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Chemistry – A European Journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 54, pp. 14368 - 14372
The hypervalent iodine reagent PhI(OAc) 2 (PIDA) mediated the formal oxidative C=C bond cleavage and subsequent cyclization of internal olefins, that is,... 
oxazolines | isothiazoline | hypervalent compounds | cleavage reactions | internal olefins | ORGANIC-SYNTHESIS | EFFICIENT SYNTHESIS | DIARYLIODONIUM SALTS | CHEMISTRY, MULTIDISCIPLINARY | N,S-ACETALS | REARRANGEMENT | INTERNAL ALKENES | OXIDATIVE CLEAVAGE | DERIVATIVES | METATHESIS | C-H | Substitutes | Alkenes | Reagents | Cleavage | Derivatives | Acetals | Iodine | Intermediates
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2014, Volume 50, Issue 83, pp. 12479 - 12481
CuCl2 and CuBr2-mediated intramolecular oxidative C-H/N-H cross-coupling/halogenation of beta-thioalkyl-substituted alpha-alkenoyl ketene N,S-acetals occurred... 
OXYGEN | ACTIVATION | HETEROCYCLES | SUBSTITUTED PYRROLIN-4-ONES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | ACCESS | AMIDES | Cross coupling | Synthesis | Halogenation | Chemical bonds | Transformations | Resultants | Derivatives | Ketenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16342 - 16346
A novel approach for the umpolung α‐arylation of amides is presented. By the nucleophilic phenylation of O‐silyl N,O‐ketene acetals, generated in situ from... 
amides | aluminum | ketene acetals | nucleophilic addition | umpolung | ASYMMETRIC-SYNTHESIS | WEINREB AMIDES | CHIRAL AUXILIARY | CHEMISTRY, MULTIDISCIPLINARY | MUKAIYAMA ALDOL REACTIONS | N-ALKOXYENAMINES | AMINO-ACIDS | ENANTIOSELECTIVE HYDROGENATION | HIGHLY DIASTEREOSELECTIVE DESYMMETRISATION | HYDROGEN-BOND CATALYSIS | CYCLIC MESO-ANHYDRIDES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2019, Volume 361, Issue 6, pp. 1208 - 1229
Journal Article
Chemical Reviews, ISSN 0009-2665, 01/2016, Volume 116, Issue 2, pp. 287 - 322
Journal Article
Molecular Diversity, ISSN 1381-1991, 2/2018, Volume 22, Issue 1, pp. 11 - 19
A synthesis of functionalized 4,5-bis(phenylimino)-1,3-thiazolidine-2-ylidenes via a simple reaction between ketene $$N,S$$ N,S -acetals (derived from... 
Life Sciences | Biochemistry, general | Polymer Sciences | Heterocyclic synthesis | Ketene acetals | Pharmacy | Push–pull olefins | Organic Chemistry | Thiazolidine | CHEMISTRY, MEDICINAL | Push-pull olefins | CHLORIDES | PRIMARY AMINES | CHEMISTRY, APPLIED | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Chemical synthesis | Chemical compounds
Journal Article
Tetrahedron, ISSN 0040-4020, 2010, Volume 66, Issue 16, pp. 2919 - 2927
Push–pull alkenes can be quickly accessed by cyclic ketene- , ′-acetal chemistry. A number of push–pull structures with a wide span of double bond lengths and... 
X-ray crystallography | Ketene acetal | Push–pull alkene | Double bond twist | Double bond elongation | Push-pull alkene | DIELS-ALDER REACTIONS | PI-ELECTRON DISTRIBUTION | AB-INITIO | ETHYLENES | REACTIVITY | CHEMISTRY, ORGANIC | DYNAMIC BEHAVIOR | C-13 NMR-SPECTROSCOPY | CATIONIC-POLYMERIZATION | KETENE ACETALS | COPOLYMERIZATION | Isocyanates | Dichloropropane | Chemical properties | Analysis | Olefins | Chlorides
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2017, Volume 2017, Issue 2, pp. 252 - 256
Claisen rearrangements of benzyl vinyl ethers are much less facile than those of aliphatic allyl vinyl ethers, and their synthetic utility has remained... 
Benzyl alcohols | Density functional calculations | Ketene acetals | Sigmatropic rearrangement | Pericyclic reactions | ROUTE | ALLYL | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | 5-METHYLENE-1,3-CYCLOHEXADIENE ORTHO-ISOTOLUENE | ENE | Acetates
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2017, Volume 58, Issue 30, pp. 2944 - 2947
Cyclic ketene silyl acetals were utilized for [2 + 2] cycloaddition with propiolates to prevent an undesired electrocyclic ring opening reaction.... 
Cyclobutenes | [2 + 2] cycloaddition | Ketene silyl acetals | Cyclobutanes | [2 + 2] cycloaddition | ELECTROPHILIC ACETYLENES | ORGANIC-SYNTHESIS | ENOL ETHERS | CHEMISTRY, ORGANIC | [2+2] cycloaddition | DERIVATIVES | ETHYL PROPIOLATE | ALKALOIDS | MOLECULES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2018, Volume 2018, Issue 30, pp. 4040 - 4049
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2009, Volume 50, Issue 18, pp. 2135 - 2139
, -Dimethyl cyclic ketene , -acetals react with two or three equivalents of isocyanates to generate tetrasubstituted push–pull alkene derivatives in one-pot... 
HYDROGEN | DIELS-ALDER REACTIONS | KETENE-N,X-ACETALS X | NMR-SPECTROSCOPY | AB-INITIO | ETHYLENES | ISOMERIZATION | CHEMISTRY, ORGANIC | OLEFINS | ACETALS | POLYMERIZATION | Isocyanates | Olefins
Journal Article