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Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, pp. 11747 - 11751
We have developed a strategy to transform olefins into homoallylic nitriles through a mechanism that combines copper catalysis with alkyl nitrile radicals. The... 
Radikale | Kreuzkupplungen | Alkene | Alkylnitrile | Kupfer
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2017, Volume 129, Issue 23, pp. 6658 - 6662
A switchable site‐selective catalytic carboxylation of allylic alcohols has been developed in which CO2 is used with dual roles, both facilitating C−OH... 
Regioselektivität | Synthesemethoden | Kreuzkupplungen | Nickel | Kohlendioxid
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 39, pp. 12032 - 12036
Catalytic enantioselective conjunctive cross‐coupling between 9‐BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence... 
Kreuzkupplungen | Nickel | Asymmetrische Katalyse | Bor | Enantiomers | Borates
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2018, Volume 130, Issue 44, p. n/a
Photochemie In der Zuschrift auf S. 14684 ff. beschreiben C. Hertweck et al. eine metallfreie Kreuzkupplung, bei der zwei Phenylgruppen über einen temporären,... 
Synthesemethoden | Kreuzkupplungen | Sulfonamide | Photochemie | Biaryle
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2014, Volume 126, Issue 28, pp. 7418 - 7422
Recently, the development of more sustainable catalytic systems based on abundant first‐row metals, especially nickel, for cross‐coupling reactions has... 
Kreuzkupplungen | Nickel | Homogene Katalyse | Reaktionsmechanismen | Metallamide
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2019, Volume 131, Issue 25, pp. 8649 - 8653
An alkoxycarbonyl radical cyclization–cross‐coupling cascade has been developed that allows functionalized γ‐butyrolactones to be prepared in one step from... 
Kreuzkupplungen | Doppelkatalyse | Radikalcyclisierungen | Photoredoxreaktionen | Spirolactone | Oxalic acid | Drug discovery | Oxalates | Organic chemistry | Coupling | Aromatic compounds | Alcohols
Journal Article
Angewandte Chemie, ISSN 0044-8249, 11/2017, Volume 129, Issue 47, pp. 15332 - 15336
We report herein the use of a dual catalytic system comprising a Lewis base catalyst such as quinuclidin‐3‐ol or 4‐dimethylaminopyridine and a photoredox... 
Synthesemethoden | Kreuzkupplungen | Boronsäuren | Lewis-Basen-Katalyse | Photoredoxkatalyse | Chemical tests and reagents | Esters | Catalysis
Journal Article
Angewandte Chemie, ISSN 0044-8249, 01/2017, Volume 129, Issue 3, p. n/a
>Carborane: In der Zuschrift auf S. 730 beschreiben Z. Xie und Mitarbeiter die übergangsmetallfreie Photoarylierung von Iodcarboranen mit nichtaktivierten... 
Radikale | Kreuzkupplungen | Arene | Carborane | Photochemie
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2016, Volume 128, Issue 42, pp. 13546 - 13546
Die Rädchen von Ir‐Photoredox‐ und Ni‐Katalyse …… greifen ineinander und erzeugen eine leistungsstarke Kreuzkupplungsmaschinerie. M. S. Oderinde, J W. Johannes... 
Synthesemethoden | Kreuzkupplungen | Photokatalyse | Nickelkatalyse | Radikalreaktionen
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2016, Volume 128, Issue 37, pp. 11472 - 11472
Der mächtige Drache …… hier das Sinnbild eines Nickel‐Katalysators, greift die Ausgangsmaterialien (Isocyanate und nichtaktivierte Alkylbromide) mit seinen... 
Synthesemethoden | Kreuzkupplungen | Reduktive Kupplungen | Nickel
Journal Article
Angewandte Chemie, ISSN 0044-8249, 02/2017, Volume 129, Issue 7, pp. 1836 - 1840
In the presence of trifluoromethylsulfonium reagents, boronate complexes derived from 2‐lithio furan and non‐racemic secondary and tertiary alkyl or aryl... 
Trifluormethylierungen | Kreuzkupplungen | Stereospezifität | Furane | Boronsäureester | Esters | Furans | Aromatic compounds | Reagents | Chemical reactions | Oxidation | Coupling | Radicals
Journal Article
Angewandte Chemie, ISSN 0044-8249, 11/2016, Volume 128, Issue 45, pp. 14291 - 14295
We report herein a new method for the photoredox activation of boronic esters. Using these reagents, an efficient and high‐throughput continuous flow process... 
Synthesemethoden | Kreuzkupplungen | Borsäureester | Durchflusschemie | Photoredoxkatalyse | Cross coupling | Reagents | Solubility | Esters | Activation | Nickel | Coupling | Lewis base
Journal Article
Angewandte Chemie, ISSN 0044-8249, 08/2016, Volume 128, Issue 35, pp. 10619 - 10623
A continuous‐flow method for the regioselective arylation of fluoroarenes and fluoropyridines has been developed. The telescoped procedure reported here... 
Synthesemethoden | Kreuzkupplungen | Palladium | Durchflusschemie | Biaryle | Cross coupling | Synthesis | Derivatives | Temperature control
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2017, Volume 129, Issue 42, pp. 13268 - 13273
Along with amide bond formation, Suzuki cross‐coupling, and reductive amination, the Buchwald–Hartwig–Ullmann‐type amination of aryl halides stands as one of... 
Arylierungen | Elektrochemie | Kreuzkupplungen | Nickel | Aminierungen | Electrochemistry | Electrochemical reactions | Amides | Cross coupling | Amination | Halides | Aromatic compounds | Chemical bonds | Alcohols
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2019, Volume 131, Issue 11, pp. 3609 - 3612
Metal‐catalyzed enantioconvergent cross‐coupling reactions of alkyl electrophiles are emerging as a powerful tool in asymmetric synthesis. To date, high... 
Silicium | Kreuzkupplungen | Nickel | Alkylierung | Asymmetrische Katalyse | Synthesis | Chemical tests and reagents | Enantiomers | Organic compounds | Coupling (molecular) | Couplings | Asymmetric synthesis | Reagents | Chemical reactions | Catalysis | Chemical synthesis
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2016, Volume 128, Issue 14, pp. 4568 - 4572
Transition metal‐free couplings of haloarenes with arenes, triggered by the use of alkali metal alkoxides in the presence of an organic additive, are receiving... 
Radikale | Kreuzkupplungen | Arene | Reaktionsmechanismen | Elektronentransfer | Pyridine | Alkoxides | Additives | Receiving | Aromatic compounds | Initiators | Alkali metals | Coupling | Derivatives
Journal Article
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