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1. Full Text Capturing Biological Activity in Natural Product Fragments by Chemical Synthesis
by Crane, Erika A and Gademann, Karl
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 12, pp. 3882 - 3902
Natural products have had an immense influence on science and have directly led to the introduction of many drugs. Organic chemistry, and its unique ability to... 
natural products | drug discovery | organic chemistry | organic synthesis | medicinal chemistry | WIDE STRUCTURAL VARIABILITY | PROTEIN-KINASE-C | FUNCTION-ORIENTED SYNTHESIS | CELL-MIGRATION INHIBITORS | PHORBOL ESTER PHARMACOPHORE | STEREOSELECTIVE TOTAL-SYNTHESIS | UNCULTIVATED BACTERIAL SYMBIONT | CHEMISTRY, MULTIDISCIPLINARY | ANTITUMOR ANTIBIOTIC DYNEMICIN | ENANTIOSELECTIVE TOTAL-SYNTHESIS | MACROCYCLIC KETONE ANALOGS | Chemical synthesis | Drug discovery | Pharmaceutical industry | Natural products | Drugs | Fragments | Light emitting diodes | Genomes | Selectivity | Drug development | Biological activity | Fragmentation | Organic chemistry | Computer applications | Reviews | Review
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2. Full Text Pursuing practical elegance in chemical synthesis
by Noyori, Ryoji
Chemical Communications, ISSN 1359-7345, 04/2005, Issue 14, pp. 1807 - 1811
In the 21st century, the field of chemistry will face more than just academic challenges. Indeed, our ability to devise straightforward and practical chemical... 
OXIDATION | CATALYSIS | KETONES | COMPLEXES | ASYMMETRIC HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | PEROXIDE
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3. Full Text Recent developments in the use of catalytic asymmetric ammonium enolates in chemical synthesis
by Gaunt, Matthew J and Johansson, Carin C.C
Chemical Reviews, ISSN 0009-2665, 12/2007, Volume 107, Issue 12, pp. 5596 - 5605
CHIRAL NUCLEOPHILE | ORGANOCATALYTIC CYCLOPROPANATION | BICYCLIC BETA-LACTONES | ENANTIOSELECTIVE SYNTHESIS | BAYLIS-HILLMAN REACTION | PHASE-TRANSFER CATALYSIS | ALPHA-AMINO-ACIDS | ALDOL REACTIONS | ONE-POT PROCEDURE | SHUTTLE-DEPROTONATION | CHEMISTRY, MULTIDISCIPLINARY | Lactones - chemical synthesis | Cyclization | Stereoisomerism | Ketones - chemistry | Lactams - chemical synthesis | Molecular Structure | Catalysis | Quaternary Ammonium Compounds - chemistry | Lactams - chemistry | Lactones - chemistry | Research | Chemical properties | Observations | Chirality | Enolates
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4. Full Text A continuous flow-batch hybrid reactor for commodity chemical synthesis enabled by inline NMR and temperature monitoring
by Schotten, Christiane and Howard, Joseph L and Jenkins, Robert L and Codina, Anna and Browne, Duncan L
Tetrahedron, ISSN 0040-4020, 09/2018, Volume 74, Issue 38, pp. 5503 - 5509
Inline, real time NMR and temperature measurements have been used to optimise the continuous flow synthesis of difluoromethyltrimethylsilane (TMSCF H) by the... 
Flow NMR | Space time yield | Exotherm control | Inline monitoring | Continuous flow | SELF-OPTIMIZATION | COPPER-MEDIATED DIFLUOROMETHYLATION | DIRECT NUCLEOPHILIC DIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | ENOLIZABLE KETONES | HIGH-RESOLUTION NMR | SPECTROSCOPY | CHEMISTRY | FLUORINE | ARYL | ONLINE NMR | Chemical synthesis | Nuclear magnetic resonance
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5. Full Text Au-Pd supported nanocrystals prepared by a sol immobilisation technique as catalysts for selective chemical synthesis
by Lopez-Sanchez, Jose Antonio and Dimitratos, Nikolaos and Miedziak, Peter and Ntainjua, Edwin and Edwards, Jennifer K and Morgan, David and Carley, Albert F and Tiruvalam, Ramchandra and Kiely, Christopher J and Hutchings, Graham J
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2008, Volume 10, Issue 14, pp. 1921 - 1930
Catalysis by gold and gold-palladium nanoparticles has attracted significant research attention in recent years. These nanocrystalline materials have been... 
GOLD NANOPARTICLES | ALCOHOLS | LIQUID-PHASE OXIDATION | PARTICLES | CARBON-MONOXIDE | O-2 | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | FUEL-CELLS | HYDROGEN-PEROXIDE | ABSORPTION | H-2 | Combinatorial Chemistry Techniques - methods | Gold - chemistry | Nanoparticles - chemistry | Oxidation-Reduction | Microscopy, Electron, Transmission - methods | Nanotechnology - methods | Benzyl Alcohol - chemistry | Particle Size | Time Factors | Hydrogen Peroxide - chemical synthesis | Spectrum Analysis - methods | X-Rays | Surface Properties | Catalysis | Palladium - chemistry
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6. Nanostructured mg-al hydrotalcite as catalyst for fine chemical synthesis
by Basahel, Sulaiman N and Al-Thabaiti, Shaeel A and Narasimharao, Katabathini and Ahmed, Nesreen S and Mokhtar, Mohamed
Journal of Nanoscience and Nanotechnology, ISSN 1533-4880, 02/2014, Volume 14, Issue 2, pp. 1931 - 1946
This paper reviews the recent research of nanostructured Mg-Al hydrotalcite (Mg-Al HT) and its application as an efficient solid base catalyst for the... 
Processing & Characterization | Hydrotalcite | Microwave Irradiation | Fine Chemicals | Materials Properties | Nanostructured | Green Protocol | Layered Materials | Anionic Clays | PHYSICS, CONDENSED MATTER | ALDOL CONDENSATIONS | PHYSICS, APPLIED | LAYERED DOUBLE HYDROXIDES | ALPHA,BETA-UNSATURATED KETONES | T-BU HYDROTALCITE | Processing and Characterization | MATERIALS SCIENCE, MULTIDISCIPLINARY | NANOSCIENCE & NANOTECHNOLOGY | CLAISEN-SCHMIDT CONDENSATION | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | HYDROTHERMAL SYNTHESIS | SOLID BASE CATALYSTS | HYDROGEN-PEROXIDE | Aluminum - chemistry | Metal Nanoparticles - chemistry | Molecular Conformation | Materials Testing | Magnesium Hydroxide - chemistry | Particle Size | Magnesium - chemistry | Macromolecular Substances - chemistry | Green Chemistry Technology - methods | Aluminum Hydroxide - chemistry | Surface Properties | Catalysis | Metal Nanoparticles - ultrastructure | Waste management | Heat treatment | Synthesis | Effectiveness | Catalysts | Fine chemicals | Nanostructure | Structural analysis
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7. Full Text The migrastatin family: Discovery of potent cell migration inhibitors by chemical synthesis
by Gaul, Christoph and Njardarson, Jón T and Shan, Dandan and Dorn, David C and Wu, Kai-Da and Tong, William P and Huang, Xin-Yun and Moore, Malcolm A. S and Danishefsky, Samuel J
Journal of the American Chemical Society, ISSN 0002-7863, 09/2004, Volume 126, Issue 36, pp. 11326 - 11337
The first asymmetric total synthesis of (+)-migrastatin (1), a macrolide natural product with antimetastatic properties, has been accomplished. Our concise and... 
ORGANIC-SYNTHESIS | RING-CLOSING METATHESIS | ABSOLUTE-CONFIGURATION | ENANTIOSELECTIVE SYNTHESIS | XESTOSPONGIA-EXIGUA KIRKPATRICK | BIOLOGICAL-ACTIVITY | STREPTOMYCES SP MK929-43F1 | ANTIFUNGAL ANTIBIOTICS | ANGIOGENESIS INHIBITOR | TRANSFORMED NIH/3T3 CELLS | CHEMISTRY, MULTIDISCIPLINARY | Endothelium, Vascular - cytology | Ketones - pharmacology | Piperidones - chemical synthesis | Humans | Endothelium, Vascular - drug effects | Structure-Activity Relationship | Piperidones - pharmacology | Lactones - pharmacology | Cell Movement - drug effects | Piperidones - chemistry | Lactones - chemical synthesis | Animals | Ketones - chemical synthesis | Macrolides - chemical synthesis | Mammary Neoplasms, Experimental - pathology | Alcohols - chemical synthesis | Macrolides - pharmacology | Mice | Alcohols - pharmacology | Mammary Neoplasms, Experimental - drug therapy | Macrolide antibiotics | Stereochemistry | Research | Observations | Aldehydes | Chemical synthesis
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8. Full Text Allene ether Nazarov cyclization
by Tius, Marcus A
Chemical Society reviews, ISSN 0306-0012, 05/2014, Volume 43, Issue 9, pp. 2979 - 3002
The ease of synthesis and the exceptional reactivity of alkoxyallenes has led to their use in a large number of highly diverse applications. This Report... 
Amines - chemistry | Oxides - chemical synthesis | Alcohols - chemistry | Ethers - chemical synthesis | Alkynes - chemical synthesis | Stereoisomerism | Oxides - chemistry | Cyclopentanes - chemistry | Ethers - chemistry | Alkynes - chemistry | Amines - chemical synthesis | Alkadienes - chemistry | Chemistry Techniques, Synthetic - methods | Biological Products - chemical synthesis | Biological Products - chemistry | Cyclization | Ketones - chemical synthesis | Alkadienes - chemical synthesis | Imines - chemistry | Ketones - chemistry | Alcohols - chemical synthesis | Imines - chemical synthesis | Cyclopentanes - chemical synthesis
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9. Full Text Natural product synthesis using multicomponent reaction strategies
by Touré, Barry B and Hall, Dennis G
Chemical Reviews, ISSN 0009-2665, 09/2009, Volume 109, Issue 9, pp. 4439 - 4486
SQUARATE ESTER CASCADE | DIVERSITY-ORIENTED SYNTHESIS | DIELS-ALDER REACTIONS | TANDEM 1,4-ADDITION-ALDOL REACTION | STEREOCONTROLLED TOTAL-SYNTHESIS | SESQUITERPENE HYDROQUINONE DERIVATIVES | 3-COMPONENT MANNICH REACTION | ANION RELAY CHEMISTRY | ASYMMETRIC TOTAL-SYNTHESIS | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Aldehydes - chemical synthesis | Alkylation | Biological Products - chemical synthesis | Biological Products - chemistry | Cyclization | Epoxy Compounds - chemical synthesis | Cyanides - chemistry | Ketones - chemical synthesis | Epoxy Compounds - chemistry | Ketones - chemistry | Catalysis | Aldehydes - chemistry | Cyanides - chemical synthesis | Carbonyl compounds | Usage | Epoxy compounds | Chemical properties | Nucleophilic reactions | Aldehydes | Structure | Enolates
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10. Full Text Heterogeneous catalysts for the one-pot synthesis of chemicals and fine chemicals
by Climent, Maria J and Corma, Avelino and Iborra, Sara
Chemical Reviews, ISSN 0009-2665, 02/2011, Volume 111, Issue 2, pp. 1072 - 1133
RUTHENIUM-GRAFTED HYDROTALCITE | HIGHLY EFFICIENT CATALYST | REDUCTION-CYCLIZATION HRC | ENTRAPPED OPPOSING REAGENTS | ONE-STEP SYNTHESIS | PHASE BECKMANN REARRANGEMENT | HYDROTALCITE-SUPPORTED PALLADIUM | BAEYER-VILLIGER OXIDATION | OCTAHEDRAL MOLECULAR-SIEVES | CHEMISTRY, MULTIDISCIPLINARY | METHYL ISOBUTYL KETONE | Condensation reactions | Heterogeneous catalysis | Analysis | Fine chemicals | Chemical reactions | Chemical properties | Chemical synthesis
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11. Full Text Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α‐Oxo Acids
by Chu, Lingling and Lipshultz, Jeffrey M and MacMillan, David W. C
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 27, pp. 7929 - 7933
The direct decarboxylative arylation of α‐oxo acids has been achieved by synergistic visible‐light‐mediated photoredox and nickel catalysis. This method offers... 
photoredox catalysis | decarboxylation | α‐oxo acids | arylation | nickel catalysis | Photoredox catalysis | Arylation | Nickel catalysis | Decarboxylation | α-oxo acids | Hydrocarbons, Aromatic - chemistry | Nickel - chemistry | Oxidation-Reduction | Ketones - chemical synthesis | Keto Acids - chemistry | Light | Hypolipidemic Agents - chemical synthesis | Ketones - chemistry | Fenofibrate - chemical synthesis | Catalysis | Hydrocarbons, Aromatic - chemical synthesis | Keto Acids - chemical synthesis | Synthesis | Ketones | Aromatic compounds | Precursors | Joining | Nickel | Radicals
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12. Full Text Transition metal-mediated synthesis of monocyclic aromatic heterocycles
by Gulevich, Anton V and Dudnik, Alexander S and Chernyak, Natalia and Gevorgyan, Vladimir
Chemical Reviews, ISSN 0009-2665, 05/2013, Volume 113, Issue 5, pp. 3084 - 3213
KETONE O-PENTAFLUOROBENZOYLOXIMES | SECONDARY PROPARGYLIC ALCOHOLS | ALPHA-DIAZOCARBONYL COMPOUNDS | RING-CLOSING METATHESIS | ONE-STEP SYNTHESIS | ONE-POT SYNTHESIS | PALLADIUM-CATALYZED CYCLIZATION | N BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY SUBSTITUTED FURANS | H INSERTION REACTIONS | Transition Elements - chemistry | Transition Elements - chemical synthesis | Heterocyclic Compounds, 1-Ring - chemistry | Heterocyclic Compounds, 2-Ring - chemistry | Heterocyclic Compounds, 2-Ring - chemical synthesis | Chemistry Techniques, Synthetic - methods | Heterocyclic Compounds, 1-Ring - chemical synthesis | Furans | Chemical properties | Research | Chemical synthesis | Pyrrole
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