXIDE SYNTHASE | ELECTRON-SPIN RESONANCE | TRIBUTYLGERMANIUM HYDRIDE | CHEMISTRY, MULTIDISCIPLINARY | SULFONYL AZIDES | CHAIN REACTIONS | N-STANNYLAMINYL RADICALS | FORMAL TOTAL SYNTHESIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2018, Volume 140, Issue 36, pp. 11202 - 11205
The first catalytic strategy to harness imidate radicals has been developed. This approach enables alkene difunctionalization of allyl alcohols by... 
AMINATION | NITROGEN-CENTERED RADICALS | COUPLED ELECTRON-TRANSFER | FUNCTIONALIZED HYDROXYLAMINES | IMINYL RADICALS | OLEFINS | 1,3 TRANSPOSITION | AMINE FUNCTIONS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHOTOREDOX CATALYSIS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 47, pp. 14017 - 14021
The formation and use of iminyl radicals in novel and divergent hydroimination and iminohydroxylation cyclization reactions has been accomplished through the... 
hydroimination | photoredox catalysis | visible light | iminohydroxylation | electron transfer | DONOR-ACCEPTOR COMPLEX | ORGANIC-SYNTHESIS | PHOTOINDUCED ELECTRON-TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | BETA-HYDROXYLATION | HETEROARENES | C-H ARYLATION | SYNTHETIC APPLICATIONS | IMINYL RADICALS | CHARGE-TRANSFER | Catalysis | Communications
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2018, Volume 360, Issue 22, pp. 4341 - 4347
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2018, Volume 24, Issue 3, pp. 594 - 598
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 4, pp. 1034 - 1037
An efficient synthesis of cyanoalkylated heteroarenes via iron-catalyzed direct C–H cyanoalkylation of heteroarenes has been developed. Structurally diverse... 
ALLYLIC ALCOHOLS | CYCLOBUTANONE O-BENZOYLOXIMES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | QUINOXALINONE DERIVATIVES | ALKYL NITRILES | IMINYL RADICALS | INHIBITORS | RING-CLEAVAGE | OXIME ESTERS | UNACTIVATED ALKENES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2018, Volume 24, Issue 2, pp. 283 - 283
The generation of an α‐iminyl radical and its application to organic synthesis were successfully accomplished. An α‐iminyl radical was produced using a... 
α-iminyl radical | radical reactions | imines | photoredox catalysis | visible light
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY B, ISSN 1520-6106, 09/2015, Volume 119, Issue 35, pp. 11496 - 11505
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 84, pp. 11544 - 11547
A photoredox approach to generate distal cyano-substituted alkyl radicals through C-C bond cleavage of cyclobutanone oximes was developed. The radicals... 
PHENANTHRIDINE DERIVATIVES | ALLYLIC ALCOHOLS | QUINOLINES | IMINYL RADICALS | ALKYL NITRILES | CASCADE | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | CYCLIZATION | PHOTOREDOX CATALYSIS | TRIFLUOROMETHYLATION
Journal Article