X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, inorganic & nuclear (17) 17
ketimide complexes (16) 16
olefin polymerization (14) 14
ligands (12) 12
reactivity (12) 12
titanium (12) 12
chemistry, organic (11) 11
ketimide (10) 10
chemistry (9) 9
chemistry, multidisciplinary (9) 9
catalysis (8) 8
copolymerization (7) 7
ethylene (7) 7
chemistry, physical (6) 6
ethylene polymerization (6) 6
uranium (6) 6
zirconium (6) 6
(cyclopentadienyl)(aryloxy)titanium(iv) complexes (5) 5
homogeneous catalysis (5) 5
living copolymerization (5) 5
molecular-structure (5) 5
polymerization (5) 5
structural-characterization (5) 5
activation (4) 4
alpha-olefins (4) 4
bonding (4) 4
crystal-structure (4) 4
crystallography (4) 4
functional-group introduction (4) 4
insertion (4) 4
ketimide complex (4) 4
ketimide ligands (4) 4
ketimides (4) 4
ligand (4) 4
metallocene complexes (4) 4
thorium (4) 4
x-ray (4) 4
alkene polymerization (3) 3
amide (3) 3
amides (3) 3
analysis (3) 3
catalysts (3) 3
crystal-structures (3) 3
cyclopentadienyl fragment (3) 3
derivatives (3) 3
efficient incorporation (3) 3
electronic-structure (3) 3
ligand effect (3) 3
mao catalyst systems (3) 3
metallocene catalysts (3) 3
polar vinyl comonomers (3) 3
polymer science (3) 3
polyolefins (3) 3
propylene (3) 3
ray crystal-structure (3) 3
styrene (3) 3
syndiospecific styrene polymerization (3) 3
actinide (2) 2
azomethine derivatives (2) 2
bonds (2) 2
carbenes (2) 2
catalytic activity (2) 2
cobalt (2) 2
communications (2) 2
complexes (2) 2
copper (2) 2
cross-coupling reactions (2) 2
cyclopentadienyl (2) 2
density functionals (2) 2
density-functional theory (2) 2
diamagnetism (2) 2
dispersion (2) 2
dispersion-force (2) 2
dispersionskraft (2) 2
disproportionation (2) 2
disproportionierung (2) 2
donor ligands (2) 2
ethylene polymerization catalysis (2) 2
h bond activation (2) 2
half-titanocene (2) 2
inert (2) 2
inorganic chemistry (2) 2
insertion reactions (2) 2
iron (2) 2
linkages (2) 2
lithium (2) 2
mao (2) 2
metal-complexes (2) 2
metallocene (2) 2
molecular-structures (2) 2
n ligands (2) 2
nitrile insertion (2) 2
olefin polymerization catalysts (2) 2
olefins (2) 2
phenyl-terpyridyl-substituted ketimide ligand (2) 2
physical chemistry (2) 2
propene polymerization (2) 2
single crystal x-ray study (2) 2
specific gravity (2) 2
spectators (2) 2
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 23, pp. 6426 - 6430
We report herein three new modes of reactivity between arylazides N 3 Ar with a bulky copper(I) β‐diketiminate. Addition of N 3 Ar X3 (Ar X3 =2,4,6‐X 3 C 6 H 2... 
copper | C−H amination | ketimide | group transfer | nitrenes | triazenide | C-H amination | ENERGY | TRIAZENIDE COMPLEXES | KETIMIDE COMPLEX | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | DICOPPER NITRENES | LIGANDS | MECHANISTIC INSIGHTS | ASYMMETRIC AZIRIDINATION | BONDS | Nitriles | Ethylbenzene | Copper | Intermediates
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2014, Volume 126, Issue 35, pp. 9510 - 9513
The ketimide anion R 2 CN − is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting... 
Amide | Carbene | N‐Liganden | Ketimide | Thorium | Linkages | Synthesis | Actinides | Insertion | Amides | Ligands | Inert | Spectators | Bonding
Journal Article
Nature Communications, ISSN 2041-1723, 03/2017, Volume 8, Issue 1, pp. 14769 - 14769
Despite a major expansion of uranium-ligand multiple bond chemistry in recent years, analogous complexes involving other actinides (An) remain scarce. For... 
URANIUM | PHOSPHORUS | MOLECULAR-COMPOUNDS | INFRARED-SPECTRA | MULTIDISCIPLINARY SCIENCES | KETIMIDE COMPLEX | REACTIVITY | CRYSTAL-STRUCTURES | LIGAND | MULTIPLE BONDS | CARBENE COMPLEXES
Journal Article
Organometallics, ISSN 0276-7333, 09/2018, Volume 37, Issue 17, pp. 2872 - 2879
Ti-C homolysis is generally regarded as a catalyst deactivation step in olefin polymerization catalyzed by titanium complexes. The present work demonstrates... 
H BOND ACTIVATION | ALPHA-OLEFINS | DORMANT SITES | PHOSPHINIMIDE COMPLEXES | DEACTIVATION PATHWAY | KETIMIDE COMPLEXES | COMONOMER AFFINITY | CHEMISTRY, ORGANIC | PROPENE POLYMERIZATION | ALKYL COMPLEXES | CHAIN TRANSFER | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 08/2011, Volume 40, Issue 30, pp. 7666 - 7682
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 34, pp. 10108 - 10113
Journal Article
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, ISSN 0887-624X, 09/2017, Volume 55, Issue 18, pp. 2877 - 2891
ARLANXEO Elastomers has developed and commercialized Keltan ACE (TM) technology, a class of half-sandwich cyclopentadienyl kappa(1)-amidinate metal complexes,... 
MECHANISTIC ASPECTS | product diversification | MOLECULAR-WEIGHT MODEL | POLYMER SCIENCE | OLEFIN POLYMERIZATION | KETIMIDE COMPLEXES | PEROXIDE CROSS-LINKING | post metallocene | MASS-SPECTROMETRY | Keltan ACE Technology | EPDM | GAS-CHROMATOGRAPHY | polyolefins | catalysts | rubber | CURED EPDM | 3RD MONOMER | COMBINATION REACTIONS
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2018, Volume 857, Issue C, pp. 34 - 37
Reaction of [UO Cl (THF) ] with 8 equiv of Li(N=C BuPh) or 6 equiv of Li(N=C Bu ) affords the uranyl ketimide complexes, [Li(THF)(Et O)] [UO (N=C BuPh) ] ( )... 
Actinide | Oxo functionalization | Lithium | Uranyl | Ketimide | OF-PLANE | ALKOXIDE | AMIDE | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | LIGANDS | CHEMISTRY | EQUATORIAL COORDINATION | REDUCTIVE SILYLATION | BOND | Surface active agents | Analysis | Chemistry
Journal Article
Catalysis Today, ISSN 0920-5861, 2008, Volume 133, Issue 1-4, pp. 647 - 653
Compounds [Ti(N C Bu )Cl ] , , [Ti(N C Bu ) Cl ] , , [Ti(N C Bu )(CH Ph) ], , [Ti(N C Bu ) (CH Ph) ], , [Ti(N C Bu )(CH Ph) (μ-CH PhB(C F ) ], and [Ti(N C Bu )... 
Ethylene polymerization | MAO | Titanium ketimide
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 50, pp. 15871 - 15875
The first homoleptic cobalt phosphanido complex [K(thf) 4 ][Co{1,2‐(P t Bu 2 ) 2 C 2 B 10 H 12 } 2 ] ( 1 ) was prepared by an unprecedented oxidative P−P bond... 
P ligands | cobalt | density functional theory calculations | homoleptic compounds | carboranes | ACTIVATION | REACTIVITY | STATE | IONS | SUBSTANCES | KETIMIDE | CHEMISTRY, MULTIDISCIPLINARY | TETRAKIS(1-NORBORNYL)COBALT | CHEMISTRY | BUILDING-BLOCK | 4-COORDINATE | Density functionals | Specific gravity | Cobalt | Ground state | Carborane | Magnetic measurement | Diamagnetism
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 02/2016, Volume 22, Issue 6, pp. 1931 - 1936
After more than 50 years, the synthesis and electronic structure of the first and only reported U-0 complex [U(bipy)(4)] (1) has been reinvestigated.... 
RAY-ABSORPTION SPECTROSCOPY | radicals | KETIMIDE LIGANDS | OXIDATION-STATE | URANIUM COMPLEXES | REACTIVITY | ELECTRON-TRANSFER SERIES | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | redox chemistry | magnetic properties | electronic structure | uranium | DENSITY-FUNCTIONAL THEORY | GROUND-STATES | OXO COMPLEX
Journal Article
Organometallics, ISSN 0276-7333, 02/2016, Volume 35, Issue 4, pp. 494 - 502
Reaction of UCl4 with 6 equiv of 2-Li-C(6)H(4)C(H)2NMe(2) affords the U(IV) dibenzyne complex[Li](])2[U(2,3-C6H3CH2NMe2)(2)(2-C6H4CH2NMe2)(2)](1), which can be... 
URANIUM | BENZYNE COMPLEX | ARYNE COMPLEXES | CHEMICAL-SHIFTS | INSERTION REACTIONS | X-RAY | KETIMIDE COMPLEX | C-C | CHEMISTRY, ORGANIC | METAL-COMPLEXES | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 02/2010, Volume 29, Issue 4, pp. 945 - 950
The insertion reactivity of (C5Me5)(2)U(C CPh)(2), 1, has been studied with CO2, PhNCO, Me-3-CC N, and Me3CN C. Insertion into both U-C CPh bonds of 1 occurs... 
SIGMA-BOND | MOLECULAR-STRUCTURE | INTERMOLECULAR HYDROAMINATION | ACTINIDE-ALKYL | ORGANOACTINIDE COMPLEXES | KETIMIDE COMPLEXES | X-RAY | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | CARBON-DIOXIDE | N-BUTYL | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 47, pp. 14766 - 14769
Journal Article
Organometallics, ISSN 0276-7333, 03/2016, Volume 35, Issue 5, pp. 785 - 798
A pendant nitrile group attached to the lithium cyclopentadienide moiety in (C(5)H(4)CM(e)2CMe(2)CN)Li was alkylated using organyl lithium reagents (RLi, R =... 
BENT METALLOCENE FRAMEWORKS | TITANOCENE COMPLEXES | ALPHA-OLEFIN COPOLYMERIZATION | CRYSTAL-STRUCTURE | MAO CATALYST SYSTEMS | REACTIVITY | CHEMISTRY, ORGANIC | ETHYLENE POLYMERIZATION ACTIVITY | FUNCTIONAL-GROUPS | CP/AMIDO TITANIUM | TITANIUM COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article